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61.
Photo-induced surface grafting with glycidyl methacrylate (GMA) as monomer in association with a pad-curing treatment by using a flame retardant (FR) solution which contains 1-hydroxy ethylidene-1,1-diphosphonic acid (HEDP) and sulfamic acid (H2NSO3H) has been used to improve the fire performance of PET fabric in this study. The effects of initiator concentration, monomer concentration and the irradiation time on the grafting percentage were investigated. The chemical structure of grafted surface of the PET fabric was characterized by an attenuated total reflection-infrared (ATR-IR) spectroscopy. The fire performance was evaluated by the LOI and the vertical flammability tests, and the results indicate that the photo grafting treatment could improve the flame retardancy and dripping resistance of PET fabric. Thermal behaviour of treated PET fabric samples was investigated by thermogravimetric (TG) and differential scanning calorimetric (DSC). The morphology of the sample char residue was also investigated by scanning electron microscope (SEM). 相似文献
62.
本文合成了正电子发射断层显像剂[18F]FET的两个新型前体:N-叔丁氧羰基-O-(2-三氟甲磺酰氧乙基)-L-酪氨酸甲酯9a和N-叔丁氧羰基-O-(2-三氟甲磺酰氧乙基)-L-酪氨酸叔丁酯9b. 化合物9a或9b以L-酪氨酸为原料, 先与甲醇发生酯化反应或与乙酸叔丁酯进行酯交换, 再用叔丁氧羰基保护氨基, 接着在苯环的酚羟基上引入羟乙基, 最后与三氟甲磺酸酐反应形成目标化合物, 这四步反应总收率分别是30%或15%. 相似文献
63.
通过含有KI的聚乙二醇(PEG)与PET熔融共混制得导电聚合物,其在常温下电阻率可达到105Ω.cm左右,电阻率随温度升高而降低,具有离子导电的特性.通过FTIR、DSC和偏光显微镜研究其形态结构和热性能,结果表明该导电聚合物中PEG和PET主要是物理共混,晶区不相容,非晶区具有部分相容性,熔融降温发生相分离,KI/PEG形成连续的一相.该导电聚合物作为导电母粒与PET切片以不同的配比共混纺丝制备出颜色较浅的导电PET纤维.当纤维中导电母粒的质量分数超过10 wt%时,制得的导电纤维的电阻率为106Ω.cm左右,具有较好的耐水洗性.该导电纤维具有双连续相结构,连续的KI/PEG导电相因形成导电通路使纤维具有导电性能;连续的PET相使纤维基本保持PET纤维的力学性能. 相似文献
64.
Young′s moduli of various epoxy coated polyethylene terephthalate (PET) micro-cantilevers were determined from the deflection results obtained using the phase-shift shadow moiré (PSSM) method. The filler materials for epoxy coatings were aluminum and graphite powders that were mixed with epoxy at various percentages. Young′s moduli were calculated from theory based on the deflection results. The PET micro-cantilever coated with aluminum-epoxy coating showed increasing value of Young′s modulus when the ratios of the aluminum-epoxy were increased. The graphite-epoxy coating on the PET micro-cantilever also showed the same trend. The experimental results also show that Young′s modulus of the graphite-epoxy coating is higher than aluminum-epoxy coating in comparison at the same mixing ratio. 相似文献
65.
Site-specific conjugation of proteins is currently required to produce homogenous derivatives for medicine applications. Proteins derivatized at specific positions of the polypeptide chain can actually show higher stability, superior pharmacokinetics, and activity in vivo, as compared with conjugates modified at heterogeneous sites. Moreover, they can be better characterized regarding the composition of the derivatization sites as well as the conformational and activity properties. To this aim, several site-specific derivatization approaches have been developed. Among these, enzymes are powerful tools that efficiently allow the generation of homogenous protein–drug conjugates under physiological conditions, thus preserving their native structure and activity. This review will summarize the progress made over the last decade on the use of enzymatic-based methodologies for the production of site-specific labeled immunoconjugates of interest for nuclear medicine. Enzymes used in this field, including microbial transglutaminase, sortase, galactosyltransferase, and lipoic acid ligase, will be overviewed and their recent applications in the radiopharmaceutical field will be described. Since nuclear medicine can benefit greatly from the production of homogenous derivatives, we hope that this review will aid the use of enzymes for the development of better radio-conjugates for diagnostic and therapeutic purposes. 相似文献
66.
