氧分压对Ni/HfO_x/TiN阻变存储单元阻变特性的影响

采用射频磁控溅射的方法,基于不同氧分压制备的氧化铪构建了Ni/HfO_x/TiN结构阻变存储单元.研究发现,随着氧分压的增加,薄膜表面粗糙度略有降低;另一方面,阻变单元功耗降低,循环耐受性能可达10~3次,且转变电压分布的一致性得到改善.结合电流-电压曲线线性拟合结果及外加温度测试探究了器件的转变机理,得出在低阻态的传导机理为欧姆传导机理,在高阻态的传导机理为肖特基发射机理,并根据氧空位导电细丝理论,对高低阻态的阻变机理进行了详细的理论分析.     

可见/红外宽光谱分色片偏振调控的设计

针对光学系统中可见/红外宽光谱分色片的偏振特性,采用诱导透射法设计了满足偏振遥感光学系统能量要求的可见/红外宽光谱分色片,并对其偏振特性进行了分析.通过计算获得了透射带400～900 nm可见/红外宽光谱分色片的偏振情况,采用等效层理论在其基底背面设计了偏振调控膜系,对分色片透射带的偏振度加以调控.使用needle优化...     

1.06μm连续激光辐照TiO_2/SiO_2/K_9薄膜元件温升规律研究

利用1.06μm连续激光在不同强度下辐照TiO2/SiO2/K9薄膜元件,实验中用红外热像仪测量激光辐照在TiO2/SiO2/K9元件表面引起的温升随时间的变化,通过数据处理,获得激光辐照区域最高温度随辐照时间的增加而增加。同时,给出材料温升随材料发射率的变化关系。并用程序模拟不同激光强度下薄膜温度场的分布,通过实验测量数据校正数值模拟计算结果,给出TiO2/SiO2/K9薄膜元件温度随激光辐照强度和辐照时间的变化规律。并且获得在薄膜厚度方向:薄膜表面温度最高,基底与薄膜接触处温度最低;沿径向:激光辐照中心温度最高,边沿温度最低。     

电聚合β-环糊精修饰电极的制备及其对铜离子的检测

采用循环伏安法(CV),由β-环糊精(β-CD)单体在玻碳电极(GCE)表面电聚合制得聚β-CD膜修饰电极(β-CD/GCE)。实验表明,β-CD/GCE对Cu2+具有明显的电催化作用,在pH=5.85的磷酸盐缓冲溶液(PBS)中,Cu2+浓度与其峰电流在4.01×10-4～1.05×10-7 mol·L-1范围内呈良好的线性关系,线性方程为:ip=-1.975c-1.336×10-4(i:A,c:mol·L-1),相关系数R=0.9981,检出限(S/N=3)为5.03×10-8mol·L-1。方法应用于实际样品测定,回收率在98.0%～103%之间。     

厚胶光刻非线性畸变的校正

利用厚胶光刻技术制作大深度微结构元件是一种有效的途径,但厚胶光刻过程中的非线性畸变对光刻面形质量的严重影响限制了该技术的应用,基于此,提出了一种对掩模透射率函数进行校正的方法。分析空间像形成及其在光刻胶内传递、曝光、显影等过程中非线性因素的影响,利用模拟退火算法对掩模透射率函数进行校正,以提高光刻面形质量,并以凹面柱透镜为例,给出了校正前后的显影轮廓模拟结果,其校正后浮雕面形的体积偏差仅为2.63%。该方法在有效改善面形质量的同时,并没有引起掩模的设计、制作难度及费用增加,这对于设计、制作高质量的微结构元件有重要意义。     

两种方法制备ITO薄膜的红外特性分析

比较了用电束加热蒸发法和直流磁控溅射法制备的氧化锡铟(ITO)薄膜在红外波段的光学特性实验发现,通过直流磁控溅射在常温下制备的ITO薄膜在红外波段折射率稳定、消光系数小,比电子束加热蒸发制备的膜有较高的透过率在波长1550nm附近的透过率可达86%以上,消光系数约为004,方电阻最低为100Ω/□.     

