基于古斯-汉欣位移的双通道窄带滤波器

本文利用光束在对称金属包覆波导表面反射得到的异常大的古斯-汉欣(Goos-Hänchen)位移,通过实验实现了双通道窄带滤波.当入射激光波长为859.60 nm时,两通道滤波的峰值位置分别为859.604 nm和859.688 nm,峰值半宽(FWHM)为0.036 nm,而消光比达到15.3 dB.峰值波长可通过改变入射角或小孔位置实现调谐. 关键词： 古斯-汉欣(Goos-Hä nchen)位移 光波导 双通道 滤波器     

全内反射型三角晶格光子晶体多模波导中的光传播特性

研究了光波在没有光子带隙的三角晶格型光子晶体多模波导中的传播特性. 利用等效折射率法,将该结构等效为三层平板介质波导,基于自映像原理,数值分析和模拟了其多模干涉效应. 研究结果表明,由于全内反射和分布式布拉格反射的联合效应,光场类似于传统波导模式,能高效地传输;随着填充率的增大,高透射区域将向波长减小的方向移动,带宽和透射率也随之增加, 研究结果为实际应用中选择适当的填充率提供了理论依据. 关键词： 光子晶体多模波导 全内反射 填充率 时域有限差分法     

光子晶体波导中的孤子传输及其延迟特性研究

研究了正方晶格和三角晶格空气背景硅介质柱光子晶体线缺陷波导导模左带隙边缘处的亮孤子脉冲传播特性及其慢光延迟特性. 采用平面波展开法仿真分析了波导相邻两行介质柱大小r₁和r₂以及波导宽度D对孤子脉冲传输所需峰值功率P₀和延迟时间T_s的影响,总结了其变化规律. 通过调整波导结构得到了正方晶格和三角晶格优化波导结构,优化后,正方晶格结构波导P₀减小了81.17%,T_s增加了66.32%;三角晶格结构波导P₀减小了73.7%,T_s增加了67.63%,实现了孤子传输性能的大幅度优化. 关键词： 光子晶体波导 光孤子 峰值功率 延迟时间     

二甲苯蒸气玻璃光波导传感元件的研制

本文利用浸渍-提拉法,将镍掺杂的过氧聚钨酸(PTA)复合薄膜固定在锡(Sn2+,Sn4+)掺杂的玻璃光波导(Sn doped glass slide OWG)表面,研制出了一种高灵敏的二甲苯蒸气光波导传感元件.采用流动注射法对二甲苯蒸气进行了检测.实验结果表明,在室温下,该传感元件对浓度在1.0×10-6～1.0×10...     

Asymmetric hydrogenation of alkenes with planar chiral 2-phosphino-1-aminoferrocene-iridium(I) complexes

The first highly enantioenriched and enantiopure planar chiral 2-phosphino-1-aminoferrocene ligands and their Ir(COD)BAr_F complexes are reported. The ligands display bidentate coordination behavior towards iridium, as indicated by trends in ³¹P and ¹H NMR spectra of the phosphine moieties and the α to nitrogen substituents of the amines. All of the new complexes showed good reactivity as catalysts in promoting asymmetric hydrogenation of several prochiral alkenes, with enantioselectivities up to 92%. Iridium complexes of dimethylaminoferrocene derivatives containing P-Ar groups [PPh₂ and P(o-tol)₂] gave the highest levels of asymmetric induction.     

Synthesis, properties and complexation of (pS)-1-isocyano-2-methylferrocene, the first planar-chiral isocyanide ligand

Reaction of enantiomerically pure, planar-chiral (_pS)-1-bromo-2-methylferrocene (1) with phthalimide in the presence of Cu₂O produces (_pS)-1-phthalimido-2-methylferrocene (2), quantitative reduction of which with hydrazine hydrate affords (_pS)-1-amino-2-methylferrocene (3) with >99% ee. Formylation of amine 3 followed by dehydration of the resulting (_pS)-1-formamido-2-methylferrocene (4) provides (_pS)-1-isocyano-2-methylferrocene (5), the first example of a planar-chiral isocyanide ligand, in a good yield. Isocyanide 5 reacts with PdI₂ to give the crystallographically characterized chiral complex trans-[PdI₂{(_pS)-1-isocyano-2-methylferrocene}₂] (6). The redox behavior of 4, 5, and 6, accessed by cyclic voltammetry, is discussed.     

