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81.
Cyclisation of the title compounds leads to mixtures of the expected 4H-cyclopental[b]pyrrol-4-ones (1), the corresponding 6-ones (3) by a single rearrangement, and the cyclopenta[c]pyrrol-4-ones (4) by a double rearrangement, the proportions depending upon the substituents.The 1H NMR spectra of 2-methyl-4H-cyctopenta[b]thiophen-6-one (3f) shows 6J long range coupling, but this is absent in the corresponding pyrroles (3c,d). The 13C spectra of 1 and 3 cannot be interpreted on the basis of substituent chemical shifts in pyrroles and thiophens, and are clearly -CH = CH-X (X = NMe, NPh, S) bridged derivatives of cyclopent-2-enone. 相似文献
82.
Abdul -Latif K. Al-Jiburi Kisma H. Al-Niami Muthana Shanshal 《Theoretical chemistry accounts》1979,53(4):327-335
The harmonic force constants, vibrational frequencies and integrated intensity ratios of CH2, H2O, CH2O, C2H2, CO2, HCN, CH3, CH4, and C2H4 have been calculated using the MINDO—FORCES program and the Pulay method for the calculation of the molecular force constants. The results obtained are in general quite satisfactory when compared with available literature values. The results are, however, not as satisfactory in case of molecules containing heteroatoms, due to the neglect of some dipolar repulsion integrals for the heteroatoms by the MINDO/3 method. Calculated integrated intensities for CH3 and C2H4 agree well with experimental results. The calculated integrated intensities for other molecules are obtained for the first time and no comparison with published data is therefore possible.Part of the M.Sc. Thesis of K. H. A. 1978. 相似文献
83.
84.
Some organogermanium oligomers with different side groups were synthesized via li-gand substitution polymerization from 1, 4-dioxane complex of germanium dichloride withdifferent organolithitum compounds. The oligomers were isolated through either precipi-tation from methanol or extraction using toluene with a yield of no less than 50%. Theweiglit average molecular weight (M_w) of the oligomers is ranging from 1.4×10~3 to 5.9×10~3depending on the type and alkyl length of the organolithium compounds used. 相似文献
85.
1,3,3—三甲基—2—[β—(5—取代苯基—2—呋喃基)乙烯基]—3H—吲哚盐的合成 总被引:2,自引:0,他引:2
1,3,3- 三甲基-2-[β-(4-取代苯基)乙烯基]-3H-吲哚盐是熟知的聚甲川型染料,常由费歇尔碱与芳香醛制备,也可由该碱的季铵盐一步合成。但这些方法往往需要使用较昂贵的溶剂,有的尚未分出染料纯品.近年来这类染料获得许多新的用途,如作光敏电照相记录材料和电照相增感剂等.本文考察了碘化1,2,3,3-四甲基-3H-吲哚(Ⅰ)与5-取 相似文献
86.
A. Karnik S. Kailas A. Chatterjee P. Singh A. Navin D. C. Biswas D. M. Nadkarni A. Shrivastava S. S. Kapoor 《Zeitschrift für Physik A Hadrons and Nuclei》1995,351(2):195-198
The fission fragment angular distributions for the system12C +232Th have been measured in the energy range 0.97<>c.m./VB<1.22. the=" measured=" anisotropies=" have=" been=" compared=" with=" the=" predictions=" of=" the=" standard=" saddle=" point=" statistical=" model,=" using=" the=" second=" moment=" of=" the=" compound=" nucleus=" spin=" distribution=">1.22.>l2 deduced from a Wong model fit to the fission excitation function. While the measured anisotropies agree with the standard saddle point statistical model for Ec.m./VB>1.05, they are abnormally large at lower energies. This is also true for the existing measurements of16O and19F +232Th systems. Since for this system pre-equilibrium fission contributions are not expected, this anomaly indicates strong channel coupling effects leading to an increase in l2 at sub-barrier energies.The authors thank Drs. R.K. Choudhury and A. Saxena for useful discussions, Dr. R.J. Singh for making the thorium target and the Pellectron operation staff for excellent operation of the machine. 相似文献
87.
H. Navarro T. Timusk W. R. Datars D. C. Houghton 《Applied Physics A: Materials Science & Processing》1994,59(4):373-379
We have applied the technique of Photo Thermal Ionization Spectroscopy (PTIS) to the study of an erbium-doped p-Ge epitaxial layer, grown by MBE on an undoped n-type germanium substrate. The Er-doped Ge layer shows continuum photoconductivity response in the far-infrared region extending from 70 cm–1 to 900 cm–1. This type of epitaxial Er-doped Ge layers is a potentially attractive system for photoconductivity detectors of far-infrared radiation. Below 900 cm–1 three acceptor-like charged states can be distinguished with ionization energies of 9, 26.6 and 50 meV. Additionally, a study of the photoconductive response of the same sample for radiation from 1000 cm–1 to 10000 cm–1, i.e., for radiation energies well inside the forbidden gap to energies above it, shows a wealth of levels, some of which have previously been associated with erbium.On leave from: Instituto de Física, Universidad Autónoma de Puebla, Puebla, México 相似文献
88.
CHARACTERIZATIONOFRADIATIONGRAFTCOPOLYMEROFINORGANICCOMPOUNDONTOALKENEZhangWanxi;CheJitai;YanMeilan(ChangchuninstituteofAppli... 相似文献
89.
Enhancing the organic dye adsorption on porous xerogels 总被引:4,自引:0,他引:4
Zhijian Wu Ik-Sung Ahn Chang-Ha Lee Jung-Hyun Kim Yong Gun Shul Kangtaek Lee 《Colloids and surfaces. A, Physicochemical and engineering aspects》2004,240(1-3):157-164
We investigate the adsorption of four different organic dyes (i.e., methyl orange, alizarin red S, brilliant blue FCF, and phenol red) on porous xerogels. To understand the factors affecting the adsorption capacity of the xerogels, we vary the hydrophobicity and the textural properties of the xerogels as well as the solution pH. We control the hydrophobicity by mixing two different precursors (i.e., vinyltriethoxysilane (VTES) and tetraethoxysilane (TEOS)) and the textural properties by using cetyltrimethylammonium bromide (CTAB) as a templating agent. We find that the adsorption capacity is enhanced as the organic/inorganic hybrid xerogel or the templated xerogel is used instead of the purely inorganic or the untemplated xerogel. In all the cases studied, adsorption decreases as the pH is increased due to the electrostatic repulsion between the dyes and the xerogel surface. We find that both the hydrophobic surface and larger pore size/volume are required to enhance the adsorption capacity significantly. 相似文献
90.
在非质子极性溶剂-二甲基乙酰胺中,室温下用碘乙烷与C_1—C_6脂肪酸及乳酸的四甲基铵盐反应制备各酸相应的乙酯。乙酯在15%的邻苯二甲酸二壬酯与6%的土温-80混合固定液填充柱上获得满意分离。用本法测定饮料酒中的低沸点有机酸含量,简便、快速、准确。 相似文献