基于混沌序列和RIPless理论的循环压缩测量矩阵的构造

压缩测量矩阵的构造是压缩感知的核心工作之一.循环矩阵由于其对应离散卷积且具有快速算法被广泛应用于压缩测量矩阵.本文力图将混沌的优点和循环矩阵的优点相结合,提出基于混沌序列的循环压缩测量矩阵.混沌循环测量矩阵元素的产生仅需要利用混沌的内在确定性,即利用混沌映射公式、初始值以及一定的采样间隔就可以产生独立同分布的随机序列;同时混沌序列的外在随机性可以满足压缩测量矩阵对随机性的要求.本文给出了使用Cat混沌映射时混沌循环测量矩阵的构造方法,以及该矩阵RIPless特性的检验.研究了采用构造的混沌循环测量矩阵对一维和二维信号进行压缩测量的效果,并与采用传统的循环测量矩阵的效果进行了比较.结果表明,混沌循环测量矩阵对于一维和二维信号都具有很好的恢复效果,且对二维信号的恢复性能要优于已有的循环矩阵.从相图角度分析了混沌循环测量矩阵优于已有的循环矩阵的机理,指出混沌的内在确定性和外在随机性的有机结合是所构造的混沌循环测量矩阵性能优于传统的循环矩阵的本质性原因.     

融合可见光-近红外与短波红外特征的新型植被指数估算冬小麦LAI

考虑到短波红外特征与叶面积指数(LAI)有很好的关联,将短波红外特征的典型水分指数与基于可见光-近红外特征的植被指数相融合,尝试构建新的植被指数估算作物LAI。通过PROSAIL辐射传输模型分析新植被指数对LAI饱和响应的特征;利用2009年和2008年北京地区冬小麦实测光谱数据进行LAI估算建模与验证。结果表明：所选择的10个典型可见光-近红外植被指数分别与5个水分植被指数相结合构建的新指数,都能够有效提高与LAI的相关性,特别是在融合了含有短波红外特征的sLAIDI*指数后,新指数显著提高了对LAI响应的饱和点,而对植被水分变化不敏感,LAI估算精度得到改善。研究表明：将短波红外特征引入到可见光-近红外植被指数中,构建的新植被指数对冬小麦LAI估算具有明显的优势。     

Oxygen-vacancy concentration in A2MgMoO6−δ double-perovskite oxides

Accurate oxygen-content analysis by means of a coulometric redox titration method specially devised for the purpose shows that as-synthesized (in 5% H₂/Ar) samples of the recently reported novel solid oxide fuel cells anode material Sr₂MgMoO_6−δ contain oxygen vacancies with a concentration of δ≈0.05. Oxygen contents and the resultant Mo-valence values are also analyzed for various A₂MgMoO_6−δ samples in order to reveal both the isovalent and aliovalent A-site cation substitution effects.     

Improvements for ground-based remote sensing of atmospheric aerosol properties by additional polarimetric measurements

We discuss the improvements in the aerosol properties characterization resulting from the additional multi-wavelength polarization measurements measured by a new CIMEL polarized sun/sky-photometer, CE318-DP. In order to process direct-sun, sky and polarization measurements in a wide spectral range (340–1640 nm), we developed new calibration methods and strategies, e.g. using the Langley plot method to calibrate both direct-sun irradiance and sky radiance, as well as combining laboratory facilities with a vicarious method to calibrate the polarized sky measurements. For studying the impact of new polarimetric measurements on the retrievals of aerosol properties, we have processed an extensive record of field measurements using an updated Dubovik and King retrieval algorithm [Dubovik O, Sinyuk A, Lapyonok T, Holben BN, Mishchenko MI, et al. Application of spheroid models to account for aerosol particle nonsphericity in remote sensing of desert dust. J Geophys Res 2006;111:D11208.]. A preliminary analysis shows that adding polarization in the inversion can reduce possible errors (notably for about 30% of our field cases) in the fine mode size distribution, real part of refractive index and particle shape parameter retrievals, especially for small particles.     

