Study on structure and properties of transition metal doped BiF3 by first-principles

Structure and physical properties of BiF₃ doped with M=Cr, Cu, Fe, Mn, Ni, Ti, V and Co are calculated by the DFT+U method. Effect of metal doping on the electronic structure and optical response of host materials BiF₃ is investigated systematically. New energy levels are formed and located within the band gap, which could decrease the recombination rate of e⁻/h⁺ pairs. Furthermore, transition metal doping extends the optical absorption of BiF₃ to the visible spectral region.     

Spectroscopical splitting of Cu ion energy levels in magnesium lead fluoro silicate glasses

Homogeneous 40.0 MgO-(10-x) PbF₂-50.0 SiO₂: x CuO glasses were prepared using melt-quenching technique under controlled conditions. Spectroscopic studies (UV-vis absorption, ESR, FT-IR) are carried out for these glasses. One broad characteristic visible absorption band is observed around 700-850 nm in these glasses, the optical band gap decreases as the content of the CuO increases in the glass network up to 0.7 mol % then reversal trend is observed. ESR spectra of all these glasses show resonance peaks characteristic of Cu²⁺ ions and hyperfine splitting is resolved with increasing the CuO content in the glass network. From the observed ESR spectra, the spin-Hamiltonian parameters have been evaluated and indicate that Cu²⁺ ions have octahedral coordination with a strong tetragonal distortion in these glasses. By correlating ESR and optical absorption data, the molecular orbital coefficients have been evaluated. FT-IR spectra give important information about the nature of bonds in the glass matrix. The density of the glasses is also measured and is found to decrease with the increase CuO contents in the glass matrix. The physical parameters along with spectroscopic parameters are measured.     

Spin-resolved polarized transport through a quasi one-dimensional mesoscopic quantum ring-shaped conductor with local Rashba spin-orbit interaction

We propose a quasi one-dimensional quantum ring-shaped model associated with Rashba spin-orbit (SO) interaction and Aharomov-Bohm flux to study a spin-dependent quantum transport. It is a possible candidate for spintronic current modulators. By tuning SO coupling strength and Fermi energy, we find there is a broad energy range of small vanishing spin transmission in the resonance and antiresonance interferences. More interestingly, the large on/off spin-resolved polarized conductance ratios are robust even in the presence of strong random on-site Anderson-type disorder in devices, which suggests a potential application in the real system.     

ICP等离子体鞘层附近区域发光光谱特性分析

为了独立控制鞘层附近区域离子密度和离子能最分布,采用光发射谱(OES)测量技术,对不同射频功率、放电气压和基底偏压下感应耦合等离子体鞘层附近区域辉光特性进行了研究.原子谱线和离子谱线特性分析表明,在鞘层附近区域感应耦合等离子体具有较高的离子密度和较低的电子温度.改变放电气压和射频功率,对得到的光谱特性分析表明,鞘层附近区域离子密度随射频功率的增大而线性增大,在低压下随气压的升高而增大.低激发电位原子谱线强度增加迅速,高激发电位原子谱线强度增加缓慢,而离子谱线强度增加很不明显.改变基底直流偏压,对得到的发射光谱强度变化分析表明,谱线强度随基底正偏压的增加而增大.随着基底负偏压的加入,谱线强度先减小而后增大;直流偏压为-30 V时,光谱强度最弱.快速离子和电子是引起Ar激发和电离过程的主要能量来源.     

Studies of the third-order nonlinear optical susceptibility for InxGa1−xN/GaN cylinder quantum dots

The resonant third-order susceptibilities at various directions (both parallel and vertical to Z-axis) in self-assembled quantum dots (QDs) have been investigated. The nonlinear susceptibilities associated with the intraband transition in the conduction band are theoretically calculated for wurtzite In_xGa_1−xN/GaN-strained cylinder QDs. The confined wave functions and energies of electrons in the dots have been calculated in the effective-mass approximation by solving the 3D Schrödinger equation, in which a strong built-in electric field effect due to the piezoelectricity and spontaneous polarization has been taken into account. Furthermore, it is shown that the magnitude and the resonant position of the nonlinear susceptibility χ⁽³⁾(3ω) strongly depend on the dots’ size as well as size distribution.     

