Preparation of CH3SiO3/2 film from methyltriethoxysilane

An oligomer solution was prepared from methyltriethoxysilane with HNO₃ catalyst. Aluninum acetylacetonate was introudced into the solution to eliminate crystalline precipitates (CH₃SiO_3/2)₈. Self-sustained film was attempted by dropping the solution onto an aqueous solution, into which NaCl was added to elevate the solution density. The film formation greatly depended both on the reaction time and on the supporting solution. The structure of the film thus obtained was investigated by FTIR attenuated total reflectance spectroscopy.     

倒浮萍聚合物LB膜的有序－无序相变研究

倒浮萍聚合物ＬＢ膜的有序－无序相变研究李宏斌，张希，张瑞丰，赵冰，徐尉青，沈家骢，高忠民（吉林大学分子光谱与分子结构开放实验室、化学系，分析测试中心，长春，１３００２３）关键词聚合物ＬＢ膜，有序－无序相变，变温红外光谱，变温小角Ｘ光衍射ＬＢ膜的有序－...     

短波长相变光盘记录介质Ge2Sb2Te5薄膜的制备及静态性能研究

研究了６３２．８ｎｍ波长下适用的相变光盘介质Ｇｅ２Ｓｂ２Ｔｅ５薄膜的制备方法和静态光存诸记录特性，发现该薄膜可在１００ｎｓ条件下实现直接重写，在优化膜层结构后，写擦循环次数高达１０＾６，反射率对比度在１５％以上。     

A thickness independent radiochromic film dosimetry system

A new radiochromic thin film dosimeter has been developed for use in radiation processing. The dosimeter's properties are similar to those of the commercially available FWT-60-00 Radiochromic Detectors with three key differences: 1) a lower sensitivity allows reading the optical density at the peak of the absorbtion spectrum (ca. 600 nm) for absorbed doses to over 50 kGy, 2) a radiation-insensitive dye additive allows for automatic thickness correction, and 3) another additive extends to higher doses the agreement between gamma and E-beam calibrations. The dosimeter is analyzed for its sensitivity, temperature and humidity dependencies, stability, reproducibility, and agreement of gamma and E-beam calibrations.     

Studies of Laser-induced-MOCVDZinc Oxide Films

ＳｔｕｄｉｅｓｏｆＬａｓｅｒ－ｉｎｄｕｃｅｄ－ＭＯＣＶＤＺｉｎｃＯｘｉｄｅＦｉｌｍｓＲＥＮＰｅｎｇ－ｃｈｅｎｇ，ＴＡＮＺｈｏｎｇ－ｋｅａｎｄＬＵＯＷｅｎ－ｘｉｕ（ＣｅｉｉｔｅｒｆｏｒＦｕｎｃｔｉｏｎａｌＭａｔｅｒｉａｌｓＲｅｓｅａｒｃｈ，Ｑｉｎｇｄａ...     

Fluorescence “Turn‐On” Patterning With Polymers Having Pendant Triphenylmethane Groups as Fluorophore Precursors

A new methodology for creating patterned fluorescence images was developed based on acrylate polymers that have pendant triphenylmethane derivatives as precursor fluorophores. Photoinduced oxidation of the substituted nonfluorescent triphenylmethane substituents on the polymers results in the generation of fluorescent cationic species. Patterned fluorescence images were obtained when the polymer film was subjected to photomasked UV‐irradiation. The rate of formation and quality of the patterned images were found to be dependent on the nature of substituents on the methane carbon of the triphenylmethane group. Inefficient image formation takes place with the polymer derived from the H‐substituted derivative owing to the inefficient oxidation of the triphenylmethane group. In contrast, photomasked UV‐irradiation of a thin polymer film derived from the CN‐substituted triphenylmethane derivative leads to fast (1 s irradiation, 12 mW · cm⁻²) and finely resolved patterned fluorescence images.

     

A novel strategy for the preparation of yttria-stabilized zirconia powders: Deposition and scratching of thin films obtained by the sol-gel method

In the present work, an alternative to the traditional sol-gel method is reported. The gel is deposited on a wide flat glassy surface so that a very thin film of solid is obtained after evaporation of the solvent. The yttria-stabilized zirconia powders are recovered by removing the referred film from the glassy surface and subsequent milling. The samples have been characterized by Scanning Electron Microscopy (SEM), nitrogen adsorption at −196 °C and Fourier Transform Infrared (FT-IR) spectroscopy. The experimental results show that the 3 mol% yttria-stabilized zirconia (3YSZ) powders prepared by drying of thin films at 100 °C exhibit extremely low values of specific surface area and pore volumes. Furthermore, the proportion of solvent or the type of alcohol used in the preparation of the powders play a very important role in the textural properties of the 3YSZ powders. In this connection, for samples prepared by varying the propanol proportion an increase in the volume of this solvent leads to larger values of specific surface area and pore volumes. On the other hand, an increase in the molecular size of the alcohol used as the solvent leads to a noticeable development of the textural parameters.     

一种新颖结构的高温超导信道滤波器设计

文章提出了一种新颖结构的高温超导信道滤波器设计方法,采用Sonnet软件进行微带电路的全波电磁场仿真.设计了一个一分二的高温超导信道滤波器,信道滤波器工作在S波段,每个信道的相对带宽约为0.4‰,采用的材料为多源热共蒸发法制备的DyBCO双面超导薄膜,衬底为0.5mm厚度的氧化镁.本文给出了本信道滤波器的等效电路、理论曲线、耦合参数和模拟仿真结果.     

PZT厚膜及高频超声换能器的研究

近年来,基于PZT厚膜的超声换能器研究受到了广泛的重视。本文综述了PZT厚膜制备技术的发展情况,简要介绍了水下声纳和医用超声领域中PZT厚膜型高频超声换能器的应用研制进展。     

用镍硅氧化物源横向诱导晶化的多晶硅薄膜

采用磁控溅射法,以镍硅合金为靶,制备了一种适用于金属诱导横向晶化的氧化物镍源——自缓释镍源.该镍源在内部构成和晶化现象上都不同于纯金属镍源.采用该镍源制备低温多晶硅材料,晶化速率不明显依赖于镍源薄膜的厚度,且晶化多晶硅膜内的残余镍量亦可有效降低,可为薄膜晶体管提供宽的工艺窗口.本文对用纯金属镍源所得多晶硅薄膜的晶化率、表面粗糙度、电学特性等与溅射条件的关系进行了研究,并对相应结果进行了讨论. 关键词： 自缓释 金属诱导横向晶化 多晶硅薄膜 低温制备与退火