偏振对飞秒激光辐照LiF晶体的影响

飞秒激光聚焦到LiF晶体内部, 晶体的加工形貌随偏振改变. 实验表明, 偏振方向平行于<110> 晶向时, 加工起点到表面的距离是<100>偏振下的1.08 倍; 而<110>偏振下加工终点到表面的距离是<100> 偏振下的1.01 倍. 为了解释加工形貌的偏振依赖, 建立了逆韧致辐射、雪崩电离和无辐射跃迁的模型, 首先, 价带电子通过强场电离和雪崩电离, 从激光中吸收能量跃迁到导带, 该过程用电子密度演化方程和傍轴非线性薛定谔方程描述, 求解方程得到导带电子密度; 其次, 导带电子通过无辐射跃迁过程释放能量给晶格, 由能量守恒计算出晶格温度沿激光传播方向的分布; 最后, 晶格温度超过熔点以上的区域被加工. 模拟结果显示, <110>偏振下加工起点到表面的距离是<100> 偏振下的1.03倍, 而<110>偏振下加工终点到表面的距离是<100>偏振下的0.981 倍, 与实验结果基本一致. 虽然Z扫描技术测量的非线性折射率随偏振方向变化, 但是非线性折射率的变化趋势与实验结果相反. 模拟和实验证明逆韧致辐射导致加工形貌随偏振变化.     

Garlic Powder as a Safe Environment Green Corrosion Inhibitor for Mild Steel in Acidic Media; Adsorption and Quantum Chemical Studies

The corrosion inhibition of mild steel in H3PO4 solution by garlic powder was investigated using weight loss and polarization techniques. The adsorption of garlic powder was found to obey Langmuir adsorption isotherm. Maximum inhibition efficiency was 75% at 50 °C and 250 ppm inhibitor concentration. The values of heat of adsorption were negative indicating the spontaneous adsorption process. Quantum chemical calculations were used successfully to evaluate the theoretical inhibitor efficiency. Mathematical and statistical analyses were also used to represent the corrosion rate data with high correlation coefficients. Polarization measurements showed that garlic powder was a mixed — type inhibitor.     

微小型氢火焰离子化检测器及在色谱中的应用

构建了一种微小型氢火焰离子化检测器(μ-FID).与传统FID不同,助燃空气从收集极上部侧面导入,沿收集极与检测器壳体之间的缝隙向下流动,以环状气流沿壁流入燃烧室,流向反转后从中空的收集极内流出.火焰喷口位于燃烧腔的正中心轴线上,该区域助燃气的流动非常稳定,因此噪音电平非常低.采用更高的极化电压以提高离子化效率.对喷口...     

以硼氢化钠为还原剂化学镀镍的电化学研究

采用线性电位扫描伏安法研究了以硼氢化钠为还原剂的化学镀镍体系, 考查了镀液组成及工艺条件对化学镀镍硼阴、阳极过程的影响, 结果表明: 乙酸镍和硼氢化钠含量的提高分别促进了Ni²⁺的还原反应和BH₄^-的氧化反应; 乙二胺、氢氧化钠以及添加剂硫脲、糖精钠对阴、阳极反应均有不同程度的抑制作用, 同时添加剂中的硫元素加速了镍的氧化; 升高温度有利于阴、阳极反应的进行.     

Spectral Dependence of Quasi-Rayleigh Polarization Leap of Nonspherical Particles: Polystyrene Beads Application

