用于高温等离子体实验的C_8H_8簿膜

一、引言 在核聚变、X射线激光和激光等离子体的研究中,对高温等离子体辐射的X射线诊断,是了解等离子体与激光相互作用的最基本的手段之一。对激光等离子体X射线光谱的分析认为,X射线光子能量在1keV附近的产额最高,所带的信息量亦最丰富,因此人们对等离子体的诊断研究大都集中在这一软X射线波段上。而用于该波段的各类探测器所需要的滤     

掺Bi钇铁石榴石薄膜光波导的线性双折射及消除方法

分析了光的线性双折射对磁光波导ＴＥ－ＴＭ模式转换，法拉第旋转，波导光隔离器隔离比及插入损耗的影响。研究了掺Ｂｉ钇铁石榴石薄膜光波导中的形状线性双折射，应力感生线性双折射及生长感生线性双折射的来源，特性和消除方法。     

Ionic conductivity of conjugated water-soluble rigid-rod polymers

Poly[(1,7-dihydrobenzo[1,2-d:4,5-d′] diimidazole-2,6-diyl)-2-(2-sulfo)-p-phenylene], a conjugated rigid-rod polymer, was derivatized with pendants of propane-sulfonated ionomers. The derivatized rigid-rod polymer was soluble in aprotic solvents as well as in water for isotropic solutions that were processed into isotropic films. Direct-current electrical conductivity σ of the films was measured using the four-probe technique. Room-temperature σ as high as 2.9 × 10^?4S/cm was achieved on pristine isotropic films without using dopants. When the rigid-rod polymer concentration exceeded 25 wt %, the isotropic solution could be transformed into a liquid-crystalline solution that allowed deformations to be applied to produce anisotropic films. Significant increase in σ was obtained in a sheared film along both the parallel direction (∥) and the transverse direction (⊥) with a σ_∥/σ_⊥ = 5. Additionally, enhanced σ was realized in films heat-treated at about 100°C, in the derivatized polymer with higher molecular weight from dialysis, and in substituting the sulfonated ion Na⁺ by H⁺ in the pendants of the polymers. Constant-voltage measurements were applied to the polymers to monitor the σ stability for ascertaining the nature of the conductivity. No electronic contribution in σ was detected. Instead, a monotonically decreasing σ was consistently observed indicative of ionic conductivity. © 1993 John Wiley & Sons, Inc.     

Stability analysis of gravity driven shear flows with free surface for power-law fluids

Summary We study the stability of thin films of fluids subject to gravity along inclined planes, obeying a power-law constitutive relation of the Ostwald-de Waele type. A first analysis, in which the inertia terms are ignored, shows such flow to be stable against small, linear perturbations; a second analysis, in which the inertia terms are included, proves that there are stable and unstable regimes that are separated by a critical Ostwald-de Waele number O. Numerical computations for selected values of O demonstrate the decay and growth rate behavior of some finite amplitude disturbances. Received 12 May 1997; accepted for publication 23 July 1997     

激光光控超导YBa2Cu3Ox薄膜开关的研制

在对光控热电效应开关进行理论分析的基础上,木文提出用YBa₂Cu₃O_x薄膜制作光控开关,并测试了在液氮温度下薄膜开关在不同激光波长下的特征参数,测试的最好结果是响应度R_v(632.8nm,10kHz,1Hz)为217V/W,归一化探测率D_*(632.8nm,10kHz,1Hz)为2.3×10¹¹cm.Hz^1/2/W,响应时间τ为0.21ms.     

组装L-B膜光学二次谐波的实验研究

一种分子形成的多层L-B膜由于相邻层的分子取向相反而使非线性极化抵消,总的X~(2)=0.本文用光学二次谐波方法确定了带有不同极性基团的L-B单分子层的有效非线性系数的大小和符号,对有效非线性系数符号相反的两种单分子层交替组装,使相邻单分子层的非线性极化相互叠加,得到了具有较大二阶非线性系数的组装L-B膜.     

Comparison of two turbulent models in simulating evaporating liquid film in a wiped molecular distillator

Wiped molecular distillation is one kind of molecu-lar distillations, and its difference from others comes from the force by which the evaporating liquid film is formed. With quick rotation of the wiper, the liquid becomes thin-film well distributed on th…     

A new,improved sensor for ascorbate determination at copper hexacyanoferrate modified carbon film electrodes

A new, improved sensor for the electrocatalytic determination of ascorbate has been developed that has both a low applied operating potential and a low detection limit. The sensor was constructed by depositing copper hexacyanoferrate film either electrochemically or chemically onto carbon film electrode, and it was then characterised by cyclic voltammetry and electrochemical impedance spectroscopy. Chemically deposited films were shown to be the best for ascorbate determination and were used as an amperometric sensor at +0.05 V versus SCE to determine ascorbate in wines and juice. The linear range extended to 5 mM with a limit of detection of 2.1 M, the sensor was stable for more than four months, and it could be used continuously for at least 20 days.     

Amperometric PMMA-microchip with integrated gold working electrode for enzyme assays

The use of a gold film in-channel detector combined with a poly(methyl methacrylate) (PMMA) CE microchip has been tested for alkaline phosphatase (AP) enzymatic assays. Tris-borate or Tris-Gly (pH 9.0, 50 mmol L^–1) buffer solutions were appropriate as running buffer. Signals for three common AP products: -naphthol, p-nitrophenol, and ascorbic acid, were obtained. They were reproducible (RSD 4.4% for six successive electropherograms corresponding to 5 mmol L^–1 -naphthol solution) and the response was dependent on concentration (linear relationship for ascorbic acid solutions between 5 and 20 mmol L^–1 concentration). Use of an end-channel gold film electrode was also investigated. If one of the reagents (substrate or enzyme) is included in the running buffer, two different types of enzymatic assay are feasible in less than 3 min.     

Correlation between rheological behaviour in uniaxial elongation and film blowing properties of various polyethylenes

Six various low density polyethylenes and one blend were rheologically characterized in elongation. Their different strain-hardening behaviour could qualitatively be related to their molecular structure. All the materials were blown to films on laboratory equipment under various conditions. The take-up force and the film homogeneity were determined quantitatively, the bubble stability was visually assessed. The bubble stability increased with growing take-up force. The take-up force was found to be the stronger the higher the elongational viscosity was. The homogeneity of film thickness is not related to the bubble stability but to the occurrence of strain hardening in the uniaxial elongational experiment at high Hencky strains. Measurements of the uniaxial elongational behaviour of polyethylene melts are a valuable and promising way to assist the development and optimisation of film blowing materials.