基于偏振光波导分光光谱技术原位研究纳米金-细胞色素c 自组装过程

时间分辨偏振光波导分光光谱技术是一种用于研究表面分子吸附动力学的强大工具. 利用该技术实时、原位监测纳米金与细胞色素c的静电自组装过程, 发现随着吸附层数的增加, 纳米金粒子吸附层产生的局域等离子体共振(LSPR)吸收峰发生了红移, 而且在横磁(TM)模式下的红移比横电(TE)模式下的红移更快; 细胞色素c在纳米金表面的吸附导致LSPR吸收峰的峰位和强度在TM模式下显著红移和升高, 相比之下, TE模式下的LSPR吸收峰无明显变化. 对实验数据的分析验证了纳米金在细胞色素c单分子层表面的吸附动力学行为遵循扩散控制模型, 细胞色素c在纳米金单粒子层表面的吸附动力学行为遵循Langmuir等温吸附模型, 进一步估算了细胞色素c在纳米金表面的吸附速率常数、脱附速率常数和吸附自由能.     

Quantum steerability of two qubits mediated by one-dimensional plasmonic waveguides

We study the dynamics of the quantum steering between two separated qubits trapped in a one-dimensional plasmonic waveguide. By numerical methods, we calculate the quantum steerability and other quantum correlations, i.e., entanglement, discord, and coherence, for both cases with and without laser driving fields. It is found that steerability may exhibit a sudden disappearance and sudden reappearance phenomenon. Specifically, there exist time windows with no steerability but finite entanglement. The effects of plasmon wavenumber and the distance between the two qubits on steerability are also examined. Furthermore, we show that quantum steerability is tunable by adjusting the laser driving fields.     

Ultra-wideband surface plasmonic bandpass filter with extremely wide upper-band rejection

An ultra-wideband bandpass filter (BPF) with a wide out-of-band rejection based on a surface plasmonic waveguide (SPW) slotline with ring grooves is designed and analyzed. A paired microstrip-to-slotline transition is designed for quasi-TEM to TM mode conversion by using a microstrip line with a circular pad and the slotline with the same circular slot. The mode conversion between the TM and the surface plasmon polariton (SPP) mode is realized by using a gradient slotline with ring grooves and an impedance matching technique. The upper cut-off frequencies of the passband can be adjusted by using these proposed SPP units, while the lower frequencies of the passband are created by using the microstrip-to-slotline transitions to give an ultra-wideband BPF. The dispersion curves of SPP units, electric field distribution, and the transmission spectra of the proposed ultra-wideband bandpass filter are all calculated and analyzed by the finite-difference time-domain (FDTD) method. The simulated results show that the presented filter has good performance including a wide 3-dB bandwidth of 149% from 0.57 GHz to 3.93 GHz, an extremely wide 40-dB upper-band rejection from 4.2 GHz to 18.5 GHz, and low loss and high selectivity in the passband. To prove the design validity, a prototype of the BPF has been manufactured and measured, showing a reasonable agreement with simulation results. The unique features of the proposed BPF may make it applicable for integrated circuit and plasmonic devices in microwave or THz frequency ranges.     

Dynamic manipulation of modes in an optical waveguide using dielectrophoresis

The emergence of optofluidics has brought a high degree of tuneability and reconfigurability to optical devices. These possibilities are provided by characteristics of fluids including mobility, wide range of index modulation, and abrupt interfaces that can be easily reshaped. In this work, we created a new class of optofluidic waveguides, in which suspended mesoparticles were employed to greatly enhance the flexibility of the system. We demonstrated tuneable quasi single mode waveguides using spatially controllable mesoparticles in optofluidics. The coupling of waveguiding modes into the assembly of mesoparticles produces strong interactions and resonant conditions, which promote the transitions of the waveguiding modes. The modal response of the system depends on the distribution of packed particles above the polymeric rib waveguide which can be readily controlled under the appropriate combination of dielectrophoresis and hydrodynamic forces.