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91.
《Surface and interface analysis : SIA》2004,36(1):61-70
In spectroscopy, the recorded spectra can often be modelled as the noisy convolution product of an instrumental function with the ‘true’ signal to be estimated. Such models have often been used for high‐resolution electron energy‐loss spectroscopy (HREELS). In this article, a new method is suggested to estimate the ‘true’ HREELS signal, i.e. the original electronic diffusion function with ‘true’ peak intensities. Our method relies upon the use of wavelets that, because they exhibit simultaneous time and frequency localization, are well‐suited for signal analysis. Firstly, a wavelet shrinkage algorithm is used to filter the noise. This is achieved by decomposing the noisy signal into an appropriate wavelet basis and then thresholding the wavelet coefficients that contain noise. This algorithm has a particular threshold related to frequency and time. Secondly, the broadening due to the instrumental response is eliminated through a deconvolution process. This step mainly rests on the existing relation between the Lipschitz regularity of the signal and the decay with scale of its wavelet coefficients and on least squares. The efficiency of this technique is highlighted by comparing the results obtained with those provided by other published methods. This work is the second in a series of three papers in this issue. The first one presents background knowledge on the wavelets required to understand the estimation methods. The third paper explores the application of wavelet filtering and deconvolution techniques to x‐ray photoelectron spectroscopy. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
92.
消色差谱相位延迟器的光谱特性测试研究 总被引:6,自引:1,他引:5
本文应用归一化偏振调制原理建立的测试系统,对常规菲涅耳菱体,改进型菲涅菱体,斜入射型以及直角棱镜组合型的消色差相位延迟的光谱特性进行了测试研究,得到了各延迟器的消色差特性曲线,并对测试结果进行了分析。结果表明改进型菲涅耳菱体以及直色棱镜组合型型消色差相位延迟器,是目前较理想的实用型消色相位延迟器。 相似文献
93.
V Babizhetskyy 《Journal of solid state chemistry》2004,177(2):415-424
Solid state phase equilibria in the ternary Gd-Si-B phase diagram have been proposed at 1270 K using X-ray diffraction, scanning electron microscopy and electron probe microanalysis. Prior to this work, the binary systems Gd-B, Gd-Si and Si-B have also been reinvestigated. The main characteristic of the ternary diagram is the occurrence of two new ternary compounds Gd5Si2B8 and Gd5Si3B0.64. The former crystallizes in tetragonal symmetry, space group P4/mbm with unit cell parameters a=7.2665(3), c=8.2229(7) Å, the second one presents hexagonal symmetry, space group P63/mcm with unit cell parameters a=8.5080(4),c=6.4141(2) Å. The X-ray structures of the two structurally related phases Gd5Si3B0.64 and host binary Gd5Si3 have been refined from three-dimensional single-crystal intensity data to the final R values of 0.036 (Rw=0.046) and 0.046 (Rw=0.055) for 457 and 401 reflections, respectively with [F>4σ(F)]. Both structures exhibit the Mn5Si3-type structure, with in addition for Gd5Si3B0.64 a partial occupancy by boron of the normally vacant interstitial site at the center of the Gd6 octahedron, which corresponds to the origin of the unit cell. Bonding between the interstitial boron atoms and the gadolinium ones forming the Gd6B polyhedra is indicated by the decrease in the corresponding Gd-Gd distances and consequently in the unit cell volume. Finally, the Gd-Si-B phase diagram is compared with the previously reported Er-Si-B, at 1070 K. 相似文献
94.
The noise of hybrid soliton pulse source (HSPS) with linearly chirped Gaussian apodized fiber Bragg grating is analyzed by couple-mode equations including spontaneous emission noise when the HSPS is mode-locked. Relative intensity noise is calculated using numerical solutions of these equations. It is shown that transform limited pulses are generated over a wide tuning range around the fundamental mode-locking frequency with low spontaneous noise. However, a high noise level affects the operation of device, and therefore transform-limited pulses are not obtainable over a wide tuning range. It is also shown that noise is extremely sensitive to the RF and DC currents, linewidth enhancement factor, gain saturation parameter and spontaneous coupling factor. 相似文献
95.
96.
调制不稳定性对级联放大光纤传输系统信噪比的影响 总被引:1,自引:0,他引:1
在考虑光纤损耗和级联放大器的情况下,推导了调制不稳定性的产生条件和增益的普适解析表达式,分析了调制不稳定性对信噪比的影响,给出了一个新的计算信噪比的表达式。 相似文献
97.
