缺陷单层和双层石墨烯的拉曼光谱及其激发光能量色散关系

拉曼光谱作为一种无破坏性、快速且敏锐的测试技术已经成 为表征石墨烯样品和研究其缺陷的最重要的实验手段之一. 本论文用离子注入在单层和双层石墨烯中产生缺陷, 并利用拉曼光谱研究了存在缺陷时单层和双层石墨烯的一阶和二阶拉曼模, 单层石墨烯的D模为双峰结构, 而双层石墨烯的D模具有四峰结构. 同时, 利用四条激光线系统地研究了本征和缺陷单层和双层石墨烯的拉曼峰频率的激发光能量依赖关系, 并基于石墨材料的双共振拉曼散射机理指认了离子注入后样品各拉曼峰的物理根源. 关键词： 石墨烯 缺陷 拉曼光谱 能量色散关系     

等离子体部分填充的波纹慢波结构中电磁波色散特性

 对有限厚环形等离子体层填充的波纹慢波结构中电磁波色散特性进行了分析。研究结果表明，对于ω＞ω_p的高频TM_0n模，模式色散曲线随等离子体密度的增加而上移；ω≤ω_p的低频等离子体模为一系列呈周期变化的密度谱，部分模式能与电子注发生较强的同步互作用。等离子体模的时间增长率随等离子体密度的增加快速增加，而TM_0n模则快速减小或缓慢增加，因此在较高的等离子体密度下，高频模式可能被抑制。     

基于正常色散玻璃二级光谱的校正

利用正常色散玻璃校正二级光谱理论,给出了单个折射面二级光谱的计算法则,并应用此算法进行光学系统设计,给出了两个设计实例.系统仅使用正常色散玻璃组合,采用三组型设计结构,由三个大空气间隔的分离透镜组构成,很好地校正了二级光谱.     

深海低声速沉积层简正波用于海底参数反演*

现有深海地声参数反演研究通常基于全波场理论,存在计算量大、多值性以及需要准确的水文环境信息等问题。针对这一问题,提出一种基于简正波频散特征的深海低声速沉积层海底参数反演方法。在南海北部大陆坡海域的一次实验中,坐底式水听器(深度约1740 m)接收的沉底弹信号中观察到一种低频成分先到而高频成分后至的到达结构,由被限制在低声速沉积层的简正波组成。通过匹配沉积层简正波60-220 Hz频段内的到达时间差对实验海域的低声速海底参数进行反演,得到沉积层厚度为16.4 m,沉积层声速为1450.5 m/s,与底质采样数据比较吻合,且具有较高的可信度,验证了所提方法的有效性。由于沉积层密度对简正波频散特征的敏感性较差,其反演结果可信度不是很高,需要进一步研究。     

基于Add-drop型微环谐振腔的硅基高速电光调制器设计

相比于传统的All-pass型微环谐振腔硅基电光调制器, Add-drop型微环谐振腔可提供更多的设计自由度, 使调制器在不改变杂质掺杂浓度的情况下就能在调制带宽和消光比性能上获得均衡考虑. 本文设计了基于Add-drop型微环谐振腔的高速、且在低调制电压下实现大消光比的硅基电光调制器, 所用微环谐振腔的半径仅仅为20 μm. 重点分析了直波导与微环谐振腔的耦合对调制器性能的影响, 发现较小的Drop端耦合系数有利于消光比的提高, 但是不能同时达到最佳的调制带宽, 因此设计上存在一个带宽和消光比性能上的折中考虑. 根据优化设计的结果进行了实际器件的制作和测试. 静态光谱测试表明, 在3 V反向偏置电压的作用下, 调制器的消光比最大可达12 dB. 动态电光响应测试中, 在仅仅1.2 V的信号幅值电压下测得了8 Gbps数据传输速率的清晰眼图. 关键词： 电光调制器 绝缘体上的硅 微环谐振腔 载流子色散效应     

三种典型结构光子晶体光纤基本特性的比较和分析

应用多极法比较和分析了相同结构参数下的正六边形、正八边形和正十边形光子晶体光纤的色散系数、色散斜率、非线性系数和限制损耗.正六边形光子晶体光纤更适合用于色散补偿和高非线性的研究,在波长0.8 μm处的非线性系数达到了0.37 m^-1·W^-1;正十边形光子晶体光纤更适合用于色散平坦和低限制损耗的研究,在波长0.8 μm处的限制损耗相对正六边形光子晶体光纤减小了约3000个数量级,在1.4—1.65 μm波长范围内,正十边形光纤的色散系数介于-0.07—0.17 p     

