Interfacial and aggregation properties of some anionic/cationic surfactant binary systems II. Mixed micelle formation and surface tension reduction effectiveness

Mixed micelle formation and surface tension reduction effectiveness (γ_cmc) were investigated for the following systems: triethanolammonium dodecylpoly(oxyethylene)sulfate (TADPS, containing about two ethylene oxide units)/dodecyltrimethylammonium bromide, TADPS/hexadecyltrimethylammonium bromide and TADPS/hexadecylpyridinium chloride. For all these anionic/cationic systems, the mixed critical micelle concentration (cmc) values reflect a strong synergism in mixed micelle formation, with β^M values ranging from −13.8 to −18.3. The mixed micelle composition is mixing-ratio dependent and, for equimolar mixtures, the mixed micelle is richer in the surfactant with the lower cmc. Precipitation is inhibited to a certain extent, thanks to the presence of ethylene oxide groups in the anionic species. The conditions for synergism in γ_cmc, differently expressed in the literature, can be derived from the surface tension equations established in our previous article. They can be conveniently described by a few characteristic constants: Γ _i ^∞ (saturated Gibbs excess), K _i (constant in the Szyszkowski equation), the cmc of the individual surfactants and the interaction parameters, β^S and β^M, of their mixtures. Excellent agreement between theoretically predicted and experimental results is obtained. With the increase in surfactant chain length, the β^M values decrease faster than the β^S ones and this can result in the loss of synergism in γ_cmc. Received: 11 June 2000 Accepted: 4 September 2000     

双参数弹性地基板计算新方法

弹性地基板的弯曲问题,尤其是自由边板,一直是学者和工程师们所十分关切的问题。本文用无单元法研究双参数弹性地基板的弯曲问题,由最小二乘法和变分原理导出了双参数弹性地基板的无单元法刚度短阵,编制相应的无单元法计算程序,并给出计算实例。结果表明本方法精度良好,可求出任意荷载作用下板中任一点的挠度、转角、弯矩和扭矩,且有广泛的工程应用前景。     

大型玻璃钢渔船帽型骨架剖面参数的力学分析

本文对大型玻璃渔船帽型架剖面参数,进行了在不受力情况下正交各向异性玻璃钢薄板稳定的力学分析,建立架受力分析－受压区的矩形薄板压缩稳定和腹板的矩形薄板剪切稳定两种力学模型,解得这两种力学模型,在两种材料（１：１玻璃钢和４：１玻璃铡）与两种边界件（四边简支和四边固支）组合的四种条件下,骨架剖面参数的ｂ／ｔ１和ｈ／ｔ的取值范围,它们依次为１０．０～２６．２和２８．７～４４．２。文中分析结果为帽型骨架剖面     

A new criterion for occurrence of strick-slip motion in drive mechanism

This paper, using Karnopp's model of friction force and phase plane method, studies the stick-slip motion of the flexble drive mechanism. It is explained that a sudden drop of friction force is the essential source of stick-slip motion when the sliding is impending. A new criterion for occurrence of stick-slip motion is established. The stick-slip region and the stable region in a parameter plane are separated by a critical parameter curve. Moreover, for the stick-slip motion of the flexible drive mechanism without viscous damping, a parameter expression is obtained. The results may be used in design of the flexible drive mechanism.     

作动器/传感器优化配置的研究进展

给出了作动器／传感器优化配置问题的数学描述,综述了作动器／传感器优化配置方法的发展现状．阐述了振动控制和模态试验中作动器／传感器优化配置的关系．并给出需要进一步研究的几个问题      

参数激励的幅值不是很小时Mathieu方程的一种解法

用改进的变形参数法求得了激励的幅值不是小量时Mathieu方程的周期解及过渡曲线。     

振动系统结构参数估计的Taylor变换法

引入了求解非线性微分方程的 Taylor变换法 ,将振动系统原分析模型变换为离散域内的代数方程组 ,建立了估计系统质量、阻尼和刚度矩阵的方程。该方法可以利用任意外载激励下的瞬态响应估计系统的结构参数 ,而不需要进行系统的模态试验 ,具有一定的工程应用价值。文中还研究了测试信号受噪声干扰时的参数估计方法 ,最后给出了 30 0 T转炉倾动机构的参数估计实例。     

材料物性参数识别的梯度正则化方法

本文对梯度正则化方法（Ｇｒａｄｉｅｎｔ－Ｒｅｇｕｌａｒｉｚａｔｉｏｎ Ｍｅｔｈｏｄ）作了进一步的研究,给出一种建立了梯度正则化迭代算法和选择正参数的简明实用方法。文中椭圆算子方程参数识别算例不仅说明了ＧＲ法具有广泛的适应性和一定的抗噪声能力,而且收敛速度较快,具有较大的收敛范围。     

键参数拓扑指数与常用元素的标准电极电位

采用元素键参数拓扑指数关联了第一、二和七主族元素的标准电极电位;采用无机化合物键参数拓扑指数关联了第四周期过渡元素和标准电极电位,结果显示,键参数拓扑指数与元素的标准电极电位之间有较好的线性相关性。     

葡萄糖与杂环化合物在甲酰胺中的焓相互作用参数

由于糖具有特殊的生物和生理性质 ,在工业生产中已有广泛应用 ,故其溶液热力学性质已成为人们感兴趣的研究课题之一 .糖在水溶液中的热力学性质已见文献报道 [1] ,但在非水体系中的有关数据则较少报道 .研究表明 ,溶剂介质的变化对溶质的溶剂化状态和溶质间相互作用的影响较大 ,选用酰胺为溶剂可以获得模拟蛋白质环境条件下的溶质 -溶剂、溶质 -溶质间相互作用的信息 [2～ 4] .本文利用微量量热法测得了葡萄糖在杂环化合物与甲酰胺的混合溶剂中的溶解焓 .如果把杂环化合物作为 x,葡萄糖作为 y,按照 Mc Millan- Mayer[5 ] 理论 ,1 mol葡萄…