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991.
992.
SbPO4, a phosphate with a layered structure, was tested as an electrode material for lithium cells spanning the 3.0-0.0 V range. Two main electrochemical processes were detected as extensive plateaus at ca. 1.6 and 0.7 V in galvanostatic measurements. The first process was found to be irreversible, thus excluding a potential intercalation-like mechanism for the reaction and being better interpreted as a decomposition reaction leading to the formation of elemental Sb. This precludes the use of this compound as a cathodic material for lithium cells. By contrast, the process at 0.7 V is reversible and can be ascribed to the formation of lithium-antimony alloys. The best electrochemical response was obtained by cycling the cell at a C/20 discharge rate over the voltage range 1.25-0.25 V. Under these conditions, the cell delivers an average capacity of 165 Ah/kg—a value greater than those reported for other phosphates—upon successive cycling. 相似文献
993.
A. V. Tarasov P. O. Yablonsky Yu. A. Moskvichev 《Chemistry of Heterocyclic Compounds》2003,39(1):119-122
Various methods were studied for the oxidation of 2-methyl-5-(phenylsulfonyl)benzenesulfamide and its derivatives. The oxidation by sodium dichromate in sulfuric acid was found most efficient. The effects of temperature, concentration, reagent ratio, and time of the oxidation reaction on the yield of the desired product were investigated. Conditions were proposed for obtaining the desired product in yields up to 95%. A synthesis was developed for a series of new saccharin derivatives. 相似文献
994.
ON OPTIMAL BACKWARD PERTURBATION ANALYSIS FOR THE LINEAR SYSTEM WITH BLOCK CYCLIC COEFFICIENT MATRIX
Based on the block style spectral decomposition, this paper deals with the optimal backward perturbation analysis for the linear system with block cyclic coefficient matrix. 相似文献
995.
“神龙一号”强流脉冲加速器由72个直线感应加速腔和18个用于测试和真空泵接口的多功能腔组成。直线感应加速器的研制建造中磁轴对中偏差和聚焦磁场的自然偏差所引起的束流质心偏移轨道中心是不可避免的,由于束脉冲期间存在能散,使束流产生Corkscrew运动,导致束流品质变坏。而束脉冲期间的能散只能减小到一定水平,因此必需采取一定的措施抑制Corkscrew幅度的增长。在加速器的安装阶段,脉冲悬丝技术被应用于准直加速段聚焦磁场,并在磁轴准直测试的同时对磁场固有倾斜偏差进行初步校正。根据脉冲悬丝测试所得实验数据,采用传输矩阵法对加速段束质心轨迹进行了初步估计,计算中考虑了各加速腔聚焦磁场的倾斜和偏移误差。给出了计算结果和分析。 相似文献
996.
997.
On the basis of critical comparison of experimental and theoretical values of the E parameter and investigation of the retardation effect of oxygen on the evaporation rate of ZnO, CdO and HgO, it was concluded that the dissociative evaporation of ZnO and HgO proceeds with releasing of atomic oxygen (O) as a primary product of decomposition. By contrast, the mechanism of dissociative evaporation of CdO corresponds to the equilibrium reaction with releasing of molecular oxygen (O2) as a primary product of decomposition. As was shown, this difference in mechanisms is not related with interatomic OO distances in these oxides. From the analysis of crystal structure for 12 different oxides, which evaporate with releasing of atomic oxygen, and for 13 compounds, which evaporate with releasing of molecular oxygen, it was revealed that the first mechanism is observed for all oxides with the cubic crystal structure. It was proposed that a decisive role in this difference belongs to a local symmetry in the position of O atoms. 相似文献
998.
Software Cold Test Simulation of Coupled Cavity Slow-Wave Structure in Millimeter Wave TWT 总被引:2,自引:0,他引:2
In this paper, the software cold-test simulation method to obtain RF dispersion, interaction impedance by MAFIA software is discussed considering effect of the conducting barrel in the millimeter-wave TWT. The dispersion simulation result is obtained more consistent with experiment data than the method that ignoring effect of the conducting barrel. By changing the structure parameter, high frequency characteristic will be affected. The change relationship of high frequency characteristic with structure parameter is obtained. The different calculation methods of the interaction impedance are discussed. These results are received and are consistent with experiment data. 相似文献
999.
For the purpose of testing the spherical uniformity based on i.i.d. directional data (unit vectors) zi, i=1,…,n, Anderson and Stephens (Biometrika 59 (1972) 613–621) proposed testing procedures based on the statistics Smax=maxu S(u) and Smin=minu S(u), where u is a unit vector and nS(u) is the sum of squares of u′zi's. In this paper, we also consider another test statistic Srange=Smax−Smin. We provide formulas for the P-values of Smax, Smin, Srange by approximating tail probabilities of the limiting null distributions by means of the tube method, an integral-geometric approach for evaluating tail probability of the maximum of a Gaussian random field. Monte Carlo simulations for examining the accuracy of the approximation and for the power comparison of the statistics are given. 相似文献
1000.
Veli B. Shakhmurov 《Journal of Mathematical Analysis and Applications》2004,292(2):605-620
This study focuses on nonlocal boundary value problems (BVP) for degenerate elliptic differential-operator equations (DOE), that are defined in Banach-valued function spaces, where boundary conditions contain a degenerate function and a principal part of the equation possess varying coefficients. Several conditions obtained, that guarantee the maximal Lp regularity and Fredholmness. These results are also applied to nonlocal BVP for regular degenerate partial differential equations on cylindrical domain to obtain the algebraic conditions that ensure the same properties. 相似文献