Hao Ouyang Wen‐Hao Lee Sham‐Tsong Shiue Tsang‐Lang Lin 《Journal of Polymer Science.Polymer Physics》2002,40(14):1444-1453
Solvent transport in poly(ethylene terephthalate) (PET) and related phase transformation were investigated. The data of mass sorption were analyzed according to Harmon's model for Case I (Fickian), Case II (swelling), and anomalous transport. This transport process in PET is accompanied by the induced crystallization of the original amorphous state. The transformation was examined by wide‐angle X‐ray scattering, small‐angle X‐ray scattering, differential scanning calorimetry, and Fourier transform infrared spectroscopy. During this process, the matrix is under a strain state that causes different kinetic paths of crystallization as compared with that by thermal annealing. This state of strain assists the development of the solvent‐induced crystallization. The model regarding crystallization was proposed in terms of the study of long period L, the crystal thickness lc, and the thickness of amorphous layer la obtained from the one‐dimensional correlation function and interface distribution function. Different kinetic paths were discovered for different crystallization processes. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1444–1453, 2002 相似文献
67.
68.
D.M. Svirachev 《Applied Surface Science》2007,253(9):4232-4241
In the following paper, empirical constants are determined by a plasma-chemical model and experimental data of the wetting contact angle. The constants characterize the alteration of the contact angle as a function of the time of the polymer treatment and the kind of the plasma-creating gas. The presented equations of the model connect the contact angle with the empirical constants for arbitrary time intervals of treatment and arbitrary percentage content of the researched gas mixtures and gasses. The chemical rate constants, which describe the process of the plasma modification of the polymer material, are determined. 相似文献
69.
This investigation examines non-Newtonian flow mechanisms and heat transfer characteristics for a micro spinneret. The working fluid, Polyethylene terephthalate (PET), is the raw material of micro fiber, and a large-scale experimental test model was designed to visualize the complex viscous flow system in the micro spinneret. To visualize the complex convective flow system, an experimental test model was constructed, using glycerin instead of PET. The related parameters of PET were compared with those of glycerin. The power law correlates the shear strain with PET viscosity at various temperatures. The pressure distribution along the flow direction was measured and the flow pattern was visualized using polyethylene (PE) powder of 20–40 m. Similar configurations were calculated for micro spinneret physical parameters to determine the thermal flow characteristics. The Reynolds number in the test model is not less than 10–2. In the non-Newtonian PET working fluid of practical micro spinneret, flows with Re = 104 to 10–2 are in the same low Reynolds number flow regime. Therefore, the working fluid is expected to have the same flow characteristic. A numerical solution covering the range of approximately Re = 10–4 at PET confirms that the flow characteristics of glycerin are constant for Re = 1.228 × 10–2. The Peclet number in the test model can be adjusted to a value similar to that in the micro spinneret. The flow visualization was compared with that of the numerical solution, and the friction factor and Nusselt number in the micro spinneret were analyzed. Finally, numerical results and friction factor with various exit angles of micro spinneret in a triangular zone flow system were also summarized. 相似文献
70.
Comparison of copolymer emulsions of fluorine and siloxane‐containing acrylates with core–shell structure for water‐repellent cotton fabrics coatings
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J. Lin C. Zheng M. N. Zhu Y. Z. Chen P. P. Lu Q. Liu X. F. Cai J. W. Zhuang X. M. Cai L. P. Liao G. Y. Yuan C. L. Xu 《先进技术聚合物》2015,26(1):68-76
This paper described the synthesis of copolymer emulsions of fluorine and siloxane‐containing acrylates for water‐repellent cotton fabrics coatings. Chemical composition, morphology structure, and properties of the latex copolymers were investigated by Fourier transform infrared (FTIR), dynamic light scattering (DLS), gel permeation chromatography (GPC), and transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). Effects of water‐repellent functional monomers (Rf) on surface morphology, water contact angle, and water‐repellent properties of the coated fabric surface were also studied. The results indicated that Rf greatly influenced molecular mass distribution of the latex copolymers, the molecular aggregation states and orientation of Rf on the coated fabric surface, and water‐repellency of coated cotton fabrics. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献