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111.
Applying a Lindemann like criterion obtained previously by Kierfeld et al. [J. Kierfeld, T. Nattermann, T. Hwa, Phys. Rev. B 55 (1997) 626], we estimate the magnetic field and temperature for a high-Tc superconductor, at which a topologically ordered vortex glass phase becomes unstable with respect to a disorder-induced formation of dislocations. The employed criterion is shown to be equivalent to a conventional phenomenological Lindemann criterion including the values for the numerical factors, i.e., for the Lindemann number. The positional correlation length of the topologically ordered vortex glass is calculated. 相似文献
112.
The partitioning of the ternary systems n-pentane/n-heptane/(helium or argon) at ambient conditions is investigated using configurational-bias Monte Carlo simulations in the
Gibbs ensemble. The results demonstrate that this approach yields very precise partition constants and free energies of transfer.
Simulations are carried out to study the dependence of the n-pentane partitioning with respect to the carrier gas, the system size, and the overall solute concentrations. None of the
changes of variables, within the ranges used here, has a significant effect on the alkane partitioning. However, chemical
potentials calculated via Widom's ghost particle insertions show a strong number dependence for phases containing relatively
few molecules of a given type. This problem originates from the fact that the chemical potential is calculated for a concentration
of real particles plus one ghost particle that is systematically larger than the equilibrium concentration. A simple correction
term is suggested to account for this problem.
Received: 13 May 1998 / Accepted: 18 June 1998 / Published online: 4 September 1998 相似文献
113.
114.
115.
Sandro Faetti Leone Fronzoni Paolo Grigolini Vincenzo Palleschi Girolamo Tropiano 《Journal of statistical physics》1988,52(3-4):979-1003
Two models for the Freedericksz transition in a fluctuating magnetic field are considered: one is based on a dichotomic and the other on a nonlinear Gaussian noise. Both noises are characterized by a finite correlation time. It is shown that the linear response assumption leading to the best Fokker-Planck approximation in the dichotomic and nonlinear Gaussian cases can be trusted only up to the order
1 and
0, respectively. The role of the corrections to the linear response approximation is discussed and it is shown how to replace the non-Fokker-Planck terms stemming from these corrections with equivalent terms of standard type. This technique is shown to produce perfect agreement with the exact analytical results (dichotomic noise) and to satisfactorily fit the results of analog simulation (nonlinear Gaussian noise). 相似文献
116.
Sandro Faetti Leone Fronzoni Paolo Grigolini Riccardo Mannella 《Journal of statistical physics》1988,52(3-4):951-978
It is shown that the Fokker-Planck operator can be derived via a projection-perturbation approach, using the repartition of a more detailed operator into a perturbation
1 and an unperturbed part
0. The standard Fokker-Planck structure is recovered at the second order in
1, whereas the perturbation terms of higher order are shown to provoke the breakdown of this structure. To get rid of these higher order terms, a key approximation, local linearization (LL), is made. In general, to evaluate at the second order in
1 the exact expression of the diffusion coefficient which simulates the influence of a Gaussian noise with a finite correlation time, a resummation up to infinite order in must be carried out, leading to what other authors call the best Fokker-Planck approximation (BFPA). It is shown that, due to the role of terms of higher order in
1, the BFPA leads to predictions on the equilibrium distributions that are reliable only up to the first order in t. The LL, on the contrary, in addition to making the influence of terms of higher order in
1 vanish, results in a simple analytical expression for the term of second order that is formally coincident with the complete resummation over all the orders in t provided by the Fox theory. The corresponding diffusion coefficient in turn is shown to lead in the limiting case to exact results for the steady-state distributions. Therefore, over the whole range 0 the LL turns out to be an approximation much more accurate than the global linearization proposed by other authors for the same purpose of making the terms of higher order in
1 vanish. In the short- region the LL leads to results virtually coincident with those of the BFPA. In the large- region the LL is a more accurate approximation than the BFPA itself. These theoretical arguments are supported by the results of both analog and digital simulation. 相似文献
117.
采用半微量相平衡方法测定了三元体系La(NCS)3.4.5H2O-B15C5-C2H5OH在298.15K的溶解度,测定了各饱和溶液的折光率。 相似文献
118.
在微波作用下,仅用1min便完成了苯甲醛亚胺的固—液相转移催化苄基化反应,然后经酸水解得到d1—苯丙氨酸,全程总产率为62.5×10(-2)。 相似文献
119.
氧化铝具有许多重要的工业用途,而制备高热稳定活性氧化铝的技术也在不断地发展[1,2],因此,研究其高温烧结下的相变过程很有意义.离子深法作为新型测试手段,已成功地用于生物大分子结构与功能研究方面[‘],而在固体材料测试中的应用尚未见报道.我们以EU’“作为荧光探针,并结合**D和*nR研究了川对。在不同烧结温度下的相变过程.1实验部分样品的制备采用复盐分解法.先将Elf刀s用高纯硝酸溶解定容.以占AlzO。重量1%的量加入到硫酸铝锭溶液中,进行超声处理,冷冻干燥.再依次登于900”C、1000C、1100C、1200C的高温炉… 相似文献