全文获取类型
收费全文 | 1819篇 |
免费 | 85篇 |
国内免费 | 208篇 |
专业分类
化学 | 413篇 |
晶体学 | 6篇 |
力学 | 48篇 |
综合类 | 25篇 |
数学 | 467篇 |
物理学 | 1153篇 |
出版年
2023年 | 37篇 |
2022年 | 18篇 |
2021年 | 18篇 |
2020年 | 39篇 |
2019年 | 47篇 |
2018年 | 31篇 |
2017年 | 43篇 |
2016年 | 46篇 |
2015年 | 33篇 |
2014年 | 112篇 |
2013年 | 132篇 |
2012年 | 64篇 |
2011年 | 149篇 |
2010年 | 105篇 |
2009年 | 109篇 |
2008年 | 137篇 |
2007年 | 131篇 |
2006年 | 139篇 |
2005年 | 108篇 |
2004年 | 76篇 |
2003年 | 79篇 |
2002年 | 78篇 |
2001年 | 72篇 |
2000年 | 51篇 |
1999年 | 49篇 |
1998年 | 47篇 |
1997年 | 28篇 |
1996年 | 18篇 |
1995年 | 18篇 |
1994年 | 16篇 |
1993年 | 9篇 |
1992年 | 16篇 |
1991年 | 9篇 |
1990年 | 6篇 |
1989年 | 10篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1969年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有2112条查询结果,搜索用时 15 毫秒
21.
消色差谱相位延迟器的光谱特性测试研究 总被引:6,自引:1,他引:5
本文应用归一化偏振调制原理建立的测试系统,对常规菲涅耳菱体,改进型菲涅菱体,斜入射型以及直角棱镜组合型的消色差相位延迟的光谱特性进行了测试研究,得到了各延迟器的消色差特性曲线,并对测试结果进行了分析。结果表明改进型菲涅耳菱体以及直色棱镜组合型型消色差相位延迟器,是目前较理想的实用型消色相位延迟器。 相似文献
22.
本文对Brauer第24问题[1]作了推广.利用Dade关于循环块的理论得到如下结果:设G是有限群,P是G的循环Sylowp子群.设|P|=pa,a为正整数.令Pi为P中唯一的pi阶子群,1ia.则|Cl(G)|=|Cl(NG(Pi))|的充分必要条件为PiG. 相似文献
23.
线圈型全光纤偏振器的研究 总被引:2,自引:0,他引:2
本文采用等效电流法对线圈型全光纤偏振器进行了分析计算.对应于保偏光纤中两正交传输基模的消光比,提出了一种分析保偏光纤弯曲损耗的新方法,这种方法基于将保偏光纤两个不同偏振模式分别等效为两个普通圆光纤的基模,等效参数通过测量不同偏振模式的模场半径来确定.实验证明这种理论计算方法与实验结果一致.最终,我们研制出的线圈型光纤偏振器在1.31μm工作波长下,实测消光比达30dB以上,工作偏振模式插入损耗≤3dB. 相似文献
24.
用浸渍法制备了掺杂不同质量分数的La0.8Sr0.2Ga0.8Mg0.15Co0.05O3-δ (LSGMC5)粉末的Ni8-Fe2-LSGMC5复合阳极, 并采用交流阻抗和直流极化技术考察了以氢气和二甲醚为燃气时该复合阳极的电化学性能及相应电池的功率输出特性. 结果表明, 在电极中掺入LSGMC5 粉末, 能显著地改善电极的形貌和电极/电解质界面结构, 减小欧姆电阻和极化电阻. 电极中LSGMC5 粉末含量对于氢气及二甲醚电化学氧化性能的影响显著不同. 以二甲醚为燃气时, 电极极化电阻随LSGMC5 粉末含量的增加而减小, 其中LSGMC5 掺杂量为30%的复合阳极具有最高的电化学性能, 相应电池在1073、1023、973 K 时的输出功率分别为1.00、0.61、0.40 W·cm-2; 以氢气为燃气时, LSGMC5 掺杂量为20%的复合阳极具有最好的电化学性能, 随着LSGMC5 掺杂量的进一步增加, 电极极化电阻显著增大. 相似文献
25.
