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排序方式: 共有354条查询结果,搜索用时 312 毫秒
61.
62.
Tzung-Hua Lin Wei-Han Huang In-Kook Jun Peng Jiang 《Electrochemistry communications》2009,11(8):1635-1638
Bio-inspired assembly of platelet particles and polyelectrolytes into ordered layered composites is of great technological importance in developing light-weight reinforced materials, separation membranes, and gas-barrier coatings. Unfortunately, the broadly applied layer-by-layer self-assembly technology is tedious in generating thick multilayered coatings. Here, we report a rapid and scalable cathodic electrophoretic co-deposition technology that enables simultaneous assembly of positively charged gibbsite nanoplatelets and cationic polyelectrolytes into ordered multilayers in a single step. The resulting nanocomposites have similar organic/inorganic weight ratio and ordered brick-and-mortar nanostructure as natural nacres. Nanoindentation tests show that the electrodeposited nanocomposites exhibit similar hardness and reduced modulus as those of pure gibbsite coatings. 相似文献
63.
采用扫描电子显微镜(SEM)观察了双带闪蝶(Morpho Achilles)翅膀表面的微观形貌, 通过样品的表观接触角表征了其浸润性, 采用高敏感性微电力学天平比较了水滴在蝴蝶翅膀表面不同方向运动时受到的黏附力. 实验结果表明, 水滴沿着干燥的蝴蝶翅膀鳞片堆叠方向运动时受到的黏附力要明显小于其它方向运动时受到的力, 且受力较稳定; 当蝴蝶翅膀被水滴浸润后, 水滴沿着湿润的蝴蝶翅膀鳞片堆叠方向运动时受到的黏附力接近甚至大于逆着鳞片堆叠方向运动时受到的力. 相似文献
64.
The assembly of gold nanorods(GNRs) into different liquid crystalline structures can be controlled by tuning their surface electric potential. After mildly removing excess surfactants in the GNRs solution, the electrostatic interaction between GNRs can be tuned by adjusting counter ion concentration. Specifically, nematic and smectic structures formed after solvent evaporation at low and high bromide concentrations, respectively. These results could be helpful for fabricating anisotropy enabled devices composed of metal and semiconductor nanorods. 相似文献
65.
GAO Yong-bo LIU Ming-xia SUN Zhi-qiang ZHANG Kai DONG Feng-xia SUN Hong-chen YANG Bai 《高等学校化学研究》2012,28(5):916-920
Determining the microstructure in human cementum might help us design new kinds of replacement materials for the treatment of teeth injury and disease. The authors characterized the nanostructures in the cementum of health human teeth via scanning electronic microscopy(SEM). It was found that the acellular cementum is mainly composed of two kinds of nanostructures―inorganic nanoparticles and organic nanofibers. And the inorganic nanoparticles show a tendency to arrange along the organic nanofibers. Based on the micro-molding in capillary strategy, the distribution of organic component in acellular cementum was copied with UV curable resin. After removing the inorganic nanoparticles by acid etching, many isolated spindle shape nanopores were left in polymer, which su- ggested that the inorganic nanoparticles should have been isolated by the organic component in cementum, and should be oval or nanosheet in shape. We hope the present work could provide reference for the biomimetic preparation of tissue engineering materials, and help us design new types of tooth implant. 相似文献
66.
Non magnetic material Ca2+ as a substitute in Cobalt ferrite (Co1?xCaxFe2O4x?=?0.00, 0.05, 0.10 & 0.15) is prepared by self auto combustion method. The synthesized samples were carried out for various characterizations such as X-ray diffraction, Field emission scanning electron microscope (FE-SEM), Dielectric measurement and Magnetic property. X-ray diffraction reveals the values of crystalline size, lattice parameter and x-ray density by using the standard formula. The saturation magnetization (Ms) decreases from 63.92 to 43.17 emu/g for x?=?0.00 to 0.15 and the coercivity (Hc) increases gradually from 819.85 to 1312.32?Oe with the increase in Ca2+ concentration. The dielectric properties of synthesized nano materials were carried out at room temperature. The dielectric parameters such as tangent loss, Cole–Cole plot (Impedance, Modulus), and AC Conductivity were determined for various Ca2+ concentration. The frequency dependent dielectric dispersion behaviour of all the samples can be explained by the Maxwell–Wagner two-layer model along with Koop's phenomenological theory. As a result, Ca2+ substituted Cobalt ferrite is enhanced with their dielectric and magnetic property which is suitable for a memory device, recording media application and high frequency device. 相似文献
67.
