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41.
《Current Applied Physics》2020,20(7):895-898
A single-walled carbon nanotube (SWCNT) with conjugated polymer molecules is analyzed via optical spectroscopy. The presence of strongly localized excitonic states in the SWCNT is confirmed using time-integrated photoluminescence (PL). The PL spectrum exhibits extremely narrow width (~0.8 meV) which is attributed to the strong confinement of the states by polymer molecules. In addition, I observed that the excited states are gradually filled as a function of the excitation power, which supports the localized excitonic behavior. Only the ground excitonic state is observed at low excitation powers, but three additional PL peaks appear as the excitation power is increased. Especially, the power-dependent PL spectrum shows a blueshift and increased width, which can be elucidated in terms of quantum confined stark effect and the screening of induced electric fields. Overall, I demonstrate that the presence of polymer molecules induces several localized states in a single SWCNT. 相似文献
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通过分析DAR成色剂的结构和作用机理,讨论了其结构与照相性能之间的关系.DAR成色剂的结构可表示为:Cp—L—A,其中Cp代表成色剂母体,A代表促进显影的功能基团即增强基团,L代表连接基团同时也有吸附功能即吸附基团.本文指出:当吸附基团和增强基团相同时,母体对照相性能影响不大;当母体及增强基团相同时,吸附基团的吸附性越强,照相性能越好;当母体及吸附基团相同时,增强基团的感染显影作用越强,照相性能越好. 相似文献
46.
Dye-sensitized solar cells (DSSCs) are the most promising alternatives to traditional fossil energy because of their advantages of low production cost, facile structure, relatively low environmental impact, relatively high photoelectronic absorption efficiency, and overall high efficiency. In addition, several studies on sensitizers as vital components have been conducted over the last three decades. Compared to metal dyes, metal-free organic dyes have been considered as promising candidates because of their simple fabrication, multiple structures, high molar absorption coefficients, easily tunable properties, and environmental friendliness. In this study, we systematically investigated the optoelectronic properties of six metal-free organic donor-acceptor dyes (RD1–6) derived from the known dye R6 by using the density functional theory (DFT) and time-dependent DFT methods. Cell performance parameters were discussed, including the geometrical and electronic structures, absorption spectrum, adsorption energy, light harvesting efficiency (LHE) curve, predictive short circuit current density (JscPred.), predictive open circuit voltage (VocPred.), and theoretical power conversion efficiency (PCE). Results revealed that all the designed dyes exhibited high theoretical PCE. In particular, dyes RD1, 2, and 4–6 showed greater conjugations, and dyes RD1–3 had smaller energy gaps than those of the reference dye. In addition, dyes RD1–3, 5, and 6 exhibited better light harvesting capacities that covered the entire visible region and extended to the near-infrared region with obviously red-shift maximum absorption wavelengths (λmax), wider LHE curves, and higher JscPred. as compared to the reference dye. It was critical that dyes RD1 and 2 not only have greater conjugations and narrow band gaps but also good light harvesting capacities with more than 56-nm red-shift maximum absorption wavelengths and broadened LHE curves than those of the reference dye. Notably, mainly because of an average increment of 12.0% of JscPred., a remarkable increment of the theoretical power conversion efficiency was observed from 12.6% for dye R6 to 14.1% for dyes RD1 and 2. Thus, dyes RD1 and 2 exhibited superior cell performances and could be promising sensitizer candidates for highly efficient DSSCs. These results could be used to guide effective synthetic efforts in the discovery of efficient metal-free organic dye sensitizers in DSSCs. 相似文献
48.
In this paper, for a finite group, we investigate to what extent its directed (resp. undirected) reduced power graph determines its directed power graph (resp. reduced power graph). Moreover, we investigate the determination of the orders of the elements of a finite group from its directed (resp. undirected) reduced power graph. Consequently, we show that some classes of finite groups are recognizable from their undirected reduced power graphs. Also, we study the relationship between the isomorphism classes of groups corresponding to the equivalence relations induced by the isomorphism of each of these graphs on the set of all finite groups. 相似文献
49.
超导故障限流器的研究现状及其应用 总被引:1,自引:0,他引:1
超导故障限流器(Superconducting Fault Current Limiter,SFCL)是利用超导体的基本特性,有效限制电力系统故障短路电流,提高电网安全性和稳定性的一种新型电力设备。文中在综合大量文献的基础上,对超导故障限流器进行了一种较为系统的分类。基于该种分类,结合目前国内外的研究现状,就电阻型、磁屏蔽型、饱和铁芯电抗器型、桥路型SFCL的工作原理作了详细的分析介绍,还给出了它们在电力系统中的安装位置。最后,对超导故障限流器的研究中存在的问题及其发展趋势做了说明。 相似文献
50.
介绍了一种L波段50W功率放大器的研制情况,采用功率合成技术获得了61W的输出功率,放大器增益大于40dB。给出了1W功放、10W功放和八路功率分配器的设计分析过程。 相似文献