首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   11340篇
  免费   1458篇
  国内免费   944篇
化学   3013篇
晶体学   69篇
力学   811篇
综合类   242篇
数学   4640篇
物理学   4967篇
  2023年   80篇
  2022年   268篇
  2021年   298篇
  2020年   245篇
  2019年   231篇
  2018年   246篇
  2017年   323篇
  2016年   362篇
  2015年   307篇
  2014年   587篇
  2013年   802篇
  2012年   588篇
  2011年   688篇
  2010年   580篇
  2009年   693篇
  2008年   781篇
  2007年   761篇
  2006年   650篇
  2005年   618篇
  2004年   497篇
  2003年   482篇
  2002年   458篇
  2001年   329篇
  2000年   343篇
  1999年   323篇
  1998年   314篇
  1997年   244篇
  1996年   207篇
  1995年   182篇
  1994年   185篇
  1993年   119篇
  1992年   116篇
  1991年   90篇
  1990年   72篇
  1989年   80篇
  1988年   73篇
  1987年   65篇
  1986年   48篇
  1985年   73篇
  1984年   47篇
  1983年   34篇
  1982年   47篇
  1981年   23篇
  1980年   22篇
  1979年   28篇
  1978年   33篇
  1977年   19篇
  1976年   20篇
  1975年   10篇
  1973年   14篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
991.
 本文利用加权和法,将ICF物理实验对靶点的定位需求分配到各个组件对靶点的需求。运用等概率和不等概率方法,将组件对靶点的需求分配到各元件对靶点的需求。通过光学元件运动量与靶点光束定位之间的关系,确定各个元件定位误差估计值,并将其值作为光学元件定位误差变化范围,在此范围内进行上千条光线追迹法,根据正态分布区间估计法进行检验与修正,最后给出一组具有可行性的光学元件定位误差估计参考表。  相似文献   
992.
This study investigated the effects of different treatment of alkaline pH-shifting on milk protein concentrate (MPC), micellar casein concentrate (MCC) and whey protein isolate (WPI) assisted by the same ultrasound conditions, including changes in the physicochemical properties, solubility and foaming capacity. The solubility of milk proteins had a significant increase with gradual enhancement of ultrasound-assisted alkaline pH-shifting (p < 0.05), especially for MCC up to 99.50 %. Also, treatment made a significant decline in the particle size of MPC and MCC, as well as the turbidity of the proteins (p < 0.05). The foaming capacity of MPC, MCC, and WPI was all improved, especially at pH 11, and at this pH, the milk protein also showed the highest surface hydrophobicity. The best foaming capacity at pH 11 was the result of the combined effect of particle size, potential, protein conformation, solubility, and surface hydrophobicity. In conclusion, ultrasound-assisted pH-shifting treatment was found to be effective in improving the physicochemical properties and solubility and foaming capacity of milk proteins, especially MCC, with promising application prospect in food industry.  相似文献   
993.
We examine the long-run average availability and cost rate of a maintained system which deteriorates according to a random-shock process. Shocks arrive according to a Poisson process. The system fails whenever the cumulative damage exceeds a given threshold. The system's failures are not self-announcing, hence, failures must be detected via inspections. The system is inspected at periodic or exponentially distributed intervals. Systems are replaced by preventive maintenance or after failure (corrective maintenance), whichever occurs first. When the distribution function of the shock magnitudes belongs to the class of subexponential distributions, we obtain simple approximations for the availability and the cost rate. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
994.
Native non‐covalently bonded protein‐protein and protein‐substrate complexes are of great interest and have been extensively studied by electrospray ionization mass spectrometry (ESI‐MS). Multiply charged protein homomultimeric complexes are shown to form by ESI‐MS. This study addresses factors that can artificially induce the formation of multiply charged protein homomultimeric complexes. Cytochrome c (Cyt c) and ubiquitin, which are monomers in solution, were found to generate (Cyt c)mn+ by electrospray ionization (ESI). The homomultimeric complexes were not limited to dimeric complexes but include also multiply charged trimers, tetramers, and pentamers. The observation of these homomultimeric complexes has never been revealed from a Cyt c solution at the concentration as low as 10 μM. Increasing the concentration of Cyt c enhanced the formation of (Cyt c)mn+ as expected; however, the protein concentration does not affect the relative intensities of monomeric and dimeric complexes. Additionally the enrichment of NH4OH also promotes the formation of (Cyt c)mn+. Notably, source collision‐induced dissociations (source‐CID) of (Cyt c)mn+ alter the charge state distribution (CSD) and may lead to an incorrect interpretation of Cyt c conformations. Hence, extra care should be taken when using CSD to interpret the conformation of a protein derived from ESI‐MS.  相似文献   
995.
