Dynamical linked cluster expansions with applications to disordered systems

Dynamical linked cluster expansions are linked cluster expansions with hopping parameter terms endowed with their own dynamics. We discuss physical applications to systems with annealed and quenched disorder. Examples are the bond-diluted Ising model and the Sherrington-Kirkpatrick spin glass. We derive the rules and identify the full set of graphs that contribute to the series in the quenched case. This way it becomes possible to avoid the vague extrapolation from positive integer n to n = 0, that usually goes along with an application of the replica trick. Received 13 December 2001 Published online 25 June 2002     

A physical organic mechanistic approach to understanding the complex reaction network of hemostasis (blood clotting)

This review focuses on how the mechanistic approach of physical organic chemistry can be used to elucidate the mechanisms behind complex biochemical networks. The dynamics of biochemical reaction networks is difficult to describe by considering their individual reactions, just as the dynamics of organic reactions is difficult to describe by considering individual electrons and atomic nuclei. Physical organic chemists have developed a useful set of tools to predict the outcome of organic reactions by separating the interacting molecules into modules (functional groups), and defining general rules for how these modules interact (mechanisms). This review shows how these tools of physical organic chemistry may be used to describe reaction networks. In addition, it describes the application of these tools to develop a mechanistic understanding of the dynamics of the complex network of hemostasis, which regulates blood clotting. Copyright © 2007 John Wiley & Sons, Ltd.     

Hadron spectroscopy and structure from AdS/CFT

The AdS/CFT correspondence between conformal field theory and string states in an extended space-time has provided new insights into not only hadron spectra, but also their light-front wave functions. We show that there is an exact correspondence between the fifth-dimensional coordinate of anti-de Sitter space z and a specific impact variable ζ which measures the separation of the constituents within the hadron in ordinary space-time. This connection allows one to predict the form of the light-front wave functions of mesons and baryons, the fundamental entities which encode hadron properties and scattering amplitudes. A new relativistic Schr?dinger light-front equation is found which reproduces the results obtained using the fifth-dimensional theory. Since they are complete and orthonormal, the AdS/CFT model wave functions can be used as an initial ansatz for a variational treatment or as a basis for the diagonalization of the light-front QCD Hamiltonian. A number of applications of light-front wave functions are also discussed.     

Interplay of charge, spin, orbital and lattice correlations in colossal magnetoresistance manganites

We derive a realistic microscopic model for doped colossal magnetoresistance manganites, which includes the dynamics of charge, spin, orbital and lattice degrees of freedom on a quantum mechanical level. The model respects the SU(2) spin symmetry and the full multiplet structure of the manganese ions within the cubic lattice. Concentrating on the hole doped domain ( 0≤x≤0.5) we study the influence of the electron-lattice interaction on spin and orbital correlations by means of exact diagonalisation techniques. We find that the lattice can cause a considerable suppression of the coupling between spin and orbital degrees of freedom and show how changes in the magnetic correlations are reflected in dynamic phonon correlations. In addition, our calculation gives detailed insights into orbital correlations and demonstrates the possibility of complex orbital states. Received 4 September 2002 / Received in final form 8 November 2002 Published online 31 December 2002     

Flow to strong coupling in the two-dimensional Hubbard model

We extend the analysis of the renormalization group flow in the two-dimensional Hubbard model close to half-filling using the recently developed temperature flow formalism. We investigate the interplay of d-density wave and Fermi surface deformation tendencies with those towards d-wave pairing and antiferromagnetism. For a ratio of next nearest to nearest neighbor hoppings, t'/t = - 0.25, and band fillings where the Fermi surface is inside the Umklapp surface, only the d-pairing susceptibility diverges at low temperatures. When the Fermi surface intersects the Umklapp surface close to the saddle points, d-wave pairing, d-density wave, antiferromagnetic and, to a weaker extent, d-wave Fermi surface deformation susceptibilities grow together when the interactions flow to strong coupling. We interpret these findings as indications for a non-trivial strongly coupled phase with short-ranged superconducting and antiferromagnetic correlations, in close analogy with the spin liquid ground state in the well-understood two-leg Hubbard ladder. Received 23 January 2002     

Classical spin liquid properties of the infinite-component spin vector model on a fully frustrated two dimensional lattice

Thermodynamic quantities and correlation functions (CFs) of the classical antiferromagnet on the checkerboard lattice are studied for the exactly solvable infinite-component spin-vector model, D↦∞. In contrast to conventional two-dimensional magnets with continuous symmetry showing extended short-range order at distances smaller than the correlation length, r ξ _c∝ exp(T ^*/T), correlations in the checkerboard-lattice model decay already at the scale of the lattice spacing due to the strong degeneracy of the ground state characterized by a macroscopic number of strongly fluctuating local degrees of freedom. At low temperatures, spin CFs decay as < >∝ 1/r ² in the range a ₀≪r≪ξ _c∝T ^-1/2, where a₀ is the lattice spacing. Analytical results for the principal thermodynamic quantities in our model are very similar with MC simulations, exact and analytical results for the classical Heisenberg model (D = 3) on the pyrochlore lattice. This shows that the ground state of the infinite-component spin vector model on the checkerboard lattice is a classical spin liquid. Received 16 November 2001 and Received in final form 12 February 2002     

Linewidths of ammonia in collisions with He: Calculations from an ab initio potential

We present semiclassical calculations based on the Robert-Bonamy formalism of collisional broadening coefficients of ammonia by collision with He at room temperature. Calculations have been performed with the accurate ab initio potential of Hodges and Wheatley. The calculated line widths are compared to the available experimental data and a satisfactory agreement is found, although the model contains no adjustable parameters. However the calculations also exaggerate the K dependence of the broadenings, especially for lines with K = J − 1 or K = J.     

Generalized algebraic transformations and exactly solvable classical-quantum models

The rigorous approach aimed at providing exact analytical results for hybrid classical-quantum models is elaborated on the grounds of generalized algebraic mapping transformations. This conceptually simple method allows one to obtain novel interesting exact results for the hybrid classical-quantum models, which may for instance describe interacting many-particle systems composed of the classical Ising spins and quantum Heisenberg spins, the localized Ising spins and delocalized electrons, or many other hybrid systems of a mixed classical-quantum nature.