Solvent-free synthesis of new metal phosphites with double-layered,pillared-layered,and framework structures

Three new metal phosphites, formulated as (H₃O)₂·Mn₂(HPO₃)₃ (1), Co(bpy) (H₂O) (HPO₃) (2), and H₂tmpda·Zn₃(HPO₃)₄ (3), have been synthesized under solvent-free conditions, where bpy = 4,4′-bipyridine, and tmpda = N,N,N′,N′-tetramethyl-1,3-propanediamine. Compound 1 has a double-layered structure with a thickness of 5.68 Å. Compound 2 has an inorganic-organic hybrid framework with cobalt phosphite layers pillared by bpy ligands. Compound 3 has a three-dimensional open-framework structure containing 8-ring channels. The temperature dependence of the magnetic susceptibility of compounds 1 and 2 were also investigated.     

环形浅液池内热毛细对流的热力学特性

为了了解径向温度梯度作用下环形浅液池内硅熔体热毛细对流的热力学特性,利用有限差分法进行了非稳态三维数值模拟。液池外半径r0=50 mm,内半径ri=15 mm,深度为d=3 mm。结果表明,当温度梯度较小时,流动为稳定轴对称流动,系统总熵产较小;随着温度梯度的增加,流动将失去其稳定性,首先转化为径向脉动波,此时系统总熵产呈周期性变化;温度梯度再增加时,流动转化为热流体波,系统总熵产较大,但不再随时间变化。     

Energy transport in boundary driven quantum spin systems: One-way street phenomenon in models with long range interactions

We address the investigation of non trivial properties of the energy current in boundary driven XXZ quantum spin models. In specific, we focus on the occurrence of the one-way street phenomenon in asymmetrical chains, a phenomenon stronger than rectification, which establishes the existence of a unique way for the energy current in the absence of external magnetic field, that is, the magnitude and direction of the energy flow does not change as we invert the baths at the boundaries. For general target polarizations at the boundaries, we show that such a phenomenon holds in the presence of long range interactions, ingredient which increases the flow and the rectification in chains of classical oscillators, and so, of interest in the study of manipulation and control of the energy flow.     

Quantum control based on machine learning in an open quantum system

Designing robust control schemes in n-level open quantum system is significant for quantum computation. Here, we investigate two quantum control strategies based on supervised machine learning to suppress the quantum noise in an open quantum system. One is controlling state distance and the other is governing the average of a Hermitian operator. In this process, the dynamics of the system is mapped to a neural network where the control fields correspond to the weights. Besides, the system is transformed into the coherence Bloch space without using superoperator thus the complications are reduced largely. As an example, the two control protocols are demonstrated in a two-level and four-level systems, respectively. By applying these examples, the results show that the state of the system transfers to the target state and the average of a Hermitian operator to its minimum value in a given time despite disturbed by various types of noise.     

A Concise Method to Predict the Mean Dynamic Pressure on a Plunge Pool Slab

Hydrodynamic pressure exerted on a plunge pool slab by jet impingement is of high interest in high dam projects. The present study experimentally investigated the characteristics of pressure induced by a jet through a constant width flip bucket (CFB) and a slit flip bucket (SFB). A pressurized plane pipe was employed in the flume experiments to control the inlet velocities in the flip buckets. A concise method is proposed to predict the mean dynamic pressure field. Its implementation is summarized as follows: First, the position of the pressure field is determined by the trajectories of free jets, and to calculate its trajectories, an equation based on parabolic trajectory theory is used; second, the maximum mean dynamic pressure is obtained through dimensional analysis, and then the pressure field is established by applying the law of Gaussian distribution. Those steps are integrated into a concise computing procedure by using some easy-to-obtain parameters. Some key parameters, such as takeoff velocity coefficient, takeoff angle coefficient, and the parameter k2, are also investigated in this paper. The formulas of these coefficients are obtained by fitting the experimental data. Using the proposed method, the easy-to-obtain geometric parameters and initial hydraulic conditions can be used to calculate the maximum mean dynamic pressure on the slab. A comparison between experimental data and calculated results confirmed the practicability of this model. These research results provide a reference for hydraulic applications.     

Capillary electrophoresis as a tool for screening aptamer with high affinity and high specificity to ricin

Aptamers which specifically recognize targets are selected from random oligonucleotide library using systematic evolution of ligands by exponential enrichment (SELEX). In this paper, capillary electrophoresis (CE) as a separation approach has been introduced to SELEX procedure. The high efficiency of CE gives rise to greatly shorten the selection procedure. The results from enzyme-linked assay and dot blot experiment show that an enrichment pool has been obtained after four rounds selection, which can specifically recognize ricin. __________ Translated from Chemical Journal of Chinese Universities, 2006, 27(10): 1,840–1,843 [译自: 高等学校化学学报]     

聚乙二醇类表面活性剂对硅表面无电沉积Ag膜光滑作用研究

应用原子力显微镜技术及开路电位～时间谱技术,研究了非离子表面活性剂聚乙二醇2000,6000,20000对硅(100)表面无电沉积银膜的光滑作用.实验表明硅(100)表面无电沉积银的光滑程度以及镀层的质量均随聚乙二醇聚合度的增加而变好.     

环形浅池内硅熔体中的热流体波

为了了解工业Czochralski炉内硅熔体表面轮型的基本特征,对环形浅池内硅熔体的热毛细-浮力对流进行了三维数值模拟,硅熔池内径为15 mm,外径为50 mm,深度为3 mm,熔池外壁被加热,内壁被冷却,底部固壁和顶部自由表面均绝热或者允许一个垂直方向的传热。模拟结果表明,当径向温差较小时,熔池内会产生稳定的单胞热毛细-浮力流动,随着温差的增大,流动将转变为三维振荡流动,在熔体自由表面会出现沿周向运动的轮型,小的垂直方向的热流密度(3W/cm2)对这种振荡流动没有大的影响。同时,讨论了流动和温度波动的特征,并确定了振荡流动的临界条件。     

Three qubits in a symmetric environment: Dissipatively generated asymptotic entanglement

We study the asymptotic entanglement of three identical qubits under the action of a Markovian open system dynamics that does not distinguish them. We show that by adding a completely depolarized qubit to a special class of two-qubit states, by letting them reach the asymptotic state and by finally eliminating the added qubit, can provide more entanglement than by direct immersion of the two qubits within the same environment.     

基于PC机的虚拟现实技术研究

本文利用所需额外硬件很少的立体显示技术,研制了一种基于微机平台的虚拟现实系统。这个系统利用最新推出的微机版的三维图形标准Open GL建模,以实时动画形式实现了真正的交互性,立体视觉效果明显,可以给观赏者提供真实的临场感和亲自控制的参与感。与已研制出的“三维立体显示系统”相比,有了实质性的进步。