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111.
电子被HF和HCl分子散射总截面的计算 总被引:1,自引:1,他引:0
利用光学势方法计算了能量在10eV—1000eV范围内电子被H、F和Cl原子散射的总截面,并与已有的实验结果和理论计算进行了比较;又利用可加性规则(additivityrule)计算得到了电子被HF和HCl分子散射的总截面,计算结果也与已有的实验结果和理论计算进行了比较 相似文献
112.
High temperature scanning tunneling spectroscopy (HT-STS) was used to investigate the electronic structure of Au(1 1 1) at different temperatures in the energy range 0-1 eV below the Fermi level. We concentrated on the influence of temperature on the Shockley surface state (SS) appearing on noble metals surface due to a surface projected bulk bang gap in [1 1 1] direction. The influence of temperature on the projected band gap edge (BE) was also investigated. The experiment was carried out in the temperature range 294-580 K. As the result of the experiment a delicate shift of the SS and the BE in direction of the Fermi level was reported. 相似文献
113.
Infrared (IR)-induced second-harmonic generation in the chalcogenide glasses is observed. A phenomenological approach of IR picosecond non-linear optical (NLO) response in glass is developed for the middle IR spectral range (5–15 μm). The observed effect is explained within the framework of fifth-order NLO susceptibilities. A model that reproduces the basic characteristics of the experimental data, in which the optical non-linearities caused by photoinduced electron–phonon anharmonic interactions, is proposed. The role of the IR-induced phase matching conditions in the observed phenomenon is discussed. 相似文献
114.
A novel method of obtaining shearing interferogram by slightly moving the crystal in a photorefractive interferometer is proposed. This method can measure the phase of an object itself instead of its diffraction field, and it is easy to realize continuously changeable shearing distance in any lateral direction and introduce carrier fringes at the same time. Both the theoretical analysis and experimental verification are given. 相似文献
115.
116.
Nanocrystalline thin films of copper selenide have been grown on glass and tin doped-indium oxide substrates using chemical method. At ambient temperature, golden films have been synthesized and annealed at 200 °C for 1 h and were examined for their structural, surface morphological and optical properties by means of X-ray diffraction (XRD), scanning electron microscopy and UV-vis spectrophotometry techniques, respectively. Cu2−xSe phase was confirmed by XRD pattern and spherical grains of 30 ± 4 - 40 ± 4 nm in size aggregated over about 130 ± 10 nm islands were seen by SEM images. Effect of annealing on crystallinity improvement, band edge shift and photoelectrochemical performance (under 80 mW/cm2 light intensity and in lithium iodide electrolyte) has been studied and reported. Observed p-type electrical conductivity in copper selenide thin films make it a suitable candidate for heterojunction solar cells. 相似文献
117.
Leszek Wachowski Antoni Grodzicki Piotr Piszczek Monika Richert Magdalena Hofman 《Reaction Kinetics and Catalysis Letters》2007,91(1):93-99
Hydrogenation of styrene has been applied as a test reaction to study the catalytic activity of TiO2 deposited by the CVD (chemical vapour deposition) method on the surface of a carbonaceous material enriched in nitrogen (CN). 相似文献
118.
Hiroshi Aoki Ken Hosoya Tomohisa Norisuye Nobuo Tanaka Daisuke Tokuda Norio Ishizuka Kazuki Nakanishi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(2):949-958
An investigation was made of the gelation of dimethacrylate‐type crosslinking agents in view of an application for separation media. The study mainly centered on a crosslinking agent, glycerol dimethacrylate (GDMA), which is relatively hydrophilic because of a hydroxyl group in the middle of its structure. The gelation of GDMA was compared with that of other hydrophobic crosslinking agents such as ethylene glycol dimethacrylate and 1,6‐hexanediol dimethacrylate. The diluents used in the study were toluene, toluene with methanol, and cyclohexanol. The gelation was observed in real time with a charge coupled device camera and dynamic light scattering (DLS). Also, the separated dry gels were extensively characterized with scanning electron microscopy, BET (N2 absorption and desorption isotherm), and Fourier transform infrared. DLS analysis showed a stronger molecular interaction of GDMA gelation in toluene, whereas this interaction was much weaker in an alcoholic solvent such as toluene with methanol or cyclohexanol. This indicated that GDMA gelation might proceed through hydrogen bonding as well as a crosslinking reaction of vinyl groups. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 949–958, 2006 相似文献
119.
Huseyin Zengin Gulay Zengin Dennis W. Smith 《Journal of polymer science. Part A, Polymer chemistry》2006,44(24):6988-6996
This study focuses on the preparation, characterization, and optical properties of new bis(3,4‐diphenylethynylphenyl)phenylamine. This is the first nitrogen‐containing bis‐ortho‐diynylarene (BODA) monomer having a nitrogen atom as the spacer group. BODA monomers are usually prepared from common bisphenols, thereby providing great synthetic versatility and the opportunity to develop a wide array of novel polyarylene thermosets by varying the aromatic spacer group. The new bis(3,4‐bisphenylethynylphenyl)phenylamine was synthesized in five steps. This compound emits an intense blue color (λ = 438 nm) upon irradiation by UV light and may be suitable for use as an emitting layer in electroluminescent devices. Bis‐(3,4‐bisphenylethynylphenyl)phenylamine and its polymer have photoluminescence quantum yields 34 and 38%, respectively, and long excited‐state lifetimes of 3.2 and 3.6 ns, respectively. The structure of the monomer and its polymer were characterized using spectroscopic techniques including Ultraviolet–visible Spectrophotometer, Photoluminescence Spectrophotometer, Fourier Transform infrared spectroscopy, and Gel Permeation Chromatography. The polymerizations were studied by Differential Scanning Calorimeter. The amount of weight loss and the thermostability of the nitrogen‐containing polymer were determined from thermogravimetric analysis. The electrical conductivity of neat HCl‐doped BODA‐derived polymer film was measured according to the standard four‐point probe technique. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6988–6996, 2006 相似文献
120.