26.
在甲醇和DMF溶剂里,以Schiff碱水杨醛缩氨基硫脲(简写为HL)和六水二氯化钴合成了配合物[CoHL2].H2O.DMF.在配合物[CoHL2]中,钴(Ⅱ)原子具有扭曲的N2O2S2八面体配位构型,晶体通过分子间氢键作用形成二维的无限网状结构.红外光谱表明,配体在形成配合物后,νS=O,νC=O和νC=N红移.荧光光谱表明,配合物金属对配体n-π*激发引起的荧光发射峰有较大的影响. 相似文献
27.
Ginting Suka IrwanShin-ichi Kuroda Hitoshi Kubota Takashi Kondo 《European Polymer Journal》2002,38(6):1145-1150
The effect of monomer concentration on photografting of methacrylic acid (MAA) onto linear low-density polyethylene (PE) film (thickness=30 μm) was investigated at 60 °C in water solvent together with the location of MAA-grafted chains. Xanthone was used as a photoinitiator which was coated on the film sample earlier. The higher percentage of grafting and graft efficiency were afforded for the system with the higher monomer concentration. The resultant MAA-grafted films were subjected to measurements of pH-responsive character and ability to adsorb cupric ion in order to understand the characteristics of function introduced. The grafted samples exhibited the pH-responsive character, where they shrank and swelled in acidic and alkaline media, respectively. The pH-responsive character of the grafted films was higher for the samples prepared in the system with a higher monomer concentration. Moreover, the grafted samples exhibited the ability to adsorb cupric ion, and the ability was reduced when the sample was prepared in the system with a higher monomer concentration. The different extents of the pH-responsive character and ability to adsorb cupric ion of the resulting grafted PE films were discussed in terms of location of grafted chains in the film substrate, which was determined by a scanning electron microscope and an attenuated total reflection infrared spectroscopy. 相似文献
28.
The interaction energy of a molecule M with a point-like charge q can be partitioned into simpler contributions, two of which can be expressed in terms of the charge distribution M of the sole M. The first term, qV(r), represents the interaction of q with the undistorted charge
M
0
of M while the second q
2
P(r) gives the additional contributions due to the polarization of
M
0
under the influence of the charge q placed at the point r. In this paper we investigate the possibility of getting an inexpensive and sufficiently accurate analytical representation of P(r) over the whole space outside the van der Waals volume of M. 相似文献
29.
Anna Painelli Francesca Terenziani Zoltán G. Soos 《Theoretical chemistry accounts》2007,117(5-6):915-931
We discuss electron-transfer processes that govern the physics of several materials or systems of interest for advanced applications.
The discussion touches upon several topics, ranging from solvatochromism to solvent-induced symmetry breaking, from excitonic
to cooperative effects in molecular crystals, from phase transitions to vibrational contributions to the dielectric constant
in organic materials, from spectroscopy to molecular transport. In all these diverse systems electron transfer (ET) plays
a major role and is discussed with reference to simple models for delocalized charges. 相似文献
30.
R. Acevedo T. Meruane E. Cortés S. O. Vasquez C. D. Flint 《Theoretical chemistry accounts》1994,88(2):99-110
Summary A theoretical model to calculate the vibronic intensities induced by the odd vibrational modes in centrosymmetric lanthanide complexes is developed and applied to octahedral complex ions, LnX
6
3–
, such as occur in the hexachloroelpasolites Cs2NaLnCl6. Both the crystal field and the ligand polarisation contributions are evaluated using a standard set of symmetry coordinates. For the crystal field term a truncated expansion of the intermediates states is employed rather than the more conventional closure approximation. Special care is necessary to ensure that the phases of the contributions are correctly determined since the cross-term between the ligand polarisation and crystal field contributions is signed. General equations applicable to anyf
n
complex ion are derived and an example of their application to the PrCl
6
3–
ion is given The agreement with experiment is satisfactory. 相似文献