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31.
LetW
(x) be a function nonnegative inR, positive on a set of positive measure, and such that all power moments ofW
2(x) are finite. Let {p
n
(W
2;x)}
0
denote the sequence of orthonormal polynomials with respect to the weightW
2(x), and let {A
n
}
1
and {B
n
}
1
denote the coefficients in the recurrence relation
相似文献
32.
H. Wätzig 《Chromatographia》1992,33(5-6):218-224
Summary It is still difficult to determine peaks and peak boundaries properly, though peak recognition is very important for the precision of quantitative data. A new computer program overcomes these problems using a method which is adapted from human judgements. The algorithm was developed for HPLC but can also be used in other fields of analytical chemistry. 相似文献
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Multivariate classification methods were used to evaluate data on the concentrations of eight metals in human senile lenses measured by atomic absorption spectrometry. Principal components analysis and hierarchical clustering separated senile cataract lenses, nuclei from cataract lenses, and normal lenses into three classes on the basis of the eight elements. Stepwise discriminant analysis was applied to give discriminant functions with five selected variables. Results provided by the linear learning machine method were also satisfactory; the k-nearest neighbour method was less useful. 相似文献
35.
36.
Direct CI mass spectrometry profiling of fatty acid methyl esters (FAMEs) from in situ thermal hydrolysis/methylation (THM) of whole bacterial cells with tetramethylammonium hydroxide (TMAH) has been demonstrated as a potential method for real time and fieldable detection/identification of microorganisms. Bacillus anthracis (Ames), Yersinia pestis (Nair. Kenya), Vibrio cholerae (E1 Tor), Brucella melitensis (Abortus wild) and Francisella tularensis (LVS vaccine) were profiled by this method during a 10-month period. Repeatability of the in situ FAME data was calculated using one-way analysis of variance (ANOVA) and a t-test. Artificial neural network (ANN) and multivariate statistics of the FAME profiles were also compared for bacterial identification/classification. Equivalent results were obtained with a multivariate rule building expert system (MuRES) and the ANN. However, the ANN analysis required much less computer time and was deemed the best choice for this application. In situ THM FAME profiles of the bacterial samples provided comparable results with those obtained from the Microbial Identification System (MIDI) (Newark, DE) wet chemistry-gas chromatographic based system. 相似文献
37.
以作者开发的从蛋白质结合部位推导出其界面所具有的疏水性质和氢键性质的计算程序PP_SITE为基础,利用蛋白质结构数据库(PDB),对蛋白质-蛋白质相互作用界面进行了统计分析.从PDB中挑出非冗余的链间相互作用对,计算出这个数据集中所有链间界面的疏水和氢键相互作用特征.对得到的界面特征进行统计分析,寻找能够明显聚类的界面特征.结果表明,界面大小、氢键和疏水相互作用在界面所占比例以及疏水相互作用的集中程度可以作为分类的依据. 相似文献
38.
39.
模式识别—人工神经网络在化学中的若干新应用 总被引:2,自引:0,他引:2
本文通过我们应用模式识别-人工神经网络方法预报新化合物、熔盐相图以及复杂化学反应体系的研究,展示应用模式识别-人工神经网络方法与物理化学理论相结合,研究化学现象的可能性和应用价值。 相似文献
40.
Tsuneo Okubo 《Colloid and polymer science》2006,284(12):1395-1401
Sedimentation and drying dissipative structural patterns formed in the course of drying colloidal silica spheres (1.2 μm in diameter) in aqueous suspension have been studied in a glass dish and a polystyrene dish. The broad ring patterns are formed within a short time in suspension state by the convection flow of water and colloidal spheres. The broad ring patterns are not formed when a dish is covered with a cap, which demonstrates the important role of the convectional flow of silica spheres and water accompanied with the evaporation of water on the air-suspension interface. The sedimentary spheres always move by the convectional flow of water, and the broad ring patterns became sharp with time. Broad ring and microscopic fine structures are formed in the solidification processes on the bases of the convectional and sedimentation patterns. Drying patterns of the colloidal suspensions containing sodium chloride are star-like ones, which strongly supports the synchronous cooperative interactions between the salt and colloidal spheres. 相似文献
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