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991.
992.
Hae‐Jeong Lee Christopher L. Soles Da‐Wei Liu Barry J. Bauer Wen‐Li Wu 《Journal of Polymer Science.Polymer Physics》2002,40(19):2170-2177
X‐ray reflectivity has been used to determine the mass uptake of probe molecules in porous thin films supported on thick silicon wafers. The adsorption occurs by capillary condensation when the films are exposed to probe vapor at controlled partial vapor pressures. The probe solvent partial pressure was varied by mixing saturated air and dry air at constant temperature or by changing sample temperature at a constant vapor concentration. Pore size distribution in the films can be calculated from the probe uptake with typical porosimetric approaches such as the application of the Kelvin equation to convert partial pressure into pore size. For illustration, the pore size distribution of three different nanoporous thin films, the primary candidate of ultra‐low‐k interlevel dielectrics in the next generation of integrated circuit chips, was determined with this technique. These samples represent different generations of low‐k dielectrics developed by industry. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2170–2177, 2002 相似文献
993.
《Electroanalysis》2003,15(8):739-746
A poly(allylamine)ferrocene monolayer was built on the surface of gold electrode modified with negatively charged alkanethiol based on electrostatic interaction. The electrochemical behavior of the modified electrode was characterized by cyclic voltammetry in detail. The modified electrode was shown to exhibit excellent electrocatalytic response to the oxidation of ascorbic acid. The anodic overpotential was reduced by about 170 mV compared with that obtained at a bare gold electrode. The modified electrode possesses several attractive features, such as simple preparation, fast response and good chemical and mechanical stability. 相似文献
994.
《Surface and interface analysis : SIA》2006,38(9):1285-1290
The incorporation of single‐wall carbon nanotubes (SWCNTs) in cadmium arachidate film by means of the Langmuir‐Blodgett (LB) technique was investigated as a function of arachidic acid/SWCNT mass ratio at the air/water interface and in Langmuir‐Blodgett films. The behaviour at the air/water interface shows that SWCNTs act as an independent phase with respect to the cadmium arachidate. Deposition conditions are optimized when the weight ratio between the arachidic acid (AA) and SWCNTs is in the range 0.018:1 to 1:1. The general order of the LB multilayered structure was destroyed by the progressive density increase in SWCNT quantity as evidenced by X‐ray reflectivity (XRR) analysis. Scanning electron microscopy images indicated that when a multilayered structure was formed its layers consisted of SWCNT bundles stacked one over the other. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
995.
Delayed feedbacks are quite common in many physical and biological systems and in particular many physiological systems. Delay
can cause a stable system to become unstable and vice versa. One of the well-studied non-biological chemical oscillators is
the Belousov-Zhabotinskii (BZ) reaction. This gives relaxation oscillations for a considerable period of time under batch
conditions. This paper deals with the effect of perturbing the limit cycle oscillation of BZ reaction by employing a delayed
electrical feedback to the system under batch conditions. The parameters chosen to study are external resistance and delay.
For various resistances and delays the system was electrically perturbed and found to exhibit various complex mixed mode oscillations.
The dynamic features are accounted for by the Oregonator model, with time delay incorporated in one of the variables.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
996.
997.
Hanns‐Dieter Amberger Lixin Zhang Hauke Reddmann Christos Apostolidis Olaf Walter 《无机化学与普通化学杂志》2006,632(15):2467-2470
Electronic Structures of Organometallic Compounds of f Elements. 64 Does the Zwitterionic Nature of the Triphenylphosphine Oxide Ligand Manifest itself in its Spectrochemical Properties? The triphenylphosphine oxide mono adducts of the moiety tris(η5‐cyclopentadienyl)lanthanide(III) (Ln(Cp)3; Ln = Pr ( 1 ), La ( 2 )) were synthesized and structurally characterized. The Ln–O distances of these compounds are noticeably shorter than those of the corresponding THF adducts. A crystal field (CF) analysis of the optical spectra of 1 leads to a low absolute value of the quadratic CF parameter which is comparable with those of [Pr(Cp)3(L)]? adducts with anionic bases but not with [Pr(Cp)3(MeTHF)]. Reasons for the latter finding are presented. 相似文献
998.
Reported here is an analytical method enabling the stereochemical resolution of a new antianginal compound possessing two stereogenic centers, leading to four stereoisomers. Only one of these isomers is currently under development as a novel antianginal agent and consequently, the other three isomers are considered as unwanted chiral impurities. Therefore, an enantioselective method is required in order to check its enantiomeric purity. This paper presents a method exploiting the high efficiency of capillary electrophoresis and the complexing properties of cyclodextrins to achieve the separation of the four stereoisomers of this weakly basic compound (pKa = 7.4). For this purpose, the combination of a neutral cyclodextrin, hydroxypropyl-gamma-cyclodextrin (HP-gamma-CD), and an anionic cyclodextrin, carboxymethyl-beta-cyclodextrin (CM-beta-CD), was added to the separation buffer running in an uncoated silica capillary. After selection of the suitable cyclodextrin system, satisfactorily separation conditions were as follows: 30 mM phosphate buffer (pH 6.4) containing 10 mM of HP-gamma-CD and 10 mM of CM-beta-CD, running voltage +30 kV. The resulting run time and resolutions were respectively about 17 min and between 1.95 and 2.84. Linearity curves (0.993 < r2 < 0.998) are also shown. 相似文献
999.
Solubility behaviors of binary mixtures of CFCl3 (R-11), CFCl2-CF2Cl (R-113), CHCl3 (R-20), CDCl3 (R-20-d), CHCl2–CF3 (R-123) with room-temperature ionic liquid [bmim][PF6] (1-butyl-3-methylimidazolium hexafluorophosphate) have been investigated using the volumetric and cloud-point methods, since all the systems show liquid–liquid equilibria (LLE). Large immiscibility (LLE) gaps of the perhalogenated compounds (R-11 and R-113) in the ionic liquid have been drastically reduced by the addition of only one hydrogen (or deuterium) in these compounds. The R-123 + [bmim][PF6] binary system belongs to the Type-V fluid behavior. Noticeably large negative values (−2 to −8 cm3 mol−1) of the excess molar volume in the ionic liquid-rich side solution have been observed for all the present systems. Experimental LLE data have been well correlated by the use of the NRTL (non-random two liquid) activity coefficient model. 相似文献
1000.