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41.
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43.
The modified wave and scattering operators are shown to be bounded between weighted L
2-spaces for two-body Schrödinger operators with long range potentials. 相似文献
44.
45.
A review of immiscibility data in binary borate and germanate systems was performed in order to compare miscibility gap consolute temperatures with ionic potentials and radii of their associated cations. The trends obtained demonstrate that a selective solution mechanism similar to the one identified for the binary silicate systems is present in the borate and germanate binaries. More importantly, the borate and germanate immiscibility data permitted the identification of a new group of cations depicting an immiscibility behaviour different from the ones identified in binary silicate systems. The new group involves highly polarizable cations possessing a lone pair of electrons. This lone pair of electrons together with oxygen bonded by strong covalent bonds to modifier cations provides efficient shielding to the cations' nuclei which considerably reduces the coulombic repulsions and produces miscibility gaps with very low consolute temperatures. A new group of cations having an homogenizing effect on melts (i.e. a capacity to make immiscible melts single phase) is thus reported. Experimental and spectroscopic data suggest that miscibility gaps associated with cations having a lone pair of electrons exist in binary silicate systems such as TlO1/2-SiO2, PbO-SiO2, SnO-SiO2 and Bi2O3-SiO2. The consolute temperature of their miscibility gaps is expected to be relatively low and metastable. 相似文献
46.
Various topological properties of projective duality between real projective varieties and their duals are obtained by making use of the microlocal theory of (subanalytically) constructible sheaves developed by Kashiwara [M. Kashiwara, Index theorem for constructible sheaves, Astérisque 130 (1985) 193-209] and Kashiwara-Schapira [M. Kashiwara, P. Schapira, Sheaves on Manifolds, Grundlehren Math. Wiss., vol. 292, Springer, Berlin-Heidelberg-New York, 1990]. In particular, we prove in the real setting some results similar to the ones proved by Ernström in the complex case [L. Ernström, Topological Radon transforms and the local Euler obstruction, Duke Math. J. 76 (1994) 1-21]. For this purpose, we describe the characteristic cycles of topological Radon transforms of constructible functions in terms of curvatures of strata in real projective spaces. 相似文献
47.
In this paper we prove the semialgebraic version of Palais' covering homotopy theorem, and use this to prove Bredon's covering mapping cylinder conjecture positively in the semialgebraic category. Bredon's conjecture was originally stated in the topological category, and a topological version of our semialgebraic proof of the conjecture answers the original topological conjecture for topological G-spaces over “simplicial” mapping cylinders. 相似文献
48.
Data in social and behavioral sciences are often hierarchically organized. Multilevel statistical methodology was developed to analyze such data. Most of the procedures for analyzing multilevel data are derived from maximum likelihood based on the normal distribution assumption. Standard errors for parameter estimates in these procedures are obtained from the corresponding information matrix. Because practical data typically contain heterogeneous marginal skewnesses and kurtoses, this paper studies how nonnormally distributed data affect the standard errors of parameter estimates in a two-level structural equation model. Specifically, we study how skewness and kurtosis in one level affect standard errors of parameter estimates within its level and outside its level. We also show that, parallel to asymptotic robustness theory in conventional factor analysis, conditions exist for asymptotic robustness of standard errors in a multilevel factor analysis model. 相似文献
49.
I. P. Romanova S. G. Fattakhov A. A. Nafikova I. I. Vandyukova R. R. Shagidullin N. M. Azancheev V. S. Reznik O. G. Sinyáshin 《Russian Chemical Bulletin》1998,47(9):1812-1819
The reactions of phosphine derivatives of diallyl isocyanurates with palladium(ii) dichloride lead to the formation of complexes, whose structure, composition, and stability depend on the length of the methylene
chain between the isocyanurate and diphenylphosphine fragments in the ligand. 1,3-Diallyl-5-[5′-(diphenylphosphino)pentyl
and 10′-(diphenyl-phosphino)decyl] isocyanurates with PdCl2 form monomeric L2PdCl2
trans-complexes in which P atoms of the ligands participate in coordination with the metal. 1,3-Diallyl-5-[2′-(diphenylphosphino)ethyl]
isocyanurate with PdCl2 forms a dimeric (LPdCl2)2 complex, which decomposes in a solution to the monomer including solvent molecule into the coordination sphere of the metal.
The reactions of 1,3-diallyl-5-[4′-(diphenylphosphino)butyl] isocyanurate and 1,3-diallyl-5-[6′-(diphenylphosphino)hexyl]
isocyanurate with PdCl2 give monomeric chelate LPdCl2 complexes in which one of the allyl groups of the isocyanurate cycle participates in coordination with the central ion along
with the phosphorus atom.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1859–1865, September, 1998. 相似文献
50.
We study the large-time behavior and rate of convergence to the invariant measures of the processes dX
(t)=b(X)
(t)) dt + (X
(t)) dB(t). A crucial constant appears naturally in our study. Heuristically, when the time is of the order exp( – )/2 , the transition density has a good lower bound and when the process has run for about exp( – )/2, it is very close to the invariant measure. LetL
=(2/2) – U · be a second-order differential operator on d. Under suitable conditions,L
z has the discrete spectrum
- \lambda _2^\varepsilon ...and lim \varepsilon ^2 log \lambda _2^\varepsilon = - \Lambda \hfill \\ \varepsilon \to 0 \hfill \\ \end{gathered} $$ " align="middle" vspace="20%" border="0"> 相似文献 |