Optimized IR synchrotron beamline design

Synchrotron infrared beamlines are powerful tools on which to perform spectroscopy on microscopic length scales but require working with large bending‐magnet source apertures in order to provide intense photon beams to the experiments. Many infrared beamlines use a single toroidal‐shaped mirror to focus the source emission which generates, for large apertures, beams with significant geometrical aberrations resulting from the shape of the source and the beamline optics. In this paper, an optical layout optimized for synchrotron infrared beamlines, that removes almost totally the geometrical aberrations of the source, is presented and analyzed. This layout is already operational on the IR beamline of the Brazilian synchrotron. An infrared beamline design based on a SOLEIL bending‐magnet source is given as an example, which could be useful for future IR beamline improvements at this facility.     

Dynamics of magnetic skyrmions

We review the recent progress on the magnetic skyrmions in chiral magnetic materials.The magnetic skyrmion is a topological spin configuration with localized spatial extent,which could be thought of as an emergent rigid particle,owing to its particular topological and chiral properties.Static skyrmionic configurations have been found in various materials with different transport and thermodynamic properties.The magnetic skyrmions respond to externally applied fields in a very unique way,and their coupling to other quasiparticles in solid-state systems gives rise to the emergent electrodynamics.Being not only theoretically important,the magnetic skyrmion is also very promising to be the information carrier in next generation spintronic devices.     

Single-Molecule Magnetism in Dy2 Cluster Based on a Schiff Base Ligand

Two dinuclear Ln^III-based clusters, namely [Dy₂L₂(NO₃)₂(DME)₄] ( 1 ) and [Gd₂L₂(NO₃)₂(DME)₄] ( 2 ) [H₂L = (E)-2-((2-hydroxybenzylidene)amino)phenol] were obtained under hydrothermal condition. Two Ln^III ions are bridged by two phenolic hydroxyl oxygen atoms, and the distances of them are 3.829 Å (Dy1–Dy1A) and 3.860 Å (Gd1–Gd1A). Two Dy1–O–Dy1A and Gd1–O–Gd1A angles are 109.4° and 109.8°, respectively. Magnetic studies reveal a weak antiferromagnetic interaction between Gd ions in complex 2 , and single-molecule magnet behavior for 1 with U_eff = 49.9 K and τ₀ = 1.54 × 10^–6 s.     

基于LabVIEW的超导磁体数采与测控系统研究

根据研制的大口径、高场强的超导强磁装置的特点,选择基于LabVIEW的数据采集和测控系统。低温传感器共六支,分别安装于磁体氦槽和冷屏不同位置,其中碳电阻温度计Cernox三支,铂电阻温度计Pt100两支、Pt1000一只,用于监测磁体温度;超导氦液面计一个,用于监测氦液面高度;根据磁体参数匹配研制了一套可调励磁速率的磁体专用直流电源及其失超保护系统,保证磁体安全运行。所有数据通过NI公司内插DAQ6251数据采集卡的PX I采集,用LabVIEW编写数据采集程序和人机界面。     

欧洲FAIR中超导二极磁体样机的初步设计与分析

介绍了欧洲FAIR超导二极磁体样机设计的背景及设计要求,以及磁体样机的几个大部件及其作用。用有限元分析软件ANSYS进行了线圈电磁性能分析,得到其磁场、电感、储能随电流的变化曲线,并对其中的一个部件线圈盒进行了结构分析,为下一步的设计提供参考。     

高温超导磁体指数损耗分析

本论文对高温超导磁体指数损耗(HTS index loss)的特点进行了分析.通过数值模拟,研究了由20个双饼组成的高温超导磁体在20k的温度下磁体的指数损耗,对每个双饼以及每匝线圈的指数损耗进行了计算,对整个磁体的指数损耗随电流变化情况进行了研究.在磁体的两端加上铁轭改变磁场的分布后,可以看出,铁轭可以有效地减少磁体上的指数损耗.     

带有双X型铁心框架的超导MRI磁体的设计

文中对带有双X型铁心框架的MR I用高温和低温超导磁体的设计进行了介绍,包括项目的市场需求、磁体的基本参数和系统热负荷的预设计结果等。     

直接冷却的高温超导磁体热稳定性有限元仿真

制冷机直接冷却超导磁体是一门新兴技术,研究超导磁体在直接冷却下的热稳定性具有重要意义。用有限元方法解决复杂边界问题的热力学问题非常有效,而有限元分析软件ANSYS能使得用有限元法解决问题更加方便。该文用有限元方法对直接冷却高温超导磁体进行了热稳定性数值仿真。仿真结果表明,在设定热负荷作用下,直接冷却的B i2223系高温超导磁体具有较好的热稳定性,磁体温度低于其临界温度。     

电感耦合等离子体发射光谱法测定记号笔笔芯和墨水中铜和铬

报道了使用ICP-AES测定记号笔芯和墨水中的铜和铬的方法。 主要关注了不同的样品前处理方法的研究。 结果表明: 对标记用的油性记号笔笔芯和含有高分子树脂的墨水, 采用550 ℃灰化, 混合酸(V_HNO3∶V_HClO4=3∶1)溶解的方法处理样品, 是该类样品比较好的处理方法; 而对不含有高分子树脂的墨水, 采用直接用混合酸(V_HNO3∶V_HClO4=3∶1)的消解即可。 消解后的样品经稀酸酸化后, 采用ICP-AES测定铜和铬, 结果准确、稳定。该方法适合记号笔或墨水中元素的测定。     

A theoretical approach to substituent effects: Stabilities and conformational preferences in β-substituted ethyl radicals

Ab initio molecular orbital theory is used to study substituent effects in a series of β-substituted Et radicals XCH₂CH₂. For X = BH₂ (plan.), CH₃, NH₂, OH and F, only slight conformational preferences and weak stabilizations are indicated. Such behaviour may be rationalized, using a PMO model, in terms of opposing changes, accompanying variation in X, in positive and negative hyperconjugation between the XCH₂ group and the CH₂ centre. On the other hand, for groups containing an appropriately oriented, low-lying vacant orbital, viz. X = Li, BeH and BH₂ (perp.), there is a pronounced preference for the perpendicular conformation of the radical. This is attributed to 1,3-interaction between the singly-occupied 2p(C) orbital and the vacant 2p(X) orbital.