CaCO3/PEEK复合体系的力学行为和热行为研究

以聚醚醚酮和碳酸钙复合体系为研究对象,考察了偶联剂和填料添加量对复合材料力学行为和热行为的影响.发现磺化聚醚醚酮作为偶联剂能有效地改善材料的力学性能,提高基体树脂的玻璃化转变温度,降低基体树脂的熔点,有助于改善聚醚醚酮的加工条件     

热历史对聚醚醚酮及其碳纤维复合材料——Ⅱ.熔融行为的影响

本文利用差示扫描量热仪(DSC)研究了聚醚醚酮(PEEK)和以PEEK为基体的碳纤维复合材料(APC-2)的热历史对它们熔融行为的影响。在200—315℃结晶并退火热处理后,试样的DSC曲线上出现了两个吸热峰。低温吸热峰(峰温T′_m)较小,并与结晶和退火温度(T_c)有关;高温吸热峰(峰温T_m)较大,几乎不受T_n的影响。T′_m的出现与在不同T_c下生成的不完整晶体的熔融和重结晶过程有关,而T_m的出现则与完整晶体的熔融过程有关。实验结果表明,T′_m与T_c之间呈线性关系。按文献报道的方法,将T′_m与T_c的直线外推至与T′_m=T_c直线相交,其交点温度即为平衡熔点.结果表明,PEEK和APC-2试样的“平衡熔点”受不同热历史条件下生成晶体的完整程度的影响。当结晶并退火时间越长,求出的“平衡熔点”值越低,并与理论值接近。实验结果还表明,碳纤维表面具有促进PEEK树脂基体晶体完整化的作用,因而导致APC-2试样中PEEK树脂基体的熔点高于纯PEEK树脂。     

发蓝光聚醚醚酮材料的合成及其光电特性

通过4-羟基苯甲醛与2,6-二(4-氯甲基苯基)苯并[1-2,4-5′]二唑之间的Wittig反应,制备了具有蓝色荧光特性的小分子单体2,6-二{4-[2-(4-羟基苯基)乙烯基]苯基}苯并[1-2,4-5′]二唑,在碳酸钾的催化作用下,通过其与4,4′-二氟二苯甲酮的缩聚反应,设计并合成了以均二苯乙烯为共轭母核的可发射蓝光的聚醚醚酮材料(BOE-PEEK),并对其结构进行了表征.测定结果表明,该聚合物的平均分子量(-Mw)为1.38×10⁵,均分散系数(PDI)为4.35,玻璃化温度(T_g)为195℃,热分解温度(T_d)为440℃,BOE-PEEK在二甲基乙酰胺(DMA)溶剂中的UV-Vis吸收光谱(λ_max)为372 nm,荧光光谱(λ_max)为455nm,由导电玻璃/发光层/金属铝电极(ITO/BOE-PEEK/Al)组成的单层器件在电压15 V时,发光亮度达530 cd·cm^-2,发光效率为0.36 cd/A.     

The effect of proton irradiation on the melting and isothermal crystallization of poly(ether‐ether‐ketone)

Amorphous poly(ether‐ether‐ketone) (PEEK) progressively crosslinks on irradiation with 11.0 MeV protons, and this has a marked effect on the extent of crystallinity that subsequently develops and on the kinetics of the high temperature isothermal crystallization. The extent of crystallinity with time was analyzed using the Avrami equation, and the temperature dependence of the rate constants was analyzed in terms of nucleation theory. While irradiation inhibits the overall rates of crystallization by the reduction in the mobility of the chain segments as observed by the progressive increase in the glass transition temperature, it also alters the fold surface free energy. The observed melting points were consistent with depression of the equilibrium melting point by the crosslinks produced by irradiation. These two effects alone are sufficient to account for the inhibition of crystallization on irradiation of PEEK by protons. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 1094–1103, 2008     

Hot tensile fracture characteristics and constitutive modelling of polyether-ether-ketone (PEEK)

The effects of strain rate and deformation temperature on the deformation behaviors of polyether-ether-ketone (PEEK) were studied by uniaxial tensile tests with the temperature range of 23–150 °C and strain rate of 0.01–1 s⁻¹. The effects of deformation temperature and strain rate on the hot tensile deformation behavior and fracture characteristics were investigated by scanning electron microscope (SEM) and discussed in detail. SEM experimental results suggest that fracture morphology is not strain rate sensitive but temperature sensitive. Based on the tensile results, the Johnson-Cook and modified Johnson-Cook constitutive models were established for PEEK. Furthermore, a comparative study has been made on the accuracy and effectiveness of the developed models to predict the flow stress. The results show that the original Johnson-Cook model reflects the deformation behavior more accurately throughout the entire test temperature and strain rate range under uniaxial tensile conditions.     

Solvent-induced crystallinity in poly(aryl-ether-ether-ketone) [PEEK]

The amount and structure of the crystals formed by the solvent-induced crystallization (SIC) following a sorption-desorption cycle of five fluids (benzene, toluene, chloroform, methylene chloride, and carbon disulfide) in amorphous PEEK was determined by wideangle x-ray scattering (WAXS). The SIC crystal structure was compared with that produced by thermal methods, both those formed at low temperature by heating the amorphous material 10–20°C above T_g or by cooling from the melt. Although smaller in size, the SIC crystals are tighter and more organized than those produced thermally. The WAXS data indicates that all five fluids produce approximately 35% crystallinity in PEEK. Gravimetric data suggest that a low-density region, consisting of either microvoids or highly disordered amorphous region, surrounds the crystals.     

厚热塑性复合材料AS4/PEEK角铺设层合板的层间应力分析

将表征热塑性复合材料AS4 /PEEK非线性行为和应变速率相关行为的三维弹塑性模型通过程序加以实现。将程序计算结果和文献实验结果相比较可以发现,二者吻合较好,验证了所生成程序的有效性。计算了厚的AS4 /PEEK角铺设层合板[±25]s4在不同界面上的层间应力。由层间应力的三维分布图,分析了不同界面上层间应力的分布特征,并说明了可能引起层间分层的主要因素。     

Liquid phase microextraction applications in food analysis

Over the last years, liquid-phase microextraction (LPME) in its different application modes (single drop microextraction, dispersive liquid-liquid microextraction and hollow fiber-LPME) has been increasingly applied for the extraction of both inorganic and organic analytes from different matrices. Its advantages over conventional extraction procedures (simplicity, effectiveness, rapidity and low consumption of organic solvents) has also attracted its application in the complex food analysis field, in which it has clearly provided good and challenging results. A comprehensive review dealing with those articles published since its introduction till the end of March 2011 is presented, offering also a critical vision of the analytical potential of LPME for the analysis of foods.