臭氧化法表面改性聚苯乙烯薄膜

 为增强聚苯乙烯(PS)与聚乙烯醇(PVA)之间的结合力,进而提高PS-VA双层空心微球存活率。利用臭氧化改性法在酸性介质中对聚苯乙烯薄膜进行表面改性,用红外光谱对处理后的表面进行了半定量的分析。结果表明：改性过后聚苯乙烯表面产生羟基、羰基等极性基团;接触角测试证明,处理后的表面由憎水变为亲水,并通过纳米压痕划痕法得到了处理前后PS与PVA薄膜之间的相互作用强度,臭氧化改性后PS与PVA膜间作用强度增大了40%。     

Effect of ultrasonic irradiation on structure and electrochemical properties of LiMn2O4 thin films cathode material for Li-ion micro-batteries

Two kinds of spinel LiMn₂O₄ thin film for lithium ion micro-batteries were successfully prepared on polycrystal Pt substrates by spin coating methods, which were carried out under ultrasonic irradiation (USG) and magnetic stirring (MSG), respectively. The microstructures and electrochemical performance of LiMn₂O₄ thin films were characterized by thermogravimetry analysis (TGA), X-ray diffraction (XRD), scanning electron microscopy (SEM), and galvanostatic charge-discharge measurements. It was found that the crystalline structure of USG samples grew better than that of the MSG samples. At the same time, higher discharge capacity and better cycle stability were obtained for the LiMn₂O₄ thin films of USG at the current density of 50 μAh/cm² between 3.0 and 4.3 V. The 1st discharge capacity was 57.8 μAh/cm²-μm for USG thin films and 51.7 μAh/cm²-μm for MSG thin films. After 50 cycles, 91.4% and 69% of discharge capacity could be retained respectively, indicating that ultrasonic irradiation condition during spin coating was more suitable for preparing spinel LiMn₂O₄ thin films with better electrode performance for lithium ion micro-batteries.     

用于高温等离子体实验的C_8H_8簿膜

一、引言 在核聚变、X射线激光和激光等离子体的研究中,对高温等离子体辐射的X射线诊断,是了解等离子体与激光相互作用的最基本的手段之一。对激光等离子体X射线光谱的分析认为,X射线光子能量在1keV附近的产额最高,所带的信息量亦最丰富,因此人们对等离子体的诊断研究大都集中在这一软X射线波段上。而用于该波段的各类探测器所需要的滤     

A Novel Electrogenerated Chemiluminescence (ECL) Sensor Based on Ru(bpy)32+‐Doped Titania Nanoparticles Dispersed in Nafion on Glassy Carbon Electrode

A novel electrogenerated chemiluminescence (ECL) sensor based on Ru(bpy)₃²⁺‐doped titania (RuDT) nanoparticles dispersed in a perfluorosulfonated ionomer (Nafion) on a glassy carbon electrode (GCE) was developed in this paper. The electroactive component‐Ru(bpy)₃²⁺ was entrapped within the titania nanoparticles by the inverse microemulsion polymerization process that produced spherical sensors in the size region of 38±3 nm. The RuDT nanoparticles were characterized by electrochemical, transmission electron and scanning microscopy technology. The Ru(bpy)₃²⁺ encapsulation interior of the titania nanoparticles maintains its ECL efficiency and also reduces Ru(bpy)₃²⁺ leaching from the titania matrix when immersed in water due to the electrostatic interaction. This is the first attempt to prepare the RuDT nanoparticles and extend the application of electroactive component‐doped nanoparticles into the field of ECL. Since a large amount of Ru(bpy)₃²⁺ was immobilized three‐dimensionally on the electrode, the Ru(bpy)₃²⁺ ECL signal could be enhanced greatly, which finally resulted in the increased sensitivity. The ECL analytical performance of this ECL sensor for tripropylamine (TPA) was investigated in detail. This sensor shows a detection limit of 1 nmol/L for TPA. Furthermore, the present ECL sensor displays outstanding long‐term stability.