Tracer Study on Catalytic Hydrogen Exchange Reactions over Nickel Catalyst

In heterogeneous catalysis it is important to know the reactivity of C-H bond in the hydrocarbon molecules. Experiments have been performed to obtain information about the exchange reaction of adsorbed hydrogen with methane and ethylene. In order to reduce the probability of forming products which contain more than one tritium atom, hydrogen labelled with H³ with low activity has been used.     

Aufbau und Erprobung von Flächenstrahlungsquellen als Sekimdärnormale zur Prüfung von Kontaminationsmeßgeraten für Betastrahler und zur Beglauhigung von Flächenstrahlungsquellen als Normale

Zur Prüfung von Kontaminationsmeβgeräten und zur Beglaubigung von Flächenstrahlungsquellen als Normale wurden im Deutscheti Amt für Meβwesen und Warenprüfung zwei Sälze von Flächenstrahlungsquellen mil den Betastrahlen ⁹⁰Sr/⁹⁰Y, ²⁰¹Tl und ⁶⁰Co angefertigt. Durch das dabei verwendete Herstellungsverfahren, bei dem je ein Tropfen rudioakliver Lösung in ein Feld eines vorgegebenen Rasters gebracht wurde, konnte eine sehr gleichmäβige Verteilung der akliven Substanz über die Quellenfläche erreicht und eine unmiltelbare Bestimmung der Flächenaktivitätswerte ermöglicht werden. Der besondere Aufbau der Flächenstrahlungsquellen geslatlet es, auf einfache Weise Meβfehler bei Kontaminationsme βgeräten, die durch das Material der Unterlage, auf dem sich die aktive Substanz befindet, und durch die Dicke der akliven Schicht hervorgerufen tcerden, zu erfassen oder zu eliminieren.     

Temperature Sensitivity Control and Mechanical Stress Effect of Boron-Doped Long-Period Fiber Gratings

We will present in this work the quantitative analysis of the relationship between the doping concentrations of GeO 2 and B 2 O 3 in the core and cladding regions and the temperature sensitivity of the resonance wavelength shift in long-period fiber gratings (LPFGs). Based on this analysis, the temperature sensitivity was suppressed and enhanced to 0.002 nm/C and 0.28 nm/C, respectively. We will also discuss the effect of the residual mechanical stress on the optical and mechanical properties of LPFGs. In particular, we will present the measurement results of the dependence of the refractive index change and mechanical strength on the residual mechanical stress in the boron-doped fibers with depressed clad and matched clad.     

On the formation of a phase with tenfold symmetry in amorphous Ni–Zr alloys

The magnetic anisotropy energy (MAE) of 3d transition-metal wires, stripes, and films is calculated self-consistently as a function of stripe width and film thickness. The magnetization-reorientation transitions in stripes are determined along the crossover from the mono-atomic one-dimensional chain to the two-dimensional monolayer. It is shown that the MAE oscillates as a function of stripe width and depends strongly on the considered transition metal. The reorientation transitions in Co films deposited on a highly polarizable substrate such as Pd are discussed. A local analysis of the layer-resolved MAEs provides new insights into the off-plane magnetization observed in Pd-capped Co films on Pd(111). The interfaces responsible for the stability of the off-plane easy axis are characterized microscopically. An unexpected internal magnetic structure of the Co–Pd interfaces is revealed in which the magnetic moments and spin–orbit interactions at Pd atoms play a crucial role. The nature of the reorientation transition from perpendicular to in-plane magnetization with increasing film thickness is studied by means of full-vectorial calculations. The existence of a spin-canted phase at intermediate film thickness is demonstrated.     

用遗传算法研究Con(n=3-60)团簇的结构特性

我们采用半经验的Gupta多体势结合遗传算法,系统地研究了Con(n=3-60)团簇的几何结构特性.我们发现在钴团簇的生长中存在一个类fcc构型与类Ih构型之间的竞争,从n=39开始,钴团簇呈现出明显的Ih生长模式.Con(n=3-60)团簇的幻数为13,19,23,38,55,结合钴团簇的平均最近邻原子间距和平均配位数,分析了钴团簇幻数序列存在的原因.我们发现团簇内部原子具有增强团簇对称性和加强团簇稳定性的显著作用.     