Alexis C. Kaporis Lefteris M. Kirousis Yannis C. Stamatiou Malvina Vamvakari Michele Zito 《Discrete Applied Mathematics》2007,155(12):1525-1538
The problem of determining the unsatisfiability threshold for random 3-SAT formulas consists in determining the clause to variable ratio that marks the experimentally observed abrupt change from almost surely satisfiable formulas to almost surely unsatisfiable. Up to now, there have been rigorously established increasingly better lower and upper bounds to the actual threshold value. In this paper, we consider the problem of bounding the threshold value from above using methods that, we believe, are of interest on their own right. More specifically, we show how the method of local maximum satisfying truth assignments can be combined with results for the occupancy problem in schemes of random allocation of balls into bins in order to achieve an upper bound for the unsatisfiability threshold less than 4.571. In order to obtain this value, we establish a bound on the q-binomial coefficients (a generalization of the binomial coefficients). No such bound was previously known, despite the extensive literature on q-binomial coefficients. Finally, to prove our result we had to establish certain relations among the conditional probabilities of an event in various probabilistic models for random formulas. It turned out that these relations were considerably harder to prove than the corresponding ones for unconditional probabilities, which were previously known. 相似文献
98.
Stephen W. Burgess Jogin R. Wu Kerry Swift Barry R. Lentz 《Journal of fluorescence》1991,1(2):105-112
Rate constants were determined for the transfer of the fluorescent lipid probe 1-palmitoyl-2-[[2-[4-(6-phenyl-trans-1,3,5-hexatrienyl)phenyl]ethyl] oxy]carbonyl]-3-sn-phosphatidylcholine (DPHpPC) between large, unilamellar extrusion vesicles composed either of dipalmitoyl phosphatidylcholine (DPPC) or of DPPC mixed with a small amount (0.5 mol%) of lyso phosphatidylcholine (Lyso PC). Transfer of the lipid probe in the presence of varying concentrations of poly(ethylene glycol) (PEG) was monitored using the SLM 48000-MHF Multi-Harmonic Fourier Transform phase and modulation spectrofluorometer to collect multifrequency phase and modulation fluorescence data sets on a subsecond time scale. The unique ability of this instrument to yield accurate fluorescence lifetime data on this time scale allowed transfer to be detected in terms of a time-dependent change in the fluorescent lifetime distribution associated with the lipid-like DPHpPC probe. This probe demonstrates two short fluoresence decay times (ca. 1.1–1.4 and 4.3–4.8 ns) in a probe-rich environment but a single long lifetime (ca. 7 ns) in a probe-poor environment. A simple two-state model for initial lipid transfer was used to analyze the multifrequency data sets collected over a 4-s time frame to obtain the time rate of change of the concentrations of donor and acceptor probe populations following rapid mixing of vesicles with PEG. The ability to measure fluorescence lifetimes on this time scale has allowed us to show that the of rate of lipid transfer increased dramatically at 35% PEG in both fusing and nonfusing vesicle systems. These results are interpreted in terms of a distinct interbilayer structure associated with intimate bilayer contact induced by high and potentially fusogenic concentrations of PEG. 相似文献
99.
Ab initio energetic calculations based on the density functional theory (DFT) and projector augmented wave (PAW) pseudo-potentials method were performanced to determine the crystal structural parameters and phase transition data of the polymorphic rare-earth sesquioxides Ln2O3 (where Ln=La-Lu, Y, and Sc) with A-type (hexagonal) and B-type (monoclinic) configurations at ground state. The calculated results agree well with the limited experimental data and the critically assessed results. A set of systematic and self-consistent crystal structural parameters, energies and pressures of the phase transition were established for the whole series of the A- and B-type rare-earth sesquioxides Ln2O3. With the increase of the atomic number, the ionic radii of rare-earth elements Ln and the volumes of the sesquioxides Ln2O3 reflect the so-called “lanthanide contraction”. With the increase of the Ln3+-cation radius, the bulk modulus of Ln2O3 decreases and the polymorphic structures show a degenerative tendency. 相似文献
100.
The Lombardo–Imbihl–Fink (LFI) ODE model of the NO+NH3 reaction on a Pt(1 0 0) surface shows stable relaxation oscillations with very sharp transitions for temperatures T between 404 and 433 K. Here we study numerically the effect of linear diffusive coupling of these oscillators in one spatial dimension. Depending on the parameters and initial conditions we find a rich variety of spatio-temporal patterns which we group into four main regimes: bulk oscillations (BOs), standing waves (SW), phase clusters (PC), and phase waves (PW). Two key ingredients for SW and PC are identified, namely the relaxation type of the ODE oscillations and a nonlocal (and nonglobal) coupling due to relatively fast diffusion of the kinetically slaved variables NH3 and H. In particular, the latter replaces the global coupling through the gas phase used to obtain SW and PC in models of related surface reactions. The PW exist only under the assumption of (relatively) slow diffusion of NH3 and H. 相似文献