全文获取类型
收费全文 | 2460篇 |
免费 | 287篇 |
国内免费 | 152篇 |
专业分类
化学 | 727篇 |
晶体学 | 24篇 |
力学 | 312篇 |
综合类 | 97篇 |
数学 | 446篇 |
物理学 | 1293篇 |
出版年
2024年 | 4篇 |
2023年 | 20篇 |
2022年 | 53篇 |
2021年 | 56篇 |
2020年 | 54篇 |
2019年 | 37篇 |
2018年 | 51篇 |
2017年 | 77篇 |
2016年 | 101篇 |
2015年 | 71篇 |
2014年 | 112篇 |
2013年 | 153篇 |
2012年 | 95篇 |
2011年 | 136篇 |
2010年 | 123篇 |
2009年 | 150篇 |
2008年 | 164篇 |
2007年 | 178篇 |
2006年 | 187篇 |
2005年 | 166篇 |
2004年 | 129篇 |
2003年 | 114篇 |
2002年 | 94篇 |
2001年 | 80篇 |
2000年 | 68篇 |
1999年 | 58篇 |
1998年 | 57篇 |
1997年 | 47篇 |
1996年 | 43篇 |
1995年 | 33篇 |
1994年 | 34篇 |
1993年 | 23篇 |
1992年 | 19篇 |
1991年 | 25篇 |
1990年 | 20篇 |
1989年 | 15篇 |
1988年 | 14篇 |
1987年 | 7篇 |
1986年 | 10篇 |
1985年 | 8篇 |
1984年 | 3篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1977年 | 2篇 |
1969年 | 1篇 |
1959年 | 2篇 |
排序方式: 共有2899条查询结果,搜索用时 281 毫秒
141.
We have calculated the ground-state energy of the symmetric quantum-dot pattern by the ab initio calculation method, i.e. unrestricted Hartree-Fock-Roothaan (UHFR) method based on the Gaussian basis, and studied their electric capacitance spectra, assuming each quantum dot of quantum-dot pattern to be confined in a three-dimensional spherical potential well of finite depth. For the systems in question, our results show that our method and theoretical model not only give the electric capacitance peaks similar to s-shell and p-shell atom-like quantum dot, but also show some new fine-structure of electric capacitance in the symmetric quantum-dot pattern system. This method might be a feasible tool to study few-electron problems on the symmetric quantum-dot pattern system. 相似文献
142.
Ajoy G Ramakrishna J Bahçeli S Klinowski J 《Solid state nuclear magnetic resonance》2000,16(4):63-338
We derive a complete analytical solution for the powder magic angle spinning (MAS) nuclear magnetic resonance (NMR) lineshape in the presence of second-order quadrupole interaction, considering a radiofrequency (rf) pulse of finite width, a finite MAS frequency, and a non-zero asymmetry parameter. Ix is calculated using two approaches. The first applies time-dependent perturbation theory in the presence of the rf pulse and stationary perturbation theory (SPT) in its absence. The second is based on the Magnus expansion of the density matrix in the interaction representation during the pulse and SPT in its absence. We solve the problem in the laboratory frame using the properties of the Fourier transform and spin operators. Diagonalisation is not required. Both approaches agree well with each other under all conditions and also with the transition probability approach for the central transition. The Magnus expansion exists at all times and the effect of the non-secular terms is negligible. We describe an analytical method of averaging Ix over the Euler angles and simulate the 11B MAS NMR lineshapes for crystalline and vitreous B2O3. A critical analysis is given of all earlier calculations of the MAS NMR lineshape. 相似文献
143.
144.
在过去二十年里,对中等尺寸硅团簇的研究一直十分活跃.为阐明低能团簇从中等到大尺寸的生长行为,我们对SiN团簇在21≤N≤50,和N=60的结构和相对稳定性进行论述.对Si21-Si29,除Si27外最低能量结构是扁长形.对N≥30,SiN团簇倾向于形成填充富勒烯结构.随着团簇尺寸的增大(N≥41),内部开始出现四面体结构,可视为金刚石晶格结构形成的初始阶段.当团簇尺寸达到N=60时,其已偏离小团簇的类分子行为,但向块体结构的转变还没完成.中等尺寸硅团簇的填充富勒烯结构可以被看作是从类分子向块体过渡的中间阶段. 相似文献
145.
146.
