大气气溶胶物理光学特性研究进展

大气气溶胶粒子作为地气系统的重要组成成分之一,在紫外、可见到红外很宽的波段内对辐射传输产生影响,一方面通过对电磁波的散射和吸收作用,导致光波的能量衰减;另一方面则把吸收的能量转化为其本身的热能,起到加热大气的作用.这一过程在直接和间接的辐射气候效应的模拟、激光大气传输、高分辨率光谱研究、地基和空基遥感、大气辐射订正、环境监测技术、目标探测和识别、陆上交通和航空航海都有着重要作用.详细阐述了大气气溶胶物理光学特性近年来的研究进展,为气溶胶科学后续研究工作的更好开展提供参考. 关键词： 大气光学 大气气溶胶 物理光学特性 研究进展     

Kinetic modeling of a high power fast-axial-flow CO2 laser with computational fluid dynamics method

A new computational fluid dynamics (CFD) method for the simulation of fast-axial-flow CO2 laser is developed.The model which is solved by CFD software uses a set of dynamic differential equations to describe the dynamic process in one discharge tube.The velocity,temperature,pressure and turbulence energy distributions in discharge passage are presented.There is a good agreement between the theoretical prediction and the experimental results.This result indicates that the parameters of the laser have significant effect on the flow distribution in the discharge passage.It is helpful to optimize the output of high power CO2 laser by mastering its kinetic characteristics.     

Fractality feature in incompressible three-dimensional magnetohydrodynamic turbulence

Direct Numerical Simulation (DNS) of decaying isotropic 3D magnetohydrodynamic (MHD) turbulence based on the 10243-modes in a periodic box is used to study the statistical properties of turbulence. In this paper, the presence of intermittency in MHD turbulence is investigated through the analysis of the Probability Distribution Function (PDF) for Elsässer fields and total energy fluctuations. We observe that the PDFs of the Elsässer fields fluctuations display a strong non-Gaussian behavior at small scale, which can be ascribed to multifractality feature, while the PDFs of the total energy fluctuations have the same shape over all observed scales and are monofractal. The PDFs have stretched exponential tail and satisfy the function P(|δX|) ～ exp(?A|δX| ^μ ). Numerically, we extract the exponent μ and find that it is constant for monofractal behavior as the length scale varies. To check the notion of self-similarity in the respective fluctuation, we apply the compensated structure functions.     

Gamma-Gamma湍流信道中大气光通信系统误码特性分析

大气信道中的大气湍流是影响无线激光通信系统性能的主要因素之一, 其引起的强度闪烁效应会对接收信号的提取和还原造成很大干扰。基于Gamma-Gamma概率分布的大气湍流信道统计模型, 研究了利用副载波相移键控(PSK)强度调制技术的大气光通信系统的误码特性; 推导了副载波二进制相移键控(BPSK)及开关键控(OOK)两种调制模式下的系统误码率表达式; 对在一定条件下的大气光通信系统, 比较了副载波BPSK和OOK两种调制模式的误码特性; 分析了链路特征、接收口径尺寸、通信波长和天顶角等因素对系统误码率的影响。结果表明, 增大接收孔径和通信波长都能有效地降低系统误码率, 而天顶角的增大则会使系统误码率增加, 副载波BPSK调制模式的误码特性要优于OOK调制模式的误码特性。     

Spreading of spatially partially coherent polychromatic beams in atmospheric turbulence

Taking the polychromatic Gaussian Schell-model (GSM) beam as a typical example of spatially partially coherent polychromatic beams, the spreading of polychromatic GSM beams in atmospheric turbulence is studied. The mean-squared width of polychromatic GSM beams in turbulence is derived by using the effective source and the strong fluctuation models. It is shown that the same result is obtained using both the models. The diffraction, atmospheric turbulence and beam polychroism result in a spreading of polychromatic GSM beams. If the scaling law fails, the spreading of polychromatic GSM beams increases with increasing bandwidth Γ, but the influence of Γ on the spreading of polychromatic GSM beams becomes small as the structure constant C_n² of the refractive index and spatial correlation parameter α increase. The spreading of polychromatic GSM beams increases as C_n² increases and α decreases. Spatially partially coherent polychromatic beams are less sensitive to the effects of atmospheric turbulence than spatially fully coherent polychromatic beams.     

