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31.
Pallab Banerji 《Applied Surface Science》2007,253(11):5129-5132
Atomic scale properties of thin porous silicon (PSi) layers, characterized by the formation of positronium, are investigated using positron annihilation lifetime spectroscopy in the temperature range 20-300 K under 10−7 Torr vacuum. The longest orthopositronium as well as the shortest parapositronium components are found to have quite low intensities in the thin layer at room temperature. It is also found that at temperatures ≤240 K, these two components do not show up in the spectrum. The reason for this absence of the longest lifetime component is suggested. 相似文献
32.
Nidhi Sinha 《Molecular physics》2013,111(18):2527-2534
ABSTRACTThis work aims at the calculation of various inelastic cross sections for three pentane isomers, namely normal pentane, isopentane and neopentane. The direct ionisation, positronium formation, total ionisation and total inelastic cross section are reported for these targets using modified spherical complex optical potential (mSCOP) and complex scattering potential-ionisation contribution (CSP-ic) method. The cross sections are computed for a wide energy range from their respective thresholds to 5?keV. We have also attempted to probe the isomeric effect in the inelastic scattering of positrons from the pentane isomers. The cross sections for the three isomers were found to overlap for the entire comparative energy range except at the peak region. Hence, in general no appreciable isomeric effect was beheld for the pentane isomers. 相似文献
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34.
Mutsumi Tashiro Pradeep K. Pujari Shu Seki Yoshihide Honda Shigehiro Nishijima Seiichi Tagawa 《Radiation Physics and Chemistry》2000,58(5-6):587-592
Temperature dependence of positron annihilation lifetime spectra of polysilanes such as, poly(methyl-n-propylsilane) (PMPrS) and poly(di-n-hexylsilane) (PDHS) has been investigated. The τ3 in PMPrS is seen to increase monotonically around the solid–liquid transition temperature. The transition temperature and free volume are observed to depend on the molecular weight and/or packing of the backbones. For PDHS, a sharp change in τ3 and I3 is seen at the solid–solid transition temperature. Free volume radius probability density functions, above and below the transition temperature, are presented in PMPrS and PDHS. Positron studies are complimented by conventional thermal analysis studies. 相似文献
35.
High purity n-type silicon single crystal with resistivity in the order of 4000 Ω cm has been irradiated with high-energy oxygen ions at room temperature up to a fluence of 5E15 ions/cm2. The energy of the beam was varied from 3 to 140 MeV using a rotating degrader to achieve a depthwise near-uniform implantation profile. Radiation induced defects and their dynamics have been studied using positron annihilation spectroscopy along with isochronal annealing up to 700 °C in steps of 50 °C for 30 min. After annealing the sample at 200 °C for 30 min, formation of silicon tetravacancies has been noticed. The formation of the tetravacancies was found to be due to agglomeration of divacancies present in the irradiated sample. An experimentally obtained positron lifetime value of 338±10 ps has been reported for silicon tetravacancies, which has a very close agreement with the value obtained from recent theoretical calculations. The tetravacancies were found to dissociate into trivacancy clusters upon further annealing. The trivacancies thus obtained were observed to agglomerate beyond 400 °C to form larger defect clusters. Finally, all the defects were found to anneal out after annealing the sample at 650 °C. 相似文献
36.
Bangdao ChenHongzhong Liu Hongtao WangFan Fan Li WangYucheng Ding Bingheng Lu 《Applied Surface Science》2011,257(21):9125-9128
Significant emission current enhancement has been achieved for surface conduction electron emitter, due to the special three-dimensional nanocrack structure fabricated by the thermal shock process. The three-dimensional configuration strongly changed the electric field distribution and controlled the emission electron trajectory. Thermal shock treatment was also used to increase the edge roughness of the nanocrack and thereby dramatically improved the field emission characteristics. Stable and uniform electron emission was observed with turn-on voltage of 150 V. The surface conduction current of 400 μA for 6 cells was obtained with the detector voltage of 1 kV and the gap voltage of 170 V. 相似文献
37.
38.
H. Murakami 《Radiation Physics and Chemistry》2000,58(5-6):531-533
Measurement of positron lifetime was carried out on polyvinylidene fluoride as a function of temperature ranging from 193 to 293 K. The local molecular motion, the cooperative motion of long chain, and the thermal expansion are discussed based on the change in free volume concluded with the use of positron lifetime. The different temperature dependence of motions is suggested for an amorphous area constrained by crystalline regions and a free amorphous area. 相似文献
39.
采用新型核素64Cu标记了含丙烯胺肟[Pn AO(3,3,9,9-Tetramethyl-4,8-diazaundecane-2,10-dione Dioxime)]结构的硝基咪唑类乏氧显像剂Pn AO-1-(2-nitroimidazole)[BMS181321],通过优化反应条件,于室温下反应10 min后即得到高放化纯度和高比活度的标记化合物64Cu-BMS181321.目标产物经放射性高效液相色谱检测验证和体外稳定性实验确认后,通过尾静脉注射到人源胰腺癌(PANC-1细胞系)裸鼠体内,分别于注射显像剂4和8 h后进行小动物正电子发射断层扫描显像(Micro-PET).结果表明,4 h左右肿瘤乏氧区域有良好的放射性浓聚.64Cu-BMS181321的合成及其分子显像研究开创了64Cu标记硝基咪唑类乏氧显像剂进行乏氧显像的先例,经进一步药物临床实验评价后,64Cu-BMS181321有望成为具有良好前景的PET乏氧显像药物. 相似文献
40.
A general overview of the development of the uses of light-emitting diodes in analytical instrumentation is given. Fundamental aspects of light-emitting diodes, as far as relevant for this usage, are covered in the first part. The measurement of light intensity is also discussed, as this is an essential part of any device based on light-emitting diodes as well. In the second part, applications are discussed, which cover liquid and gas-phase absorbance measurements, flow-through detectors for chromatography and capillary electrophoresis, sensors, as well as some less often reported methods such as photoacoustic spectroscopy. 相似文献