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31.
Ordered, mesoporous SBA-15 functionalized with organic and inorganic moieties exhibits efficient catalytic activity in a variety
of organic transformations. In this account, reviewing our own work, three-sets of surface-modified SBA-15 materials have
been investigated. The first-set of materials consists of SBA-15 modified with organo-acidic (propyl thiol and propyl sulfonic
acid) and basic (propyl amine and propyl adenine) moieties. The second-set of materials was prepared by grafting Mn complexes
to the organo-functionalized SBA-15. The third-set composes of nanocrystalline metal oxides supported on SBA-15. All these
catalysts have been characterized by structural and spectroscopic techniques. Catalytic activities of the first-set of solid
materials have been investigated in acid/base-catalyzed reactions viz., ring-opening of epoxides with amines (producing β-amino
alcohols), esterification, three-component-Mannich reactions and cycloaddition of CO2 to epoxides. The Mn complexes grafted on organofunctionalized SBA-15 are efficient catalysts for the chemo-, regio- and stereoselective
aerial oxidation of monoterpenes at ambient conditions. TiOx, VOx, MoOx and WOx supported on SBA-15 catalyzed biomimetic oxyhalogenation of aromatic compounds. In all these reactions, the functionalized
SBA-15 showed high selectivity. 相似文献
32.
Ordered Mesoporous Carbon and Thiolated Polyaniline Modified Electrode for Simultaneous Determination of Cadmium(II) and Lead(II) by Anodic Stripping Voltammetry 下载免费PDF全文
Lin Tang Jun Chen Guangming Zeng Yuan Zhu Yi Zhang Yaoyu Zhou Xia Xie Guide Yang Sheng Zhang 《Electroanalysis》2014,26(10):2283-2291
The fabrication and evaluation of a glassy carbon electrode (GCE) modified with ordered mesoporous carbon (OMC), 2‐mercaptoethanesulfonate (MES)‐tethered polyaniline (PANI) and bismuth for simultaneous determination of trace Cd2+ and Pb2+ by differential pulse anodic stripping voltammetry (DPASV) are presented here. The morphology and electrochemical properties of the fabricated electrode were respectively characterized by scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). Experimental parameters such as PANI disposition, preconcentration potential, preconcentration time and bismuth concentration were optimized. Under optimum conditions, the fabricated electrode exhibited linear calibration curves ranged from 1 to 120 nM for Cd2+ and Pb2+. The limits of detection (LOD) were 0.26 nM for Cd2+ and 0.16 nM for Pb2+ (S/N=3), respectively. Additionally, repeatability, reproducibility, interference and application were also investigated, and the proposed electrode exhibited excellent performance. The proposed method could be extended for the development of other new sensors for heavy metal determination. 相似文献
33.
在准化学模型框架下, 假设有序原子对同时具有可区分与不可区分的双重属性, 首先构造了双重短程有序准化学模型, 然后讨论了该模型所能满足的各类理论极限. 经总结提炼, 提出了有序原子对的对立统一理论. 基于该理论, 进一步将双重短程有序准化学模型做了一般化推广, 开发了多重短程有序准化学模型. 该模型能够有效描述二元熔体中存在多重短程有序构型时的热力学行为. 选取了至少存在两重短程有序构型的Bi-K熔体来检验模型的合理性和可靠性. 结果表明, 除配位数外, 只需4个模型参数就能合理再现该二元熔体所有的热化学数据. 相似文献
34.
采用两步法将不同尺寸的silicalite-1分子筛纳米晶种通过自组装合成了一系列有序介孔silicalite-1分子筛。首先将强碱性的silicalite-1前驱体分别加热不同时间得到纳米晶种,然后在类似合成SBA-15的强酸性条件下组装成有序的介孔材料。合成条件的剧烈变化阻止了分子筛晶种的继续长大,并在三嵌段共聚物模板的诱导下组装成有序介孔材料。这种“自下而上”的方法制备有序介孔分子筛同时包含微孔和介孔。氮气吸脱附结果表明所制备的介孔分子筛材料均表现了很大的比表面积(730 m2/g以上)。 相似文献
35.
The actual structure of the vanadium phosphate K6(VO)2(V2O3)2(PO4)4(P2O7) has been determined, using a much larger single crystal than previously used for the isostructural Rb-phase. The actual supercell is four times larger than the corresponding orthorhombic subcell with , , , α=β=γ=90°. The structure resolution, performed in the triclinic space group C-1, shows that the P2O7 groups alone are responsible for the superstructure, all the other atoms keeping the atomic positions of the orthorhombic subcell. This structural study shows a perfect ordering of the P2O7 groups in the actual structure, in contrast to the results obtained from the subcell. Concomitantly, the V4+ and V5+ are found to be ordered in the form of [110] stripes. 相似文献
36.
37.
自组装有序纳米银线表面增强拉曼光谱检测牛奶中三聚氰胺 总被引:4,自引:0,他引:4
制备具有表面增强拉曼散射(SERS)增强效果的基底是获得灵敏SERS检测的基础.本研究以多元醇法合成、流体流动法组装制备的有序纳米银线作为三聚氰胺的SERS增强基底,实现了样品中痕量三聚氰胺的快速灵敏检测.通过理论计算及实验考察得到了三聚氰胺的拉曼特征峰,优化了三聚氰胺在有序纳米银线基底上的SERS检测条件.在pH=8、水为溶剂、溶剂挥发时间为14 min的最佳条件下,三聚氰胺特征峰强度与浓度在0.05 ~ 1.00 mg/L范围内呈现良好的线性关系,其线性相关系数R=0.997,检测限为0.05 mg/L.在牛奶中添加不同浓度的三聚氰胺,其回收率为89.7%~ 109.2%,相对标准偏差低于6.8%.本方法对三聚氰胺检测具有很好的灵敏度和稳定性,为其它小分子化合物的SERS检测提供技术支持. 相似文献
38.
Radomír Halaš 《Czechoslovak Mathematical Journal》2000,50(2):415-429
In the paper, the notion of relative polarity in ordered sets is introduced and the lattices of R-polars are studied. Connections between R-polars and prime ideals, especially in distributive sets, are found. 相似文献
39.
M. R. Weber 《Mathematische Nachrichten》2009,282(10):1478-1487
In Banach spaces ordered by a normal cone that contains interior points the positive invertibility of operators is studied. If there exists a uniformly positive functional then any positively invertible operator A possesses a B -decomposition, i.e., a positive decomposition A = U – V with the properties: U–1 exists, VU–1 ≥ 0, Ax ≥ 0, U x ≥ 0 imply x ≥ 0 and r (VU–1) < 1. Earlier it was shown that the existence of a B -decomposition with r (VU–1) < 1 is sufficient for the positive invertibility of the operator A. Peris' result is obtained as a special case of the main theorem. The decomposition is demonstrated for a positively invertible operator in a Banach space ordered by an ice cream cone (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
40.
The existence theorems of common fixed points for two weakly increasing mappings satisfying an almost generalized contractive condition in ordered metric spaces are proved. Some comparative example are constructed which illustrate the values of the obtained results in comparison to some of the existing ones in literature. 相似文献