First measurements of the HCFC-142b trend from atmospheric chemistry experiment (ACE) solar occultation spectra

The first measurement of the HCFC-142b (CH₃CClF₂) trend near the tropopause has been derived from volume mixing ratio (VMR) measurements at northern and southern hemisphere mid-latitudes for the 2004–2008 time period from spaceborne solar occultation observations recorded at 0.02 cm⁻¹ resolution with the ACE (atmospheric chemistry experiment) Fourier transform spectrometer. The HCFC-142b molecule is currently the third most abundant HCFC (hydrochlorofluorocarbon) in the atmosphere and ACE measurements over this time span show a continuous rise in its volume mixing ratio. Monthly average measurements at northern and southern hemisphere mid-latitudes have similar increase rates that are consistent with surface trend measurements for a similar time span. A mean northern hemisphere profile for the time span shows a near constant VMR at 8–20 km altitude range, consistent on average for the same time span with in situ results. The nearly constant vertical VMR profile also agrees with model predictions of a long lifetime in the lower atmosphere.     

分段滤波用于消除脉搏血氧检测中多种运动干扰的研究

脉搏血氧饱和度检测仪可以无损、实时地检测动脉血液中的含氧百分比,从而快速对人体的呼吸状况以及心肺功能作出判断,但其检测精度极易受到测试部位运动的影响.人体测试部位的运动大致可以分为突发性运动干扰以及周期性的运动干扰.突发性干扰表现在局部脉搏波的波形突变上,而周期性的干扰体现在多个局部脉搏波的波形的周期性变化上.文章有针对性地提出了一种将微分阈值分段与迭带中值滤波相结合的方法来剔除突发扰动的方法,并且在上诉方法上再加上一级多点移动平滑以消除周期性运动干扰.实验证明该方法在消除多种运动伪差上有着较好的效果,且该方法计算简单,易于实现,有着一定的实际应用价值.     

高双折射光纤环镜应变传感研究

研究了高双折射光纤环镜的应变传感原理,推导了谐振波长与轴向应变的关系式,并进行了实验研究.该传感器具有很高的灵敏度：谐振波长漂移为0.031 8 nm/με,约是裸光纤光栅的32倍.谐振波长和轴向应变之间的线性拟合度为0.999 4.该传感器具有灵敏度高、结构紧凑、使用方便等优点.     

CO_2激光写入的长周期光纤光栅加速度传感器实验研究

基于高频CO_2激光在普通单模光纤上制作的长周期光纤光栅的应变和弯曲特性,本文设计制作了一种新型的加速度传感器.基于等强度梁理论分析了梁振动与长周期光纤光栅输出光强之间的关系,最后推导出了系统的加速度理论模型.文中搭建了长周期光纤光栅加速度计的实验测量系统.实验结果表明系统的加速度灵敏度约为2.82 v/g,准确度约为8.96×10~(-4) g,加速度测量误差约为0.82%.基于这种长周期光纤光栅的加速度计具有成本低、灵敏度较高等优点,因此在振动测量、惯性导航等方面将具有较好的潜在应用价值.     

等离子体金属纳米结构在SERS传感及可穿戴应力传感中的应用

等离子体金属(金、银)纳米结构因其特有的理化性能,被广泛应用于表面增强拉曼散射(Surface-enhanced Raman scattering,SERS)传感及可穿戴应力传感领域.其中,SERS是一种应用贵金属纳米材料增强拉曼散射信号的检测技术,该技术灵敏度高、特异性强,已被广泛用于生物医学、环境监测、食品药品检测...     

Oxygen fluorescence quenching studies with single tryptophan-containing proteins

The work of Lakowicz and Weber [Biochemistry 12, 4161 (1973)] demonstrated that molecular oxygen is a powerful quencher of tryptophan fluorescence in proteins. Here we report studies of the oxygen quenching of several proteins that have a single, internal tryptophan residue. Among these are apoazurin (Pseudomonas aeruginosa), asparaginase (Escherichia coli), ribonuclease T₁ (Aspergillus oryzae), and cod parvalbumin. Both fluorescence intensity and phase lifetime quenching data are reported. By comparison of these data we find that there is a significant degree of apparent static quenching in these proteins. The dynamic quenching rate constants,k _q, that we find are low compared to those for tryptophan residues in other proteins. For example, for apoazurin we find an apparentk _q of 0.59×10⁹ M ^–1 s^–1 at 25°C. This value is the lowest that has been reported for the oxygen quenching of tryptophan fluorescence.