Ryongjin Kim Weiping Qin Guodong Wei Goufeng Wang Lili Wang Daisheng Zhang Kezhi Zheng Ning Liu 《Journal of Crystal Growth》2009,311(18):4301-4305
Large-scale SiC nanocables were synthesized on a Ni(NO3)2-catalyzed Si substrate by using a simple and cheap method based on thermal decomposition of methanol. Based on X-ray diffraction and high-magnification transmission electron microscopy, the as-grown nanocables consisted of crystalline SiC cores and amorphous SiO2 shells. The diameters of SiC cores were 5.7–10 nm and the thicknesses of SiO2 shells were 9–20 nm. Dividing of nanocables was observed and its origin was investigated. An asymmetric feature of SiC TO band with a shoulder at the high-frequency side was attributed to the contribution of SiC TO mode. The nanocables displayed strong violet–blue emission. A possible growth mechanism was proposed. 相似文献
68.
In this paper, the disk-like and pumpkin-like hierarchical zeolite T aggregates consisted of primary nano-grains have been hydrothermally synthesized with and without the aid of the second template. The first template is used with tetramethylammonium hydroxide (TMAOH) and the second template is used with triethanolamine (TEA) or polyving akohol (PVA). A combination of characterization techniques, including XRD, SEM, TEM and N2 adsorption–desorption to examine the crystal crystallinity, morphology and surface properties of hierarchical zeolite T aggregates. In the single-template preparation process, the two-step varying-temperature treatment has been used to improve the meso-porosity of zeolite T aggregates. In the double-template preparation process, the amounts of PVA or TEA on the crystallinity, morphology and meso-porosity of zeolite T aggregates have been studied. It has been proved that the interstitial voids between the primary grains of aggregates are the origin of additional mesopores of samples. The micro- and meso-porosities of samples prepared with and without the second template have been contrasted in detail at last. In particular, the sample synthesized with the addition of PVA presents a hierarchical pore structure with the highest Sext value of 122 m2/g and Vmeso value of 0.255 cm3/g. 相似文献
69.
由于表面效应、小尺寸效应和量子效应,使纳米结构的导电聚合物材料与传统聚合物材料相比,显示出更优越的性能。基于神经组织对电场和电刺激敏感性,使得导电聚合物纳米材料在生物医学应用方面很有前景。本文综述了纳米结构的导电聚合物的合成方法,及其在生物医学领域的应用。合成方法主要关注于硬模板法、软模板法和无模板自组装法,以及这些方法中导电聚合物纳米结构的形成机理。总结了具有纳米结构的导电聚合物,如纳米颗粒、纳米纤维和纳米管等作为神经电极涂层材料和生物传感器等方面的应用。 相似文献
70.
Mai Xia Ma 《中国化学快报》2012,23(8):949-952
We report the microstructure,application for lithium-ion batteries of mesoporous Co3O4 prepared by modified KIT-6 template method.The sample was characterized by XRD,TEM,HRTEM and nitrogen adsorption.Their electrochemical behaviors as electrode reactants for lithium ion batteries were evaluated by cyclic voltammograms and static charge-discharge.A direct comparison of electrochemical behaviors between mesoporous nanostructure and bulk reflects interesting "nanostructure effect",which is reasonably discussed in terms of how the 3D nanostructures of Co3O4 materials function in tuning their electrochemistry.The results demonstrate that further improvement of electrochemical performance in transition metal-oxide-based anode materials can be realized via the design of multiporous nanostructured materials. 相似文献