Y2Ti2O7:Tm3+的制备及其发光性能研究

采用溶胶-凝胶法(Sol-gel)制备了不同烧结温度和Tm³⁺掺杂浓度的Y₂Ti₂O₇:xTm (x=0.005,0.01,0.03,0.05)荧光粉,分别采用X射线衍射分析仪(XRD)、透射电子显微镜(TEM)和荧光光谱仪对样品的晶型结构、形貌以及发光性能进行了表征。XRD结果表明,所得到的样品为单一立方相烧绿石结构。样品在361 nm紫外光激发下发射出 蓝光,其峰值波长为456 nm,对应于Tm³⁺的¹D₂→³F₄跃迁。1 000 ℃烧结的Y₂Ti₂O₇: 0.01Tm³⁺样品具有较好的发光性能。样品在456 nm处的相对发光强度随Tm³⁺掺杂浓度的增大先升高后降低,在Tm³⁺摩尔分数为1%时达到最大,即出现了浓度猝灭现象。     

YVO_4∶Eu~(3+)@SiO_2核壳结构纳米复合材料的合成与表征

用沉淀法制备了尺寸约为8 nm的YVO4∶Eu3+纳米粒子,然后用反相微乳液法在YVO4∶Eu3+纳米粒子的表面包覆了一层Si O2壳。利用XRD、TEM、UV-Vis吸收光谱和光致发光光谱对合成的样品进行了表征。得到的复合物具有较好的核壳结构,通过改变硅酸四乙酯的用量可以改变Si O2壳的厚度。研究了Si O2壳对YVO4∶Eu3+发光性质的影响,结果表明:包覆和未包覆的样品在紫外光激发下都有Eu3+的特征发射;随着Si O2壳厚度的增加,发光强度和量子效率越来越低,Eu3+格位对称性越来越高。     

Chronoamperometric determination of lead ions using PEDOT:PSS modified carbon electrodes

A new simple chronoamperometry methodology was developed for the ultrasensitive determination of lead ions using a PEDOT:PSS coated graphite carbon electrode. The polymer was directly coated on a graphite carbon electrode and characterized using simple cycle voltammetric measurements. The presence of lead ions induced a cathodic peak starting at −550 ± 10 mV vs. Ag/AgCl, and an anodic peak starting at −360 ± 10 mV vs. Ag/AgCl. Electroaccumulation of lead ions onto the PEDOT:PSS modified electrode was performed at −650 mV vs. Ag/AgCl for 30 s in a pH 2.2 hydrochloric acid solution. Chronoamperometry measurements were carried out at −350 mV vs. Ag/AgCl allowing the oxidation of accumulated lead. Using this method, lead ions were detected for concentrations ranging between 2.0 nmol L⁻¹ and 0.1 μmol L⁻¹ (R² = 0.999). The detection limit was calculated to be 0.19 nmol L⁻¹ and the quantification limit of 0.63 nmol L⁻¹. The method was shown to be highly precise and sensitive, negligible interference was detected from other metal ions. The proposed method was successfully applied for the detection of lead ions in vegetables.     

Study on Conductivity Properties of PEDOT Prepared through a Modified LB Film Method

Adopting LB film method, an arachidic acid (AA)/PEDOT multilayer LB film was chosen, and polymerized EDOT monomers in hydrophilic group of LB to prepare arachidic acid (AA)/PEDOT multilayer LB film. UV‐Vis, FT‐IR and XPS analyses implied that EDOT was effectively polymerized in film, and thus PEDOT conducting polymer was produced. Analyses of XRR and SIMS indicated that film had a well‐arranged lamella structure, and further research showed that polymerization of EDOT in AA film destroyed the orderliness of the original LB film. This phenomenon could be related to the destructive effect of polymerization on layered structure. We used four‐point probe and semiconductor instrument to study the conductivity property of the film, and observed that the conductivity of AA/PEDOT film had sudden changes with the processing time of changes in effective conduction network. That was caused by "permeability" in conducting channel of multilayer film. The test results also indicated that the conductivity of AA/PEDOT film was obviously better than that of spin‐coating PEDOT/PSS film or that of ODA‐SA/PEDOT‐PSS film, which was due to the higher π structure of PEDOT structure and ordered film structure.     

