2,5-二(2-菲基)-[3,2-b]并二噻吩的合成、表征及在有机薄膜晶体管中的应用

本文合成了2,5-二(2-菲基)-[3,2-b]并二噻吩(PhTT), 表征了其基本的物理和化学性质, 制备了相应的有机薄膜晶体管.     

Synthesis, spectroscopic studies and crystal structure of a polyoxoanion cluster incorporating para-bromophenylimido ligand, (Bu4N)2[Mo6O18(NC6H4Br-p)]

An organic-inorganic hybrid compound, (Bu₄N)₂[Mo₆O₁₈(NAr)] (Ar = p-BrC₆H₄) has been synthesized via the DCC dehydrating protocol of the reaction of [α-Mo₈O₂₆]⁴⁻ with 4-bromoaniline hydrochloride in anhydrous acetonitrile, which has been characterized by UV-Vis spectra, ¹H NMR and single crystal X-ray diffraction study. By comparing the UV-Vis spectra, which were used to monitor the reaction, the optimum preparative condition for this compound was also determined. This compound crystallizes in the monoclinic space group P2₁/n, which is featured in a terminal para-bromophenylimido group linked to an Mo atom of a hexamolybdate cluster by a Mo-N triply bond. In addition, there are π-π dimerization of the neighboring cluster anions though the parallel aromatic rings in their crystals.     

Tweezer分子的合成和对有机阴离子的配位效应

本文报道新的Ｔｗｅｅｚｅｒ（１）的合成，用＾１ＨＮＭＲ研究了新的Ｔｗｅｅｚｅｒ分子和对硝基苯甲酸盐的配位效应，结果表明它兴通过氢键，静电引力和芳环夹心堆叠作用而自动缔合。     

A novel indicator series for measuring pKa values in acetonitrile

A series of substituted azobenzene dyes was found to span a range of 8 pK_a units in acetonitrile. The UV absorption spectra of the dyes are responsive to protonation, changing in both absorption maximum and intensity. These characteristics make the dyes useful as indicators for the measurement of pK_a values of neutral organic bases that absorb in the visible region of the spectrum.     

Dependence of Performance of Organic Light-emitting Devices on Sheet Resistance of Indium-tin-oxide Anodes

IntroductionIndium-tin-oxide(ITO) has been widely used asthe anode material in organic light-emitting devices(OLEDs) because of its high transmittance in the visi-ble region and low electrical resistivity. In the pastyears, many investigations focused on …     

Enhanced deep-red emission in donor-acceptor molecular architecture: The role of ancillary acceptor of cyanophenyl

Cyanophenyl as ancillary acceptor to modify donor-acceptor compound,plays an effective role in shifting the emission color to deep red and maintaining the luminescent efficiency.     

Drying agents for water-free introduction of desorption solvent into a GC after on-line SPE of aqueous samples

Summary A small cartridge containing a drying agent is inserted between a solid phase extraction (SPE) column and a gas chromatograph (GC) to enable the introduction of water-free desorption solvent into the GC in on-line liquid chromatography (LC)-type enrichment of trace-level analytes from water samples. Some characteristics of the drying agents, such as their capacity to retain water and their re-usability after heating, have been tested. Possible interactions of the drying agent with the analytes, e.g., irreversible adsorption or catalyzed degradation, have been checked for a wide range of alkanes, alkylbenzenes chlorobenzenes, chlorophenols and phthalate esters. Using the on-line SPE-GC system with flame ionization detection (FID) and spiked samples containing different levels of the test compounds, the repeatability was shown to be satisfactory (6–17%). For 10 mL samples, the detection limits were lower than 0.1 g/L. The on-line SPE-GC-FID system here presented can be used for the repeated analysis of water samples without exchange of the dyring cartridge. The technique is applied to the analysis of tap water.     

珠江广州河段水中有机污染物的GC-MS分析

用吹扫捕集、树脂富集珠江广州河段海印断面水中有机物，毛细管色谱柱分离，用气相色谱－质谱联用方法测定有机污染物的组成，从水中鉴定出60个有机物，并作了定量分析；结果表明有机物种类多，污染较严重。     

Sulfide oxygenation by tert-butyl hydroperoxide with mononuclear (Me3TACN)Mn catalysts

Mononuclear (Me₃TACN)MnX₃ compounds, where X is Cl⁻, Br⁻, or N₃⁻, and Me₃TACN is 1,4,7-N,N′,N″-trimethyl-1,4,7-triazacyclononane, have been tested for catalyzing both sulfide oxygenation and styrene epoxidation by tert-butyl hydroperoxide (TBHP) and display turnover frequencies (TOF) up to 200 h⁻¹ at room temperature. Sulfoxides or sulfones may be produced selectively by varying reaction conditions. Product distribution from the oxygenation reactions of ethyl phenyl sulfide, 2-chloroethyl phenyl sulfide, and styrene is consistent with a mechanism involving an early single-electron transfer (SET) step.     

梯度淋洗离子色谱法同时分析有机酸与无机酸阴离子的应用研究

利用梯度离子色谱法和抑制电导检测器对有机酸与无机酸阴离子的色谱分析条件进行了研究,建立了最佳梯度程序。通过浓缩柱的富集,可使方法的检出限达1×10-3μg·L-1,各离子的相对标准偏差大部分在5%以下。此方法可用于火电厂水汽系统中痕量低分子有机酸和无机酸阴离子的快速、准确分析,结果满意。