Optically induced mechanical interaction between semiconductor quantum dots under an electronic resonance condition

Assuming an electronic resonance condition, we study the shape-dependence of the radiation force (RF) on a semiconductor quantum dot (QD) floating in medium and the optically induced mechanical interaction (OIMI) between two QDs with Maxwell stress tensor (MST) method, where the response fields are calculated by the improved discrete dipole approximation (DDA). Main results are as follows: (1) Properties of the RF on an isolated QD drastically change due to its shape and polarization of an incident light, which can be used for shape-selective manipulation. (2) Anomalous OIMI between two QDs arises depending on the spatial structures of internal fields, which results from the interaction between polarizations in respective QDs when they are near each other.     

Performance enhancement on mechanical and electrical effects for on-line fiber-optic bending loss measurement

For an automatic testing of the fiber bending loss parameter, we proposed an on-line fiber optic bending loss measurement system. Many impact factors from the supporting systems, free space coupling alignment, external spatial perturbation device and the other automatic testing systems may degrade the on-line fiber-optic bending loss measurement system. We reduce those impact factors and show the mechanical and electrical improvement in this paper. The accuracy can be improved by 3–5 dB for the proposed on-line bending loss measurement system. Development of an on-line fiber-optic bending loss measurement system can provide a fast-checking solution for jump-line quality improvement on fiber-from-the-desk (FFTD) access network.     

Optical and conductive properties of AlSi-alloy/SiCp composites: application in modelling CO2 laser processing of composites

The optical properties—reflectivity, real part of the refractive index, absorption coefficient as well as the thermal and electrical conductivity of AlSi-alloy/SiC_p composite were measured. The optical parameters and both conductivities decreased with the increase of SiC_p particles volume in AlSi-alloy matrix. This decrease was almost linear for the volume fraction of SiC_p particle up to 10 vol% of the total mass of the composite. For the 15 vol% of SiC_p particles, the departure from linearity is connected with the presence of additional phases in AlSi-alloy/SiC_p composite materials. The measured temperature dependencies of optical reflectivity and electrical conductivity for AlSi-alloy/SiC_p 15 vol% are of metallic character. Modelling of the interaction of the CO₂ laser radiation with AlSi-alloy/SiC_p 15 vol% composite should allow to estimate the initiation time at which the surface composite reaches melting temperature.     

Polystyrene-co-maleic acid/CdS nanocomposites: Preparation and properties

Composites of CdS nanoparticles confined in a polystyrene-co-maleic acid (PS-co-MAc) matrix have been prepared and characterized. It was shown that the acid groups of the co-polymer could be successfully used to control the aggregation of the nanoparticles, because they act as coordinate sites for Cd ions. UV-VIS measurements showed a blue shift of the absorption threshold, proving the presence of nanoparticles. An average size of the nanoparticles of about 4 nm is estimated from the change in band gap energy. Although the FTIR spectrum of the nanocomposite showed the presence of C-S bonds, a broad emission originating from surface recombination sites are noticed. DSC and TGA measurements revealed changes in thermal properties upon incorporation of nanoparticles. No thermal transition was observed in the nanocomposite, while the pure co-polymer exhibits a glass transition at 190 °C. In the presence of nanoparticles the onset of the thermal decomposition of the matrix is also shifted by 50 °C towards a higher temperature.     

光学渡越辐射测量中能量分辨精度分析

 基于光学渡越辐射原理的用于高能强流电子束束流参数在线测量及诊断系统,具有时间响应快、分辨率高等特点,可以测量电子束的束剖面、发散角、能量等多个参数。分析了测量系统的结构参数（包括了透镜的焦距、成像面位置、CCD像元尺寸）对电子束能量测量精度的影响,并在理论上模拟了电子束的发散角的影响。还根据系统数据的特点,阐述了数据噪声对能量测量结果精度的影响,指出了光学渡越辐射测量中电子束能量分辨精度受到多种因素的影响,需要在数据处理时考虑修正。