A divergence-conforming hybridized discontinuous Galerkin method for the incompressible Reynolds-averaged Navier-Stokes equations

We present a hybridized discontinuous Galerkin (HDG) method for the incompressible Reynolds-averaged Navier-Stokes equations coupled with the Spalart-Allmaras one-equation turbulence model. The method extends upon an HDG method recently introduced by Rhebergen and Wells for the incompressible Navier-Stokes equations. With a special choice of velocity and pressure spaces for both element and trace degrees of freedom (DOFs), the method returns pointwise divergence-free mean velocity fields and properly balances momentum and energy. We further examine the use of different polynomial degrees and meshes to see how the order of the scalar eddy viscosity affects the convergence of the mean velocity and pressure fields, specifically for the method of manufactured solutions. As is standard with HDG methods, static condensation can be employed to remove the element DOFs and thus dramatically reduce the global number of DOFs. Numerical results illustrate the effectiveness of the proposed methodology.     

Kinetics studies of 5-methyl-2-hexanol, 2,2-dimethyl-3-hexanol,and 2,4,4-trimethyl-1-pentanol with chlorine atoms: Photooxidation mechanism of 2,4,4-trimethyl-1-pentanol

The rate constants for the reaction between chlorine atoms and either 5-methyl-2-hexanol, 2,2-dimethyl-3-hexanol, or 2,4,4-trimethyl-1-pentanol at 298 K were determined using the relative method with 2-butanol and 1-pentanol as reference compounds. The values obtained for 5-methyl-2-hexanol, 2,2-dimethyl-3-hexanol, and 2,4,4-trimethyl-1-pentanol (k × 10¹⁰ cm³ molec⁻¹ s⁻¹) were, respectively, (2.64 ± 0.5), (2.72 ± 0.5), and (2.50 ± 0.4), in agreement with the values of the rate constants reported in bibliography for similar alcohols and the values estimated by structure activity relationship methods. The photooxidation products of 2,4,4-trimethyl-1-pentanol initiated by chlorine atoms were identified (formaldehyde, 2-propanone, 2,2-dimethyl propanal, 4,4,-dimethyl-2-pentanone, and 3,3-dimethylbutanal), and the reaction mechanism was determined.     

Wave turbulence and intermittency in directional wave fields

The evolution of surface gravity waves is driven by nonlinear interactions that trigger an energy cascade similarly to the one observed in hydrodynamic turbulence. This process, known as wave turbulence, has been found to display anomalous scaling with deviation from classical turbulent predictions due to the emergence of coherent and intermittent structures on the water surface. In the ocean, waves are spread over a wide range of directions, with a consequent attenuation of the nonlinear properties. A laboratory experiment in a large wave facility is presented to discuss the sensitivity of wave turbulence on the directional properties of model wave spectra. Results show that the occurrence of coherent and intermittent structures become less likely with the broadening of the wave directional spreading. There is no evidence, however, that intermittency completely vanishes.     

An experimental and theoretical study on the kinetics of the reaction between 4‐hydroxy‐3‐hexanone CH3CH2C(O)CH(OH)CH2CH3 and OH radicals

Experimental and theoretical rate coefficients are determined for the first time for the reaction of 4‐hydroxy‐3‐hexanone (CH₃CH₂C(O)CH(OH)CH₂CH₃) with OH radicals as a function of temperature. Experimental studies were carried out using two techniques. Absolute rate coefficients were measured using a cryogenically cooled cell coupled to the pulsed laser photolysis‐laser‐induced fluorescence technique with temperature and pressure ranges of 280‐365 K and 5‐80 Torr, respectively. Relative values of the studied reaction were measured under atmospheric pressure in the range of 298‐354 K by using a simulation chamber coupled to a FT‐IR spectrometer. In addition, the reaction of 4H3H with OH radicals was studied theoretically by using the density functional theory method over the range of 278‐350 K. Results show that H‐atom abstraction occurs more favorably from the C–H bound adjacent to the hydroxyl group with small barrier height. Theoretical rate coefficients are in good agreement with the experimental data. A slight negative temperature dependence was observed in both theoretical and experimental works. Overall, the results are deliberated in terms of structure–reactivity relationship and atmospheric implications.     

临近空间相干激光通信链路外差效率分析

临近空间相干激光通信链路是天地一体化高速通信网络节点间连接的重要链路。围绕外差效率这一表征大气湍流扰动后信号光和本振光相干合成的指标,推导了非均匀湍流路径上的外差效率理论表达式,并结合大气折射率结构常数廓线,开展了临近空间-地面、临近空间-临近空间和临近空间-低轨卫星三类临近空间相干激光通信链路的外差效率仿真。仿真结果表明：临近空间-低轨卫星链路可以忽略大气对外差效率的影响;如果临近空间-临近空间链路距离大于500 km或是临近空间-地面链路天顶角大于60,外差效率将小于50%,有必要采用自适应光学技术进行补偿。