Syntheses and Vasodilatory Activities of New Pyrazolo [ 4,3-d ] pyrimidin-7-ones

IntroductionAdenosine 3′,5′-cyclic monophosphate (cAMP)and guanosine 3′,5′-cyclic monophosphate(cGMP) areubiquitous second messengers that mediate biologicalresponses to a variety of extracellular cues, includinghormones, neurotransmitters, chemokines…     

Three-dimensional steady supersonic duct flow using Lagrangian formulation

In this paper, numerical simulation of three-dimensional supersonic flow in a duct is presented. The flow field in the duct is complex and can find its applications in the inlet of air-breathing engines. A unique streamwise marching Lagrangian method is employed for solving the steady Euler equations. The method was first initiated by Loh and Hui (1990) for 2-D steady supersonic flow computations and then extended to 3-D computation by the present authors Loh and Liou (1992). The new scheme is shown to be capable of accurately resolving complicated shock or contact discontinuities and their interactions. In all the computations, a free stream of Mach numberM=4 is considered.This article was processed using Springer-Verlag T_EX Shock Waves macro package 1.0 and the AMS fonts, developed by the American Mathematical Society.     

Low-energy ion-assisted control of interfacial structures in metallic multilayers

A molecular dynamics method has been used to simulate the argon ion-assisted deposition of Cu/Co/Cu multilayers and to explore ion beam assistance strategies that can be used during or after the growth of each layer to control interfacial structures. A low-argon ion energy of 5–10 eV was found to minimize a combination of interfacial roughness and interlayer mixing (alloying) during the ion-assisted deposition of multilayers. However, complete flattening with simultaneous ion assistance could not be achieved without some mixing between the layers when a constant ion energy approach was used. It was found that multilayers with lower interfacial roughness and intermixing could be grown either by modulating the ion energy during the growth of each metal layer or by utilizing ion assistance only after the completion of each layers deposition. In these latter approaches, relatively high-energy ions could be used since the interface is buried and less susceptible to intermixing. The interlayer mixing dependence upon the thickness of the over layer has been determined as a function of ion energy.     

YZr2OZr3:Er3+纳米晶anti-Stokes发光性质的研究

采用均相沉积法制备了不同Er³⁺离子浓度掺杂的Y₂O₃纳米晶, 应用XRD，SEM和PL光谱对该体系材料进行了表征.在Y₂O₃:Er³⁺纳米材料体系中, 观察和研究了Stokes及anti-Stokes PL谱强度与Er³⁺离子摩尔浓度变化的关系, 当Er³⁺离子浓度为2.0mol%时, anti-Stokes PL强度最强.粉末X 关键词： 氧化钇纳米晶 anti-Stokes PL 双光子吸收     

利用KTP晶体实现1.08μmNd：YAP激光器锁模

本文描述了利用ＫＴＰ晶体和腔的基波输出镜构成非线性镜实现１．０８μｍＮｄ：ＹＡＰ激光器的被动锁模。实验表明，这种新的锁模技术比用染料作可饱和吸收体的被动锁模技术有很多突出的优点，具有很大的发展潜力。实验测得锁模时基波１．０８μｍ输出２．４ｍＪ，二次谐波０．５４μｍ输出０．５ｍＪ（同样条件下的静态输出为２．５ｍＪ），基波脉冲的平均脉宽为４０ｐｓ。     

镁掺杂对In2O3电导和气敏性能的影响

用共沉淀法制备了Mg2 + 掺杂的In2 O3 纳米粉 ,研究了镁掺杂对In2 O3 电导和气敏性能的影响 .结果表明 :MgO和In2 O3 间可形成有限固溶体In2 -xMgxO3 (0≤x≤ 0 .40 ) ;MgIn× 电离的空穴对材料导带电子的湮灭 ,使掺镁纳米粉的电导变得很小 ;n(Mg2 + )∶n(In3 + ) =1∶2共沉淀物于 90 0℃下热处理 4h ,用所得的纳米粉制作的传感器在 32 0～ 370℃下 ,对 45 μmol/LC2 H5OH的灵敏度达 10 2 .5 ,为相同浓度干扰气体Petrol的 12倍多 .     

The growth of Pd thin films on a 6H-SiC(0 0 0 1) substrate

Pd thin films, grown on Si-rich 6H-SiC(0 0 0 1) substrates, were studied by atomic force microscopy, electron diffraction and high-resolution transmission electron microscopy. It is concluded that the growth is successful only when all the growth process takes place at room temperature. Under these conditions a very good epitaxial growth of Pd is achieved, despite the large misfit (about 8.6%) between Pd and the substrate and the existence of a semi-amorphous layer between the thin film and the substrate. A large number of twins appear in these films.     

Synthesis and characterization of poly(higher‐α‐olefin)s with a nickel(α‐diimine)/methylaluminoxane catalyst system: Effect of chain running on the polymer properties

Homopolymerization of octadecene‐1 at different reaction conditions has been studied. Significant chain running can be seen at higher polymerization temperatures. Interestingly, insertion of octadecene‐1 into a sterically hindered nickel‐cation/carbon (secondary) bond is observed. The microstructure of the polymer was established using NMR spectroscopy. The effects of chain running on polymer melting, crystallization behavior, and dynamic mechanical thermal properties were studied using DSC and DMTA. The extent of chain running (i.e., 2,ω‐, 1,ω‐enchainments) decreases with an increase in the carbon number of α‐olefins. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 191–210, 2007     

Transformations of <Emphasis Type="Italic">N</Emphasis>-ethylamines into amide derivatives under the action of sulfur monochloride

Tertiary N-ethylamines were converted into amide derivatives by reactions with sulfur monochloride and DABCO at 0 °C. Depending on the nature of the substituents in the amine, the reaction can be accompanied by unexpected transformations. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1135–1140, June, 2007.