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51.
52.
The present work addresses the correlation of bisphenol A (BPA) degradation by hydrodynamic cavitation with the fluid mechanical properties of the cavitating jet in the reactor. The effects of inlet pressure and two orifices were investigated. The fluid mechanics conditions during the reaction were evaluated by optical measurements to determine the jet length, bubble volume, number of bubbles, and bubble size distribution. In addition, chemiluminescence of luminol is used to localize chemically active bubbles due to the generation of hydroxyl radicals in the reactor chamber. The correlation between the rate constants of BPA degradation and the mechanical properties of the liquid is discussed. Here, linear dependencies between the degradation of BPA and the volume expansion of the bubble volume and chemiluminescence are found, allowing prediction of the rate constants and the hydroxyl radicals generated. BPA degradation of 50% was achieved in 30 min with the 1.7 mm nozzle at 25 bar. However, the 1 mm nozzle has been demonstrated to be more energetically efficient, achieving 10% degradation with 30% less power per 100 passes. There is a tendency for the number of small bubbles in the reactor to increase with smaller nozzle and increasing pressure difference. 相似文献
53.
It is shown that the Mott insulating and superfluid phases of bosons in an optical lattice may be distinguished by a non-local ‘parity order parameter’ which is directly accessible via single site resolution imaging. In one dimension, the lattice Bose model is dual to a classical interface roughening problem. We use known exact results from the latter to prove that the parity order parameter exhibits long range order in the Mott insulating phase, consistent with recent experiments by Endres et al. [M. Endres, M. Cheneau, T. Fukuhara, C. Weitenberg, P. Schauß, C. Gross, L. Mazza, M.C. Bañuls, L. Pollet, I. Bloch, et al., Science 334 (2011) 200]. In two spatial dimensions, the parity order parameter can be expressed in terms of an equal time Wilson loop of a non-trivial U(1) gauge theory in 2+1 dimensions which exhibits a transition between a Coulomb and a confining phase. The negative logarithm of the parity order parameter obeys a perimeter law in the Mott insulator and is enhanced by a logarithmic factor in the superfluid. 相似文献
54.
O. Auciello 《辐射效应与固体损伤》2013,168(1):11-16
A simple model for blistering mechanism is proposed for energies higher than 20 keV. The model assumes that through the nucleation of smaller bubbles, a critical bubble radius is reached. The planar stress results of Jeffery for a semi-infinite plate with a circular hole subject to a uniform inner normal pressure are roughly taken as valid for the three-dimensional case. Under this assumption, the thickness of the blister's cover and critical ion dose for blister formation are calculated from the knowledge of the mean projected range of ions and blister diameter taken from experimental results. The resulting values are in agreement with the experimental values reported. The model can qualitatively explain breakage at the top of the dome-shaped blisters observed in molybdenum at 1100 K. 相似文献
55.
D. G. Pettifor 《辐射效应与固体损伤》2013,168(3-4):121-126
The different roles played by the valence s and d electrons in determining the bulk properties of pure transition metals is described. In the light of this the expected behaviour of the inert gas-metal and metal-metal interatomic potentials is discussed. 相似文献
56.
We find the existence conditions for stationary dipole and tripole surface solitons formed at the interface of a nonlocal nonlinear medium and a lattice with linearly modulated frequency. We investigate how the degree of nonlocality, the depth, and the modulation frequency of the optical lattice field affect on the existence of the surface solitons and their dynamics. The relationship between the power and the model parameters is identified. The stability of the surface dipole and tripole solitons is numerically investigated. 相似文献
57.
R. M. Montereali 《辐射效应与固体损伤》2013,168(6-12):545-551
Research activities concerned with color centers in alkali halide films started recently. The use of versatile, well-assessed, and low-cost fabrication techniques consisting of physical vapor deposition of Lithium Fluoride (LiF) films combined with direct writing lithographic processes allows the realization of miniaturized structures, like broad-band emitters, channel waveguides, optical microcavities and point-light sources emitting in the visible spectral range. Promising results have been obtained in the generation, amplification and waveguiding of visible light in LiF treated by low energy electron beams, where the efficient formation of stable primary and aggregate color centers also induces a local modification of the refractive index. A brief overview of the investigated optical properties is presented together with a short discussion about their perspectives of applications in optoelectronics. 相似文献
58.
Theoretical analysis of the radiation effect on transient behavior of an optoelectronic integrated device composed of a heterojunction phototransistor and a light emitting diode is studied theoretically. First, the transient behavior and the rise time of this device before radiation are investigated based on the frequency response of the constituent devices and the optical feedback inside the device. Second, the effect of neutron irradiation flux on the transient behavior of this device is theoretically studied. The results show that, by increasing the optical feedback inside the device, the rise time in the amplification mode is increased along with an increasing output, while that in the switching mode can be reduced effectively, and the neutron irradiation reduces the transient response and the rise time in both the amplification and switching modes. This type of model can be exploited as optical amplifier, optical switching device, and other applications. 相似文献
59.
Optical diffraction is reviewed as a technique for investigation of the phase transitions in crystals with a multidomain structure. It has been used to study the phase transitions in KIO3 and KNbO3 single crystals. Strong optical diffraction bands resulted from electric domains in KNbO3 crystals and their change with temperature were observed when a laser beam passed through the crystals. The diffraction patterns observed changed abruptly at 427°C, 223°C, and -50°C respectively, at which KNbO3 crystals undergo structural phase transitions. It is considered that the change of the diffraction patterns with temperature is due to change of the electric domains in the crystals. 相似文献
60.
T. Takagahara 《Phase Transitions》2013,86(1):281-363
In this article, the fundamental physics of multi-exciton states in semiconductor nano-crystals is reviewed focusing on the mesoscopic enhancement of the excitonic radiative decay rate and the excitonic optical nonlinearity and the mechanism of their saturation with increase of the nanocrystal size. In the case of the radiative decay rate the thermal excitation of excited exciton states having small oscillator strength within the homogeneous linewidth of the exciton ground state is essential in determining the saturation behavior. The weakly correlated exciton pair states are found to cause a cancellation effect in the third-order nonlinear optical susceptibility at the exciton resonance, providing the first consistent understanding of the experimentally observed saturation of the mesoscopic enhancement of the excitonic optical nonlinearity. The presence of the weakly correlated exciton pair states is confirmed convincingly from the good correspondence between theory and experiments on the induced absorption spectra from the exciton state in CuCl nanocrystals. Furthermore, ultrafast relaxation processes of biexcitons are discussed in conjunction with the observed very fast rise of the biexciton gain in nanocrystals. In prospect of future progress in research, the theoretical formulation to calculate the triexciton states as one of the multi-exciton states beyond the biexciton is presented for the first time including the electron-hole exchange interaction. 相似文献