ZnS:Mn/ZnS量子点在DNA定量分析中的应用

以巯基乙酸为稳定剂,采用成核掺杂的方法在水溶液中一步制备得到具有核壳结构的ZnS:Mn/ZnS量子点.研究了荧光、室温磷光产生的机理.基于DNA对量子点发光的增强效应,以ZnS:Mn/ZnS量子点作为标记探针建立了测定DNA的荧光、室温磷光的分析方法.考察了量子点浓度、EDC/NHS用量和反应时间等条件对DNA测定的影...     

Production of highly conductive textile viscose yarns by chemical vapor deposition technique: a route to continuous process

An oxidative chemical vapor deposition (OCVD) process was used to coat flexible textile fiber (viscose) with highly conductive polymer, poly (3,4‐ethylenedioxythiophene) (PEDOT) in presence of ferric (III) chloride (FeCl₃) oxidant. OCVD is a solvent free process used to get uniform, thin, and highly conductive polymer layer on different substrates. In this paper, PEDOT coated viscose fibers, prepared under specific conditions, exhibited high conductivity 14.2 S/cm. The effects of polymerization conditions, such as polymerization time, oxidant concentration, dipping time of viscose fiber in oxidant solution, and drying time of oxidant treated viscose fiber, were carefully investigated. Scanning electron microscopy (SEM) and FT‐IR analysis revealed that polymerization of PEDOT on surface of viscose fiber has been taken place and structural analysis showed strong interactions between PEDOT and viscose fiber. Thermogravimetric analysis (TGA) was employed to investigate the amount of PEDOT in PEDOT coated viscose fiber and interaction of PEDOT with viscose fiber. The effect of PEDOT coating on the mechanical properties of the viscose fiber was evaluated by tensile strength testing of the coated fibers. The obtained PEDOT coated viscose fiber having high conductivity, could be used in smart clothing for medical and military applications, heat generation, and solar cell demonstrators. Copyright © 2010 John Wiley & Sons, Ltd.     

用于空间碎片清除的高功率激光器（英文）

虽然人类的太空活动已经考虑了尽量减少空间碎片的措施,但近地轨道碎片的数量仍呈指数增长,特别是中小型碎片的现有数量已对在轨卫星构成了实质性的威胁。作为具有较高期待的消除碎片办法,用地基DF激光器和空基Nd∶YAG激光器消除碎片的方案令人关注,它们可以以低成本和非破坏性的方式清除空间轨道的危险碎片。本文介绍了使用平均功率为100 kW的高功率、高重复频率P-P Nd∶YAG激光器和平均功率约为1.5 MW的DF激光器来保护在轨飞行器和清除直径为1～10 cm空间轨道危险碎片涉及的相关工作。     

Repetition-rate Tube-shaped Nd∶YAG Laser

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Complementary electrochromic windows with conductive nano-composite thin films

All-solid-state electrochromic windows which have complementary color transition were assembled by employing poly(aniline-N-butylsulfonate)s (PANBS), photo polymerizable electrolyte and poly(3,4-ethylenedioxythiophene) (PEDOT) in sequence. Each electrochromic layer thickness was controlled in nano-scale in order to balance charges between the electrodes generated from the electroactive layers. The electrochromic (EC) properties were characterized using cyclic voltammetry, chronocoulometry and UV–Vis spectroscopy. Absorbance change and coloration efficiency were dependant on charge density and an all solid state EC display based on an optimized thickness showed EC response at 2.4 V within 5 s with a stable memory effect.     

拱形激光二极管侧抽运Nd∶YAG固体激光器的实验研究

详细阐述了同心抽运、同心冷却的激光二极管紧包侧抽运Nd∶YAG激光器的实验研究工作。这种抽运结构使晶体内的增益场与谐振腔基模实现了良好的匹配,易于得到良好的光束质量和大能量输出,基模提取效率高。模拟分析了晶体内的增益场以及横截面内的温度分布,从不同角度探讨了激光二极管的温度特性对器件工作的影响。研究了晶体的热致退偏效应对器件调Q工作的影响,并且初步探讨了不同腔长、不同腔型下器件的工作情况,这些实验结果对进一步优化使用这种抽运结构有指导意义。所设计的激光器在工作频率6Hz时,得到了斜效率为44.3%的多模调Q输出。在抽运能量735mJ时,得到最大输出能量135mJ,脉宽7.6ns的调Q脉冲,光光效率为18.4%,插头效率为11.0%,光束发散角小于1.5mrad。