T. Saito T. Nakano H. Hoshizuki K. Sakai Y. Tatematsu S. Mitsudo I. Ogawa T. Idehara V. E. Zapevalov 《International Journal of Infrared and Millimeter Waves》2007,28(12):1063-1078
A 300 GHz CW gyrotron FU CW I has been developed and installed in the Research Center for Development of Far-Infrared Region,
University of Fukui as a power source of a high frequency material processing system. Its performance was tested and the maximum
power of 1.75 kW / CW has been attained at the beam voltage of 15 kV and the beam current of 1A. The maximum window power
efficiency of 15.5% has been obtained at the cathode voltage slightly lower than 15 kV. This gyrotron is designed to deliver
a Gaussian beam after mode conversion from the oscillation mode TE22,8 in the cavity with a complex of an internal radiator and beam shaping mirrors. The detailed measurement with an infrared
camera has confirmed that a Gaussian beam is radiated when the magnetic field strength B
c
at the cavity is adjusted at a proper value. However, within a range of B
c
, the output power is emerged into multiple directions, which suggests simultaneous oscillation of competing cavity modes. 相似文献
147.
This paper introduces a relative structural complexity measure for the characterization of disordered surfaces. Numerical solutions of 2d+1 KPZ equation and scanning force microscopy (SFM) patterns of porous silicon samples are analyzed using this methodology. The results and phenomenological interpretation indicate that the proposed measure is efficient for quantitatively characterize the structural complexity of disordered surfaces (and interfaces) observed and/or simulated in nano, micro and ordinary scales. 相似文献
148.
Rajesh Das 《Applied Surface Science》2007,253(14):6068-6073
Sn doped In2O3 films are deposited by rf-magnetron sputtering at 300 °C under Ar, Ar + O2 and Ar + H2 gas ambients. For the film prepared under argon ambient, electrical resistivity 6.5 × 10−4 Ω cm and 95% optical transmission in the visible region have been achieved optimizing the power and chamber pressure during the film deposition. X-ray diffraction spectra of the ITO film reveal (2 2 2) and (4 0 0) crystallographic planes of In2O3. With the introduction of 1.33% oxygen in argon, (2 2 2) peak of In2O3 decreases and resistivity increases for the deposited film. With further increase of oxygen in the sputtering gas mixture crystallinity in the film deteriorates and both the peaks disappeared. On the other hand, when 1.33% hydrogen is mixed with argon, the resistivity of the deposited film decreases to 5.5 × 10−4 Ω cm and the crystallinity remains almost unchanged. In case of reactive sputtering, the deposition rate is lower compared to that in case of non-reactive sputtering. HRTEM and first Fourier patterns show the highly crystalline structure of the samples deposited under Ar and Ar + H2 ambients. Crystallinity of the film becomes lower with the introduction of oxygen in argon but refractive index increases from 1.86 to 1.9. The surface morphology of the ITO films have been studied by high resolution scanning electron microscopy. 相似文献
149.
In this paper we consider a class of scalar integral equations with a form of space-dependent delay. These nonlocal models arise naturally when modelling neural tissue with active axons and passive dendrites. Such systems are known to support a dynamic (oscillatory) Turing instability of the homogeneous steady state. In this paper we develop a weakly nonlinear analysis of the travelling and standing waves that form beyond the point of instability. The appropriate amplitude equations are found to be the coupled mean-field Ginzburg-Landau equations describing a Turing-Hopf bifurcation with modulation group velocity of O(1). Importantly we are able to obtain the coefficients of terms in the amplitude equations in terms of integral transforms of the spatio-temporal kernels defining the neural field equation of interest. Indeed our results cover not only models with axonal or dendritic delays but also those which are described by a more general distribution of delayed spatio-temporal interactions. We illustrate the predictive power of this form of analysis with comparison against direct numerical simulations, paying particular attention to the competition between standing and travelling waves and the onset of Benjamin-Feir instabilities. 相似文献
150.
Within the methodology [M. Khazaei, A.A. Farajian, Y. Kawazoe, Phys. Rev. Lett. 95 (2005) 177602] based on first-principles electronic structure calculations, the effects of Cs treatment on current emissions and emission patterns of capped carbon nanotubes are considered at low deposition densities when the nanotubes are under an electric field 0.2 V/Å. The results show that the current emission from the cap with one adsorbed Cs is 3.4 times larger than the cap without any Cs. It is 9.6 times larger in the cap with two adsorbed Cs atoms. After Cs deposition the emission patterns become asymmetric (current emission from the carbon atoms located at the topmost pentagon ring close to Cs atoms is larger than the other atomic sites). There are very few localized states on Cs atoms. Hence, although the tunneling probability of electron emission from Cs atoms is significant, there is no current from Cs atoms. In addition, the effect of Cs on work function reduction of nanotubes is explained in terms of Cs deposition densities and the surface dipole moments. 相似文献