二项分布下的一种贝叶斯可靠性验收试验方案   总被引:3,自引:0,他引:3  
为了合理利用先验信息制定可靠性验收试验方案,以降低验收试验的费用,在进行可靠性定型试验的前提下,提出了一种先验信息加工方法,并根据生产与使用双方实际所关心的风险意义,制定了产品可靠性验收试验的一种贝叶斯方案。算例结果证实,该方案在保证了生产方与使用方利益的前提下,减少了试验量,降低了验收试验费用。说明所提出的先验信息利用方式是有效的。  相似文献   
996.
煤焦在燃烧过程中孔隙结构变化的模拟   总被引:4,自引:1,他引:4  
煤焦在燃烧过程中的物理特性,如比表面积和孔径分布会发生连续变化,直接测量煤焦在燃烧过程中的孔隙结构变化很困难,但可以通过合适的数学模型来观察,二维的圆柱孔模型已大量用来对煤焦气化与燃烧过程中表面积和孔隙结构的变化进行模拟,这个模型把孔隙分成两大部分--大孔与小孔,因为小孔构成比表面的绝大部分,所以在反应过程中比表面积的变化可以由单一小孔模型来拟合,本文采用了用Tseng和Edgar提出的孔模型对几  相似文献   
997.
通过分析噪声对跃迁概率的不同影响,借助Novikov定理及MSR理论,建立了受多源白噪声影响的有限化学反应体系的有效主方程及有效熵平衡方程,导出非平衡定态时这类噪声体系熵产生的一般表达式,揭示涨落熵产生的统计内涵及噪声贡献,并针对非宏观量级的外噪声,借助扰动按分布参数分离法及有效主方程的Kramers-Moyal展开,进一步对简单加合性噪声建立了非平衡定态宏观稳定性判据的随机模拟,论证了噪声对化学反应体系定态稳定性的弱化作用.  相似文献   
998.
We propose a square-core metallic nanotube array and investigate its optical transmission property theoretically. We find that the transmission spectra can be tuned by the width of square-core edge, the intertube spacing and the dielectric constants of the core and the embedding medium between the nanotubes. We show that there is a band gap over a wide optical wavelength, and its width, number and position are sensitive to the tunable parameters. We also discuss the situation of the rectangular-core nanotube arrays and present that modification of the size of internal holes leads to redshift of the transmission spectra. Based on the localized nature of the field distributions, we show that there are local plasmonic resonant modes that originate from multipolar plasmon polaritons and a large number of opposing surface charges build up in the gap between adjacent nanotubes.  相似文献   
999.
Endoglucanases were used as a selective tool to determine the substituent distribution along the chains of partially substituted cellulose acetates. Unsubstituted segments are intensively fragmented while highly substituted segments are only slightly degraded or not affected at all. Two different procedures were developed to perform a preparative separation of the fragments by size exclusion chromatography. One system is based on a direct separation of the fragmentation products using pyridine : water (9 : 1) as an eluent. The isolated fragments can be analysed regarding to their DS values by ATR/FTIR spectroscopy or by hydrolysis and HPLC. The second system is based on deutero-acetylation of endoglucanase fragmented samples. The complete acetylation of all OH groups enables a chromatographic separation in chloroform. Afterwards the isolated fragments can be analysed regarding to their partial DS values by 1H-NMR spectroscopy.  相似文献   
1000.
A semi-analytical solution is obtained for a rotating stress-free edge disk of constant thickness and density. In the plastic range, the Hill’s quadratic orthotropic yield criterion is adopted. In the elastic range, the Hooke’s law holds with thermal effects included. The analysis of singularities performed may be used for correct implementation of numerical codes and preliminary engineering design.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号