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81.
提出了用草酸.邻菲哕啉去除硅灰石中Fe^2 的方法,研究了浸取剂的浓度、浸取时间和温度等条件对Fe^2 的去除率的影响,在最佳的浸取条件下,Fe^2 的去除率达到98.35%。在去除猝灭剂后的硅灰石矿物中,掺加适量的稀土激活剂Eu^3 ,通过高温固相法制成荧光发光材料,发光强度明显提高,接近于化学试剂合成的发光材料。 相似文献
82.
开展正常人体内元素含量的检测研究具有重要生物学意义,不仅可充实我国正常成年人脏器组织元素含量值的基础医学数据,为研究人体内微量元素与健康的关系提供科学依据、也为辐射防护领域内放射性核素的剂量估算提供重要参数。本文从以下五个方面进行了论述:()体内元素含量检测研究的目的、意义及其概况;(2)元素含量检测的重要性及其历史沿革;(3)元素的检测方法及质量控制;(4)人体内脏器组织元素含量的数值;(5)与国外资料相比较。本文着重介绍了我国100例正常成年人20个脏器组织(包括胃、小肠、大肠、心、肝、脾、肺、肾、… 相似文献
83.
Sm2+-doped glasses in the system of Al2O3-SiO2 were prepared by sol-gel processing of metal alkoxides and reacting with H2 gas at 800°C. The hole burning properties of these glasses were investigated. The holes were burned in the 7F0 5D0 line of the Sm2+ ions using a DCM dye laser at 77 K. The hole depth increased with increasing the laser irradiation time, reaching up to 15% of the total intensity within a few hundred seconds. The hole width was 3 cm–1 full width at half maximum. Fluorescence line narrowing spectra of the 5D0 7 F1 transition were analyzed to study the local structure surrounding the Sm2+ ion. It is concluded that the Sm2+ ions are closely coordinated with nine oxygens of the AlO6 group in aluminosilicate glasses and that the addition of Al3+ ions into glass induces an increase in the coordination number of the Sm2+. 相似文献
84.
LIMS系统在实验室规范运作中的应用 总被引:6,自引:0,他引:6
简要介绍了LIMS系统及其对规范实验室运作发挥的作用和在应用中的具体情况。 相似文献
85.
R. Pikl U. Posset S. Möller R. Lankat W. Malisch W. Kiefer 《Vibrational Spectroscopy》1996,10(2):161-167
In order to examine the influence of the transition metal on the metal-silyl fragment MSiH3 and the metal-silicon bond, polarized Raman spectra of the complexes (C5R5)(CO)2FeSiH3 R = H (Cp) (1a), Me (Cp*) (1b)], (C5H5)(CO)(PPh3)FeSiH3 (1c), (C5Me5)(CO)2RuSiH3 (2), (C5R5)(CO)2(PMc3)MoSiH3 [R = H (3a), Me (3b)], and (C5R5)(CO)2(PMe3)WSiH3 [R = H(4a), Me (4b)] have been recorded. The spectral data have been evaluated and interpreted on the basis of a normal coordinate analysis of the MSiH3 core and the derived force constants and potential energy distributions were compared to results obtained for analogous halogen derivatives in the series XSiH3 [X = Br (5), I (6)]. 相似文献
86.
The spectral evolution of the surface-enhanced Raman scattering (SERS) of 4-tert-butylbenzylmer-captan(4-tBBM)on gold nanopanlcles assembly under laser irradiation is reported.The reIative intensities of typical peaks in the spectrum of 4-tBBM gradually change with irradiation time.Comparison of the rate of spectral changes under several experimental conditions indicates that the surface plasmon resonance(SPR)induced heat in the gold nanoparticles assembly is the origin of the spectraI evolution.During the process of self-assembly,4-tBBM molecules do not form a compact ordered monolayer because of the spatial hindrance of the 4-tert-butyl end group.The heat induced by laser irradiation drives the 4-tBBM molecules to rearrange to a more stable orientation. 相似文献
87.
《中国科学B辑(英文版)》2007,(4)
The spectral evolution of the surface-enhanced Raman scattering (SERS) of 4-tert-butylbenzylmer-captan (4-tBBM) on gold nanoparticles assembly under laser irradiation is reported. The relative intensities of typical peaks in the spectrum of 4-tBBM gradually change with irradiation time. Comparison of the rate of spectral changes under several experimental conditions indicates that the surface plasmon resonance (SPR) induced heat in the gold nanoparticles assembly is the origin of the spectral evolution. During the process of self-assembly, 4-tBBM molecules do not form a compact ordered monolayer because of the spatial hindrance of the 4-tert-butyl end group. The heat induced by laser irradiation drives the 4-tBBM molecules to rearrange to a more stable orientation. 相似文献
88.
通过1-环庚烯基锂与6,6-二烷基富烯发生环外双键的加成反应形成的大取代茂锂试剂与MCl4(M=Ti,Zr)反应,合成了12个含或不含手性碳的大位阻取代茂金属有机化合物,并研究了它们的1HNMR,EIMS和IR. 相似文献
89.
Preparation, Crystal Structure and Normal Coordinate Analysis of Linkage Isomeric Pentachlororhodanoosmates(IV) By treatment of [OsCl5I]2? with (SCN)2 in dichloromethane the linkage isomers [OsCl5(NCS)]2? and [OsCl5(SCN)]2? are formed which have been separated by ion exchange chromatography on diethylaminoethyl cellulose. The X-ray structure determination on single crystals of (Ph4As)2[OsCl5(NCS)] (monoclinic, space group P21/a, a = 18.872(2), b = 11.6024(2), c = 22.786(1), β = 109.057(1)°, Z = 4) and (Ph4As)2[OsCl5(SCN)] (monoclinic, space group P21/a, a = 19.057(2), b = 11.306(2), c = 22.612(1), β = 106.64(2)°, Z = 4) reveals the complete ordering of the complex anions. The thiocyanate group is located above one of the Cl ligands of the equatorial plane with the Os? N? C angle of 166.1° for N bonding and the Os? S? C angle of 109.9° for S bonding. The IR and Raman spectra of both linkage isomers known from literature are assigned by normal coordinate analysis based on the general valence force field using the molecular parameters of the X-ray determination. The valence force constants are fd(OsN) = 1,81 and fd(OsS) = 1,32 mdyn/Å. Taking into account increments of the trans influence a good adjustment between observed and calculated frequencies is achieved. 相似文献
90.
Magorzata Bancewicz 《International journal of quantum chemistry》2002,88(6):742-749
The expressions for moments of spectral density distribution of a Hamiltonian representing a system of N coupled Morse oscillators are reduced to the large‐N limit. The effect of the values of coupling constants on the spectral density distribution is analyzed. For the values of coupling constants within the pertinent range for real molecules, the relations between moments appear to be close to those for a Gaussian distribution. Outside this range, the deviations from the normal distribution are substantial. © 2002 Wiley Periodicals, Inc. Int J Quantum Chem, 2002 相似文献