Solid particles in Earth’s atmosphere, such as polystyrene beads, are an important factor affecting the processes of absorption and scattering of light in the atmosphere. These processes affect on the solar energy transfer in the Earth’s atmosphere, consequently they have influence on the regional and global climate changes and atmospheric visibility. In particular, great interest to study the scattering properties of small particles compared with wavelength, because of such particles experience low gravitational settlement and may have long time of life in the atmosphere. When scattering particle is much smaller than the wavelength of the scattered or absorbed light, this is the case of Rayleigh scattering. Scattering properties of these particles (such as intensity and the degree of linear polarization) at the Rayleigh scattering are simply derived from electromagnetic Maxwell’s equations. But when the particles are large enough to be comparable with the wavelength, the deviations from Rayleigh scattering law are observed. One of the clear manifestations of such deviations is the recently discovered quasi-Rayleigh polarization leap of monodisperse spherical particles. This quasi-Rayleigh polarization leap allows remote sensing of the sizes of distant particles, based on the spectral position of quasi-Rayleigh polarization leap at different phase angles of observation. In this paper, we studied the effect of the non-sphericity of a scattering polystyrene particle on the magnitude and position of the quasi-Rayleigh polarization leap. It is established that the non-sphericity shifts the position of the quasi-Rayleigh polarization leap shorter wavelengths. It is shown that for non-sphericity of particles makes the quasi-Rayleigh polarization leap becomes less pronounced. Moreover, it was found, that increasing of the phase angle and degree of non-sphericity shift the quasi-Rayleigh polarization leap position to shorter wavelength. However, in the case of not very elongated particles, the quasi-Rayleigh polarization leap is quite well manifested. Therefore, this method is suitable for remote sensing not only the size, but also the degree of non-sphericity of the scattering particles. A simple formula has been obtained for polystyrene beads that relates the degree of non-sphericity of a particle with the wavelength and phase angles at which the quasi-Rayleigh polarization leap is observed.     

A novel method to measure dielectric properties of materials in terahertz spectroscopy

We present a simple method to obtain the optical and dielectric properties of samples without reference measurement in the reflection-type terahertz time-domain spectroscopy. The dielectric properties of the samples of silicon and gallium arsenide were examined. The optical and dielectric properties of the samples were measured through only simple configuration, without the misplacement error. The obtained dielectric functions of the samples in reflection geometry are in good agreement with that predicated by the theory. The main advantage of this method over other methods is its simplicity and accuracy and ease for application of the reflection systems with different incident angle.     

White light interferometry test and analysis of LiNbO3 polarizer

White light interferometer can be used to measure the amplitude extinction ratio (ER) of polarizer and coupling distribution in fiber. A LiNbO₃ polarizer coupled with a polarization maintaining fiber and a silica planar waveguide at the two ends was measured using white light interferometer. According to the principles of optical coherence domain polarimeter (OCDP) technique, the test scheme is analyzed and presented to measure the ER of LiNbO₃ polarizer with its apparatus proposed correspondingly. By analyzing the interference intensity, both the ER of LiNbO₃ polarizer and its coupling crosstalk with optical fiber and waveguide are obtained. The results illustrate that the ER of a 5 mm-long LiNbO₃ polarizer is 71 dB and the crosstalk of the coupling points are around 40 dB. The results have good agreement with analysis.     

云母1/4波片偏振干涉谱的研究

本文利用岛津UV301－PC分光光计，测定了云母1／4波片的偏振干波谱，该光谱和以往文献中的显著不同。本文对此进行了分析和解释，并由此得出了在考虑吸收的情况下的爱里方程表达形式。该将有助于测定某些晶体的吸光度。     

离子回旋共振加热的离子加热

本文在直住几何位形下用线性化动力论得到了离子能量吸收及吸收特征长度的解析表示式，离子能量吸收的主要物理机制是回旋阻尼，波与离子的共振吸收条件是ω－ｌωｃｉ＝ｋⅡνⅡ，其中ω和ωｃｉ分别是波的频率和离子回旋频率，ｋⅡ和ｖⅡ是平行于主磁场方向的波矢和离子速度的分量，ｌ为整数。在等离子体参量慢变化的假定下，也得到了能量吸收半宽度的表示式。结合托卡马克的各种具体情况分别讨论了各种离子回旋共振加热模式的...     

宽带可调谐掺Yb3+双包层光纤激光器的研究

利用闪耀光栅构成可调谐Littrow外腔,对掺Yb³⁺双包层光纤激光器的波长调谐输出进行了实验研究.激光调谐输出波长范围70nm.针对光纤内的双折射效应对激光的输出功率的影响,实验中使用了在线光纤偏振控制器,从而有效地减小了调谐曲线的起伏及其与荧光谱的差别,并得到了窄线宽、线偏振、宽带调谐的激光输出.