Improving microwave dielectric properties of La2.98/3Sr0.01(Mg0.5Sn0.5)O3 ceramics with CuO additive

The microwave dielectric properties of CuO-doped La_2.98/3Sr_0.01(Mg_0.5Sn_0.5)O₃ ceramics were investigated with a view to their application in microwave devices. CuO-doped La_2.98/3Sr_0.01(Mg_0.5Sn_0.5)O₃ ceramics were prepared by the conventional solid-state method. The X-ray diffraction patterns of CuO-doped La_2.98/3Sr_0.01(Mg_0.5Sn_0.5)O₃ ceramics exhibited no significant variation of phase with sintering temperature. By adding 0.75 wt.% CuO, a dielectric constant of 20.07, a quality factor (Q × f) of 63,000 GHz, and a temperature coefficient of resonant frequency τ_f (−77.0 ppm/°C) were obtained when La_2.98/3Sr_0.01(Mg_0.5Sn_0.5)O₃ ceramics were sintered at 1500 °C for 4 h.     

Effects of divalent alkaline earth ions on the magnetic and transport features of La0.65A0.35Mn0.95Fe0.05O3 (A = Ca, Sr, Pb, Ba) compounds

We have studied the magnetic and transport properties of Fe doped La_0.65A_0.35Mn_0.95Fe_0.05O₃ (A = Ca, Sr, Pb, Ba) manganites. All the compositions show ferromagnetic/metal to paramagnetic/insulator transition (T_C) except the Pb doped sample which is insulating and ferromagnetic (FM) in the entire temperature range. The magnetization and T_C are decreased by decreasing the cation size on La site. The transition temperature and magnetic moment at 77 K is a maximum for Sr doped sample and is decreasing if we increase or decrease the cation size from Sr size. The maximum value of T_C and magnetic moment for Sr based sample is most likely due to the closer ionic sizes of La and Sr as compared to the other dopants (Ca, Pb, and Ba). We observed a spin freezing type effect in the Pb doped sample below 120 K in resistivity, ac susceptibility and in magnetization. This suggests that the AFM interactions introduced by the Fe are most effective in the Pb doped composition leading to increased competition between the FM and AFM interactions. This FM and AFM interaction generates some degree of frustration leading to the appearance of spin glass like phase whose typical magnetic behavior is studied for small ion when the metallic like behavior is lost.     

平行因子分析法在太湖水体三维荧光峰比值分析中的应用

以太湖水样三维荧光光谱数据为例,提出在采用平行因子分析法(PARAFAC)处理后的荧光数据中提取荧光峰强度计算荧光峰比值进行水环境分析评价的方法,较直接在水样原始荧光谱图中获取的荧光峰强度更加准确客观。天然水体中各水样间由于受荧光团复杂多样性等因素的影响,某类荧光物质荧光峰的激发发射波长位置并不是固定不变的,就同一水样而言各类荧光峰之间的相互重叠干扰也将影响到荧光峰强度和位置的准确判断。而在PARAFAC模型各因子中提取相应荧光峰值可以保证各水样间同类荧光物质荧光峰在同一位置又有效减弱同一水样中各类荧光物质荧光峰之间的相互干扰,更加高效准确的利用荧光峰比值进行水环境分析。区域差异性分析时水样因子得分比值的区域变化与原始荧光峰比值变化趋势是一致的。     

Symmetry of Lagrangians of holonomic nonconservative system in event space

This paper analyzes the symmetry of Lagrangians and the conserved quantity for the holonomic non-conservative system in the event space. The criterion and the definition of the symmetry are proposed first, then a quantity caused by the symmetry and its existence condition are given. An example is shown to illustrate the application of the result in the end.     

Generation of a squeezed state at 1.55 μ with periodically poled LiNbO3

We report on the generation of a squeezing vacuum at 1.55 μm using an optical parametric amplifier based on periodically poled LiNbO₃. Using three specifically designed narrow linewidth mode cleaners as the spatial mode and noise filter of the laser at 1.55 μm and 775 nm, the squeezed vacuum of up to 3.0 dB below the shot noise level at 1.55 μm is experimentally obtained. This system is compatible with standard telecommunication optical fibers, and will be useful for continuous variable long-distance quantum communication and distributed quantum computing.     