Microscopic origin of asymmetric magnetization reversal of Co/Pt multilayers with perpendicular magnetic anisotropy

We have comprehensively investigated asymmetric magnetization reversal behaviors of (x-Å Co/7.7 Å Pt)₅ multilayers (x = 3.1 and 4.7) with perpendicular magnetic anisotropy. Our direct observation of magnetic domain structures by means of magneto-optical microscopy reveals that the asymmetry arises both from nucleation and wall-motion processes. An asymmetric nucleation behavior is observed, which could be originated from the preexisting non-reversed domains which might have a reproducible or random spatial distribution, controllable by tuning the field profile. An asymmetric wall-motion behavior stemming from asymmetric stripe domain evolution is also observed.     

[Co2（H2O）6（bpdc）2]·3.75H2O的原位合成、晶体结构及电化学性质研究

室温下,Co（NO3）2·6H2O与1,10–邻菲罗啉–5,6–二酮（pdon）的水溶液进行原位反应,得到一维链状配合物晶体{[Co2（H2O）6（bpdc）2]·3.75H2O}n（bpdc=2,2＇–联吡啶–3,3＇–二羧酸）.单晶X–射线衍射分析表明：该晶体属于单斜晶系,P21/c空间群,晶胞参数为：a=18.001（4）A,b=11.336（2）,c=18.192（4）A,β=118.88（3）°,V=32501（2）A3,Dcalc=1.578 g·cm^-3.每个钴（Ⅱ）离子与周围2个氮原子和4个氧原子配位,形成扭曲的八面体构型,并通过bpdc连接形成沿b轴无限延伸的手性螺旋链.在整个晶体结构中,这些链以准一维堆积方式排列,相互之间存在广泛的氢键作用.同时,电化学分析表明：在磷酸盐缓冲溶液（pH=7.0）中,该配合物在-0.6～0.6V电压范围内具有电化学活性,电极反应为准可逆的Co（Ⅲ）与Co（Ⅱ）的氧化还原过程.     

Sm_2Co_（17） magnet blocks for the in-vacuum undulators （IVU20） at the SSRF

The design and development status of Sm₂Co₁₇ magnet blocks for two in-vacuum undulators (IVU20) at the SSRF with the same hybrid design has been described. By the technological improvement of some processes and comparison with the experimental Sm₂Co₁₇ magnet blocks for the IVU25A, magnetic properties such as the intrinsic coercive force H_ci and the average magnetic moment M are increased, the bend point magnetic field H_k value and pass rate are significantly increased, and the magnetic field uniformity of the magnet blocks are significantly improved. The basic developmental method of high uniformity Sm₂Co₁₇ magnet blocks for IVU20 is presented. The magnetic field qualities of the magnet blocks, including the magnetic property, the magnetic moment distribution, the magnetization deviation angle and the magnetic field uniformity, basically satisfy the specifications of the two IVU20 in-vacuum undulators.     

Interrelation between inhomogeneity and cyclability in O3‐NaFe1/2Co1/2O2

O3‐NaFe_1/2Co_1/2O₂ shows initial capacity of 160 mAh/g and an average operating voltage of 3.1 V (vs. Na) with good cyclability, and is a promising candidate of the cathode materials for sodium‐ion secondary batteries (SIBs). Here, we found that the cyclability of the slowly‐cooled sample is much worse than that of quenched one, even though the former sample keeps the O3‐type structure. The energy dispersive X‐ray spectroscopy (EDX) images suggest that the slow‐cooled sample (Na_x Fe_1–yCo_y O₂) is inhomogeneous in the Fe concentration (1 – y), perhaps triggered by the Na deficiency (1 – x). We ascribed the poor cyclability in the slowly‐cooled sample to the concentration inhomogeneity (Δy). The Δy is further responsible for the fluctuation of the lattice constants (a and c), as revealed by the Williamson–Hall plot. (© 2016 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)     

KNSBN：Co晶体自泵浦位相共轭特性的研究

本文报道在两块不同尺寸的KNSBN:Co晶体中实现了自泵浦位相共轭输出,通过实验验证了位相共轭反射率与入射角、入射位置以及波长有关,并给出各自的实验曲线.保持激光器工作波长为514.5nm不变,在大块晶体中可得到高达73.0%的位相共轭反射率.文章还给出共轭光的形成时间随系统光强变化关系的实验曲线,并指出自泵浦形成时透射光强和晶体表面反射光强的时间变化特性,解释了自泵浦形成的阈值特性.