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841.
Effect of glycine substitution on the ferroelectric phase of betaine arsenate [(CH3)3NCH2COO·H3AsO4]
The present work reports an experimental investigation on the influence of glycine (NH2CH2COOH) substitution in the polar properties and the critical dynamics of the molecular ferroelectric betaine arsenate, (CH3)3NCH2COO·H3AsO4. The dielectric dispersion (20 Hz<ν<3 MHz) and the thermally induced displacement currents are investigated in detail over the extended Curie region of the system (130 K<T<100 K). The results obtained for a single crystal with nominal glycine content of 20% are analyzed, compared with those obtained for pure betaine arsenate and discussed within the scope of a phenomenological Landau model previously used to describe a system with competing ferroelectric and structural instabilities. 相似文献
842.
Inma Peral Jonathan McKinlay Michael Knapp Salvador Ferrer 《Journal of synchrotron radiation》2011,18(6):842-850
A concept is given for describing multicrystal analyser detectors (MADs), as they are in use for synchrotron powder diffraction, on the basis of the Rowland circle construction. The Rowland circle is typically used to describe focusing geometries and can be adapted for the case of MADs working at a single energy as well as in a limited energy range. With this construction it is also possible to quantify and optimize the walk of the beam along non‐central crystals which is inevitable in certain detector designs. The results of this geometrical inspection are correlated with a real detector design that is implemented at the ALBA synchrotron facility in Spain. An error budget is given to estimate the influence and amount of tolerance of the manufacturing process. 相似文献
843.
Zhong-Li Liu Xiao-Feng LiXiu-Lu Zhang Ling-Cang CaiFu-Qian Jing 《Physica B: Condensed Matter》2011,406(23):4518-4522
We have performed the first-principles and classical molecular dynamics simulations to investigate the phase diagram and thermodynamic properties of Sr under high pressure and temperature. The obtained solid phase diagram of Sr, based on the quasi-harmonic approximation (QHA), is greatly supported by the available experimental data under low pressure. From the coexistence-phase molecular dynamics simulations, we also obtained the high-pressure melting curve of Sr which shows good agreement with the experiment. While, the experimentally observed β-Sn structure of Sr-III was found to be mechanically unstable according to our phonon dispersion calculations and evolutionary algorithm structure searches. We find that α-U phase (space group Cmcm) is energetically favorable and is the good candidate of Sr-III. 相似文献
844.
845.
The high-pressure structural transformation of elemental Sn is studied using an ab initio density functional theory implementation of the metadynamics method that predicts with sufficient compression, Sn will transform from the bcc structure into an hcp structure. The low-free-energy pathway associated with this phase transition is characterized as the Burgers transition mechanism. The superconducting properties of Sn under pressure are also investigated. Both bcc and hcp structures of Sn exhibit very weak electron-phonon coupling and therefore would not sustain superconductivity at high pressure. 相似文献
846.
Phase transition properties of a spin-1 Blume-Emery-Griffiths model (BEGM) with random transverse crystal field is studied by the effective field theory for a simple cubic lattice. In T−Dx space, we obtain the phase diagrams with the ratio α between the biquadratic interaction and the exchange interaction as well as a tunable parameter l of the transverse crystal field. The tricritical point (TCP) appears at α<0, which undergoes a crossover from positive to negative direction of the transverse crystal field when l<0. The TCP cannot be observed for α>0. The maximum critical temperature increases with the increase of α. The position of the peak value tends to the drift of negative or positive direction for a different magnitude or an imperfect (±) transverse crystal field distribution. In T−α space, the range of ordered phase is magnified when the ratio is changed from α<0 to α>0. The random transverse crystal field obviously affects the TCP. 相似文献
847.
848.
A novel algorithm for branch cut phase unwrapping 总被引:1,自引:0,他引:1
Dongliang ZhengFeipeng Da 《Optics and Lasers in Engineering》2011,49(5):609-617
Branch cut method is a powerful noise-immune algorithm for correct phase unwrapping of noisy phase maps. The shortest branch cut length promises the optimal unwrapping result of the wrapped phase maps. A new algorithm is proposed to search for the shortest branch cut length by simple exchange operation. Although the algorithm is on the basis of stochastic search techniques, it has a high probability of finding the shortest branch cut length or an approximation of it. Compared with the traditional algorithms, the algorithm is fast and competitive. 相似文献
849.
A novel fringe projection profilometry using a single sinusoidal fringe pattern projected is proposed. Computer-generated sinusoidal fringe and uniform intensity patterns are firstly projected on a testing object by a liquid crystal display projector. The variable reflection intensity of a fringe pattern is then roughly normalized by division operation applied to the grabbed fringe and uniform intensity patterns projected. Fringe intensity is further normalized by employing an interpolation algorithm. The deformed sinusoidal pattern encoding object shape is converted to a wrapped phase map without using phase-shifting or Fourier transform. Computer simulation and experimental performance are evaluated to demonstrate the validity of the proposed method. The experimental results compared with those of the four-step phase-shifting and fast Fourier transform methods are also presented. 相似文献
850.
Excepted for the very short terms the frequency stability of ultra-stable oscillators is mainly limited by the resonator noise. In this work we proposed a parametric model of the bulk acoustic wave (BAW) resonator phase noise based on an equivalent circuit. This model explains phase noise generated by a BAW crystal from a point of view of parametric fluctuations and proves the f−1 dependences of the crystal noise. The model performance is verified with simulation. Simulation results are compared to experimental data and discussed. Comparison of three existing models is made. 相似文献