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81.
Cynthia Kolb Whitney 《Foundations of Physics》2007,37(4-5):788-812
This paper revisits the historical sequence in which some of the major developments of 20th-century physics occurred, and
explores how theories could have turned out differently, if the sequence of developments had been different. It shows how
a delay in founding special relativity theory until after (1) at least one puzzling problem in electromagnetic theory could
be acknowledged, and (2) sat least some of the experimental observations pertinent to the development of quantum mechanics
had become well known, could have resulted in a larger theory that covers both domains in a manner quite different from that
of any of the theories we use today. The revised theory dispenses with a separate postulate introducing Planck’s constant
h, identifying instead a physical mechanism that implies the constant. Some important aspects of quantum chemistry then follow.
Editor, Galilean Electrodynamics, Proceedings of the Natural Philosophy Alliance; Visiting Industry Professor, Tufts University,
retired 相似文献
82.
83.
E.C. Reynhardt L. Latanowicz 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,130(2):195-208
Equations for the temperature dependence of proton and deuteron spin–lattice relaxation rates and second moments due to a complex motion consisting of classical jumps over a potential barrier and quantum mechanical tunneling through the barrier have been derived. Asymmetric double and triple potential wells are considered. These equations have been employed to analyze proton spin–lattice relaxation data for solid naphthazarin in the laboratory and rotating frames as a function of temperature. It is shown that tunneling plays an important role in the proton transfer dynamics of this compound. 相似文献
84.
T. González-Lezana G. Delgado-Barrio P. Villarreal F.X. Gadéa 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(2):227-232
The stabilization method is applied to the case of interacting resonances in the photo-dissociation of van der Waals clusters
composed by a rare gas atom bound to a dihalogen molecule. The study of an illustrative two-dimensional model consisting in
a T-shaped NeI2 molecule shows the adequacy of the method whenever the projection of the stabilization wave functions on the assumed prepared
initial state is accounted for. The agreement of the fragmentation cross-sections with some previous results using the effective
resolvent method and accurate close-coupling calculations is excellent. The method reveals its utility as a complementary
tool since allows, through the analysis of the stabilization wave function in terms of zero-order levels, a precise characterization
of the resonant states involved.
Received 5 April 2002 / Received in final form 24 May 2002 Published online 19 July 2002 相似文献
85.
A. S. Romanov 《Theoretical and Mathematical Physics》2007,150(3):347-354
We solve the problem of the relative motion of two nearby vortices (a dipole pair) and a third vortex for different current
functions.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 150, No. 3, pp. 409–416, March, 2007. 相似文献
86.
Solution rheology of 2‐vinyl pyridine and N‐methyl‐2‐vinyl pyridinium chloride random copolymers in ethylene glycol was studied over wide ranges of concentration and effective charge. The fraction of quaternized monomers α and the fraction of monomers bearing an effective charge f of these copolymers were measured using counterion titration and dielectric spectroscopy, respectively. Ethylene glycol is a good solvent for neutral poly(2‐vinyl pyridine), with very few ionic impurities. The viscosity η and relaxation time τ of dilute and semidilute unentangled solutions exhibit the scaling with concentration and effective charge expected by the Dobrynin model. Reduced viscosity data are independent of concentration in dilute solution, giving an intrinsic viscosity that depends on effective charge, and the experimental data obey the Fuoss law in the semidilute unentangled regime. Scaling concentration with the overlap concentration (c/c*) reduces these data to common curves, and c* ~ f ?12/7 as predicted by the Dobrynin model, where f is the fraction of monomers bearing an effective charge. While the overlap concentration depends strongly on effective charge until counterion condensation occurs, the entanglement concentration ce is surprisingly insensitive to effective charge, indicating that entanglement effects are not understood using the Dobrynin model. The terminal modulus G = η/τ depends only on the number density of chains G = ckT/N for c* < c < ce, and G ~ c3/2 for c > ce independent of the effective charge. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2001–2013, 2006 相似文献
87.
A series of molecular dynamics simulations have been performed to study the supramolecular structure of self‐assembled complexes formed by N‐dodecyltrimethylammonium cations and the synthetic polypeptide poly(α,L ‐glutamate). The influence of the type of solvent has been investigated, considering explicit environments of chloroform, water, and methanol on a stoichiometric complex containing 15 residues. In chloroform, the complex stabilizes in a regular structure: the polypeptide adopts an α‐helix conformation that is regularly surrounded by surfactant molecules to form electrostatic interactions through a multiple interaction pattern. However, this structure destabilizes in methanol and water: (a) the α‐helix unfolds in the two solvents and (b) the electrostatic links between the surfactant molecules and the polyanion are disrupted in aqueous solution, although these interactions are still preserved in methanol. The role of the solvent environment in stabilizing or destabilizing the polypeptide secondary structure, the organization of the surfactant molecules, and predominantly the surfactant–polypeptide supramolecular organization is discussed in detail. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1122–1133, 2006 相似文献
88.
In this paper, we applied multifractal modeling techniques to analyze the traffic data collected from the Beijing Yuquanying. The results indicated that multifractal characteristics obviously exist in the traffic system; the degree of fractality of these traffic data tends to increase as the traffic system becomes congested; the Hölder exponent that measures the local rate of fractality may be used as indicators to predict the presence of the traffic congestion. 相似文献
89.
Yi-rang Yuan 《应用数学学报(英文版)》2007,23(2):255-268
For a coupled system of multiplayer dynamics of fluids in porous media,the characteristic finiteelement domain decomposition procedures applicable to parallel arithmetic are put forward.Techniques suchas calculus of variations,domain decomposition,characteristic method,negative norm estimate,energy methodand the theory of prior estimates are adopted.Optimal order estimates in L~2 norm are derived for the error inthe approximate solution. 相似文献
90.
在相对论σ-ω-ρ模型的平均场近似下, 研究了质子中子星物质在均熵状态下的组成、温度和物态方程. 如给定每一个重子的熵, 一些热力学量的值将随重子密度的增加而增加, 当考虑超子时, 这些值会减小. 给定重子密度, 中子在S=2时的组分比S=1时的小, 而质子、电子、μ子在S=2时的组分比S=1时的大, 特别是在低密度区域. S是每个重子的熵. 保持重子密度不变, 在低密度区域, 超子在S=2时的组分比S=1时的大, 在高密度区域则相反. 同样, 在同一重子密度处, S=2时的温度、能量密度及压强分别比S=1时的大. 另外, 有限熵对粒子组分和温度的影响比对质子中子星物质的物态方程的影响大. 还研究了反粒子的贡献, 他们确实很小. 相似文献