Ion Product of Pure Water Characterized by Physics-Based Water Model

Pure water has been characterized for nearly a century, by its dissociation into hydronium (H₃O)¹⁺ and hydroxide (HO)^1- ions. As a chemical equilibrium reaction, the equilibrium constant, known as the ion product or the product of the equilibrium concentration of the two ion species, has been extensively measured by chemists over the liquid water temper-ature and pressure range. The experimental data have been nonlinear least-squares fitted to chemical thermodynamic-based equilibrium equations, which have been accepted as the industrial standard for 35 years. In this study, a new and statistical-physics-based water ion product equation is presented, in which, the ions are the positively charged protons and the negatively charged proton-holes or prohols. Nonlinear least squares fits of our equation to the experimental data in the 0-100 ℃ pure liquid water range, give a factor of two better precision than the 35-year industrial standard.     

Thermoresponsive poly(ionic liquid): Controllable RAFT synthesis,thermoresponse, and application in dispersion RAFT polymerization

The thermoresponsive poly(ionic liquid) of poly[1‐(4‐vinylbenzyl)‐3‐methylimidozolium tetrafluoroborate] trithiocarbonate (P[VBMI][BF₄]‐TTC) showing the soluble‐to‐insoluble phase transition in the methanol/water mixture at the upper critical solution temperature (UCST) was synthesized by solution RAFT polymerization and the synthesized P[VBMI][BF₄]‐TTC was employed as macro‐RAFT agent to mediate the RAFT polymerization under dispersion condition to afford the thermoresponsive diblock copolymer nanoparticles of poly[1‐(4‐vinylbenzyl)‐3‐methylimidozolium tetrafluoroborate]‐b‐polystyrene (P[VBMI][BF₄]‐b‐PS). The controllable solution RAFT polymerization was achieved as indicated by the linearly increasing polymer molecular weight with the monomer conversion and the narrow molecular weight distribution. The P[VBMI][BF₄]‐TTC macro‐RAFT agent mediated dispersion polymerization afforded the P[VBMI][BF₄]‐b‐PS nanoparticles, the size of which was uncorrelated with the polymerization degree of the P[VBMI][BF₄] block. Several parameters including the polymerization degree, the polymer concentration and the water content in the solvent of the methanol/water mixture were found to be correlated with the UCST of the poly(ionic liquid). The synthesized poly(ionic liquid) is believed to be a new thermos‐responsive polymer and will be useful in material science. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 945–954     

Charge transport and contact resistance in coplanar devices based on colloidal polyaniline dispersion

The charge transport properties of thin films prepared from colloidal dispersion of polyaniline stabilized by poly(N‐vinylpyrrolidone) (PANI/PVP) have been investigated. The electrical characterization of coplanar device comprising of gold electrodes and PANI/PVP film deposited by spin coating served to gain insights into the contact and bulk resistance. The films prepared from PANI/PVP colloidal dispersion show high stability over a large temperature range. Temperature dependent measurements in the range from 90 to 350 K reveal that the charge transport can be described by a three‐dimensional variable‐range hopping mechanism as the dominant mode in the films. The stability of the films cast from dispersion within a large temperature range opens the possibility of the application as a polymer semiconductor layer in sensors and charge‐transport interlayer in organic solar cells. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1710–1716     

介质加载折叠波导行波管的线性分析

提出了一种介质加载折叠波导慢波结构,给出了该结构中存在电子注时慢波互作用的热色散方程,在介电常数ε_r=1的特殊情况下该方程即简化为普通折叠波导的小信号工作方程.在给定慢波结构尺寸的基础上,分析比较了介质加载对放大器小信号增益特性的影响,结果表明:"弱加载"(介质厚度d/a<0.1)时,无需重新设计慢波结构的参数,只需适当调整工作电压和电流就可以满足原有设计要求,而且和未加载时相比增益特性更为平坦,降低的电子注阻抗也有利于电子效率的提高.考虑到 关键词： 折叠波导 行波管放大器 介质加载 热色散方程