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71.
Adsorption of anions to zirconium(IV) and titanium(IV) chemically immobilized on gel-phase 总被引:1,自引:0,他引:1
Adsorption behaviors of 25 anions to zirconium(IV) and titanium(IV) chemically immobilized on a gel-phase were studied by ion chromatography and by batch adsorption experiments. The affinities of Zr(IV) to iminodiacetate as an anchoring group and to anions as a sample are much stronger than those of Ti(IV). On a Zr(IV) column, fourteen anions showed no retention, four anions showed pH-dependent retention in a low pH region, and seven anions were irreversibly adsorbed at pH <7. In the last group, fluoride was adsorbed both by the ligand exchange mechanism and the addition mechanism, while phosphate, arsenate and selenite were only by the ligand exchange mechanism. The structures of the adsorbed species are discussed. 相似文献
72.
Treatment of magnesium alkylidene carbenoids, generated from 1-chlorovinyl p-tolyl sulfoxides with isopropylmagnesium chloride at −78 °C in toluene, with 2-lithiothiophenes gave 2-alkenylated thiophenes in good to high yields. The intermediate of this reaction was found to be an alkenylmagnesium, which could be trapped with iodoalkanes and ethyl chloroformate. This procedure offers a novel and efficient one-pot synthesis of thiophenes having a disubstituted or a trisubstituted olefin at the 2-position from thiophenes in good yields. 相似文献
73.
An approximate kinetic‐energy functional of the generalized gradient approximation form was derived following the “conjointness conjecture” of Lee, Lee, and Parr. The functional shares the analytical form of its gradient dependency with the exchange‐energy functionals of Becke and Perdew, Burke, and Ernzerhof. The two free parameters of this functional were determined using the exact values of the kinetic energy of He and Xe atoms. A set of 12 closed‐shell atoms was used to test the accuracy of the proposed functional and more than 30 others taken from the literature. It is shown that the conjointness conjecture leads to a very good class of kinetic‐energy functionals. Moreover, the functional developed in this work is shown to be one of the most accurate despite its simple analytical form. © 2002 Wiley Periodicals, Inc. Int J Quantum Chem, 2002 相似文献
74.
W. Schwieger U. Brenn P. Grabner H. Utschick 《Journal of Thermal Analysis and Calorimetry》1998,52(1):21-32
Aluminium-free layered silicates of the metal silicate hydrate type (M-SH) comprise an interesting supplement to the well-known zeolite-like porous materials. Their specific properties allow these materials to be used as catalysts, adsorbents and ion-exchangers. Comparative X-ray diffraction and thermoanalytical investigations (TG and DSC) have shown that the thermoanalytical methods are useful to follow the process of structure formation of ilerite. The interlayer cations influence the properties of the different ilerites. In particular, the hydration behaviour of ilerite is affected. Thus, H+- and DTMA+-ilerite are stable up to temperatures of about 800°C, while the as-synthesized Na-form loses water irreversibly at about 150°C, is dehydroxylated, and is then desomposed structurally at about 400°C. The course of the dehydration exhibits significant differences for the various cation forms.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
75.
Proton NMR was used to study the complexation reaction between silver ion and hexathia-18-crown-6 in a number of binary mixed solvents of dimethyl sulfoxide with acetonitrile and methanol. Formation constants for the resulting 1:1 complexes in different solvent mixtures were determined by computer fitting of the chemical shift-mole ratio data. The influence of solvent composition on the stability of the resulting complex is discussed. The exchange kinetics of Ag+-hexathia-18-crown-6 in 70-30 wt.% dimethyl sulfoxide-acetonitrile and 75-25 wt.% dimethyl sulfoxide-methanol were studied by proton NMR line-shape analysis. In both solvent mixtures, the exchange of thiacrown ether between the free and complexed sites was found to proceed via a dissociative pathway. The exchange rates and the activation parameters E
a, H
, S, and G for the ligand exchange were determined and the influence of solvent properties on these parameters discussed. 相似文献
76.
77.
Sánchez-Machado DI López-Cervantes J López-Hernández J Paseiro-Losada P Simal-Lozano J 《Biomedical chromatography : BMC》2004,18(2):90-97
A high-performance liquid chromatographic (HPLC) method is described for determination of the ratio of beta-d-mannuronic acid to alpha-l-guluronic acid (M/G ratio) in dietary fibre of edible seaweeds. Total dietary fibre (TDF) content was determined gravimetrically. The TDF fraction was hydrolysed with 12 m and 1 m H(2)SO(4), then neutralized with AG 4 x 4 resin. The uronic acids were separated in a Tracer Extrasil SAX 5 micro m column (25 cm x 4 mm) at 35 degrees C, with 2 mm KH(2)PO(4) containing 5% methanol as mobile phase at a fl ow rate of 1.5 mL/min. The detection wavelength was UV 210 nm. The chromatographic identifications of beta-d-mannuronic acid and alpha-l-guluronic acid were confirmed by liquid chromatography-mass spectrometry (LC-MS). The method precision was 1.4% for beta-d-mannuronic acid and 3.5% for alpha-l-guluronic acid. The method was used to determine M/G ratio in canned seaweeds (Saccorhiza polyschides and Himanthalia elongata) and in dried seaweeds (H. elongata, Laminaria ochroleuca, Undaria pinnatifida, Palmaria sp. and Porphyra sp.). 相似文献
78.
Ti4+修饰阳离子交换树脂催化制备环已烯 总被引:5,自引:0,他引:5
在Ti^4 修饰阳离子交换树脂催化剂上进行了环己醇脱水制备环己烯的反应,考察了催化剂吸附毗啶的FT-IR,证实了该催化剂表面具有Bronsted酸和Lewis酸性住是催化环己烯脱水反应的物质基础,实验结果表明:修饰树脂具有较高的热稳定性,Ti^4 交换容量对阳离子交换树脂的催化活性存在着明显的影响,催化剂对环己醇脱水制环己烯反应的活性高,并得到该反应的优化条件如下:环己醇40g,催化剂5g,反应温度175℃,反应时问60min,在此条件下,环己烯的产率达89%。 相似文献
79.
Electropolymerization of 3,3′-diaminobenzidine on a gold surface gave an adherent, stable film of poly(3,3′-diaminobenzidine) (PDAB). This polymer film retained the complexational functionalities of its monomer, demonstrating preconcentration abilities for several ions, including Se(IV) and Te(IV). In particular, in this work, continuous flow and flow injection methods were developed for the sensitive and selective determination of Te(IV). The optimized method for the continuous flow mode had a detection limit of 5.6×10−9 mol l−1 for 10 min preconcentration. Typical relative standard deviations for six consecutive determinations were 1.82 and 2.56% for Te(IV) concentrations of 1.0×10−6 and 5.0×10−8 mol l−1, respectively (10 min preconcentration). The method was applied to the determination of Te(IV) in real samples. 相似文献
80.
用水合五氧化二锑分离放射性母子体的研究─—一个新的~(201)Pb—~(201)T1发生器的制备 总被引:1,自引:0,他引:1
本文研究了无机离子交换剂—水合五氧化二锑(Sb2O5·nH2O)的制备,并用它分离了放射性母子体,制备了一个新的201Pb—201Tl放射性发生器。结果表明,末发生器具有高效、快速、简便的特点,此外还讨论了离子交换反应的机理。 相似文献