等离子喷涂含钪氧化物阴极制备及发射特性研究

在三元碳酸盐中加入微量钪,利用大气等离子喷涂方法制备出含钪等离子喷涂氧化物阴极. 制备过程中,在三元碳酸盐原来配比基础上增加12%—22%(摩尔百分比)的碳酸钡进行混合, 并将该混合物进行造粒,在造粒过程中加入微量的钪.利用扫描电子显微镜分析了等离子喷涂材料的形态 和分布,表明符合等离子喷涂对粉末大小和形状的要求,并解决了等离子喷涂过程中钡的损失问题. 对这种新型氧化物阴极的分解排气过程进行详细分析,结果表明,排气时这种阴极比普通喷涂阴极出气少 且分解时间短.对发射性能及寿命进行测试,结果显示这种新型氧化物阴极的性能显著提高,阴极寿命延长.     

电离层钡云释放早期动力学行为的数值模拟

在中性钡云扩散动力学模型的基础上,考虑钡原子的氧化和电离损耗, 探讨了钡云释放早期(t≤ 100 s)的演化基本特征、钡云形态、亮度以及电子密度分布等问题. 得到了不同释放量(1, 10 kg)、不同释放高度(250, 300 km)和不同初始形状因子(1, 10) 条件下钡云释放早期动力学行为的数值模拟结果.     

时空混合调制型偏振干涉成像光谱仪的全视场偏振信息探测研究

基于Savart板的新型时空混合调制型偏振干涉成像光谱仪(TSMPIIS)是一种静态、小型化、高稳定性的遥感偏振探测器件, 可以用来实现对目标的光谱信息以及偏振信息的探测. 目前, 已经确立了通过旋转TSMPIIS偏振片法来实现测量的方案, 然而该方案破坏了TSMPIIS系统原有的稳定结构, 降低了仪器的测量精度和可靠性. 为克服旋转偏振片法的不足, 本文从TSMPIIS的探测原理出发, 通过分析和计算TSMPIIS的Mueller矩阵, 推导出了全视场角度的TSMPIIS旋转偏振探测法的基本公式, 论证了TSMPIIS全视场偏振信息探测的可行性和准确性, 为TSMPIIS的遥感探测以及Stokes参数的反演提供了理论依据, 进一步拓展了TSMPIIS遥感探测的优越性.     

翼前缘层板对流冷却结构的防热效果分析

针对飞行器高超声速飞行时严重的气动加热环境, 设计一种层板对流冷却结构对翼前缘进行热防护. 提出一种壁面冷却效率参数η, 并运用流固耦合的分析方法, 研究了对流冷却结构在特定条件下的冷却效果, 其中采用水冷时头部冷却效率η 值最低为0.25. 研究表明, 对流结构冷却效果与内部冷却槽道深宽比γ 有重要关系, η值随γ 的增大而增大至一个稳定值, 此时冷却效果达到饱和, 若此时γ 继续增加则可能出现不利于冷却的现象. 冷却效果η随着前缘头部半径的减小而减弱. 研究还表明, 当层板对流冷却结构和材料固定时, η 值随冷却剂流量增加而增大, 并逐渐趋近至一个稳定值, 而冷却槽道进出口压差急剧增大. 因此需要综合考虑提高流量给供给系统带来的压力, 选取最佳流量值以达到相对较好的冷却效果. 对于材料而言, 内部冷却通道和外部耐热层都应选择导热系数较高的材料, 能够强化结构传热增强冷却效果.     

液态结构与性质关系Ⅲ——剩余键理论模型

利用剩余键的思想, 通过数学推导, 建立定量描述金属熔体结构与黏度关系的物理模型, 提出黏度的微观结构变化特性为熔体剩余键结构尺寸d的演变; 应用建立的模型理论计算液相线以上一定温区镁熔体和铝熔体的运动黏度, 得到函数关系式分别为v_Mg=3.17×10^-7+3.04×10^-7· d和v_Al=1.65×10^-7+1.05×10^-7·d, 这与采用坩埚扭摆振动法的实验测量结果相符合. 该模型从化学结合键角度揭 示了金属熔体的结构微观不均匀性及其黏度的微观物理本质, 为金属熔体黏度的理论计算提供了一种新的途径. 这对于深入认识液态金属的微观结构及其与宏观物性之间的关系具有重要意义.