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991.
Clifton C. Sluss Jace Pittman Donald M. Nicholson David J. Keffer 《Entropy (Basel, Switzerland)》2022,24(5)
Evaluation of the entropy from molecular dynamics (MD) simulation remains an outstanding challenge. The standard approach requires thermodynamic integration across a series of simulations. Recent work Nicholson et al. demonstrated the ability to construct a functional that returns excess entropy, based on the pair correlation function (PCF); it was capable of providing, with acceptable accuracy, the absolute excess entropy of iron simulated with a pair potential in both fluid and crystalline states. In this work, the general applicability of the Entropy Pair Functional Theory (EPFT) approach is explored by applying it to three many-body interaction potentials. These potentials are state of the art for large scale models for the three materials in this study: Fe modelled with a modified embedded atom method (MEAM) potential, Cu modelled with an MEAM and Si modelled with a Tersoff potential. We demonstrate the robust nature of EPFT in determining excess entropy for diverse systems with many-body interactions. These are steps toward a universal Entropy Pair Functional, EPF, that can be applied with confidence to determine the entropy associated with sophisticated optimized potentials and first principles simulations of liquids, crystals, engineered structures, and defects. 相似文献
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TiO2 photocatalyst was supported with tetrabutyl titanate sol as precursor and fine silicon powder obtained from ferroalloys factory as carder to discuss the influence of pH value of gel precursor on microstructure and activity of photocatalyst in the process of synthesizing nano-TiO2 by using sol-gel method, the purpose of which is to provide fundamental data for the recycle of photocatalytic material. Under the irradiation of ultraviolet light, the photocatalytic degradation rate of methyl orange solution was used to characterize the photocatalytic activity of the sample. The specific surface area of the sample was tested by N2 desorption method, crystal form of TiO2 was analyzed by X-ray powder diffraction, and the microtopography of the sample was observed by scanning electron microscopy. The experimental results showed that the acidity of gel precursor could greatly affect the specific surface area and photocatalytic activity of the photocatalyst, and the optimum pH value of the precursor was determined as 2.0, and at this time the specific surface area of photocatalyst could reach 34.0 m^2/g. In the sample, the proporticn of anatase to rutile is 7:3, which makes l0 mg·L^-1 methyl orange solution fade after irradiation by 15W ultraviolet light for 24 h, and the degradation rate might be up to 98.1%. 相似文献
994.
Martina Vizza Walter Giurlani Lorenzo Cerri Nicola Calisi Antonio Alessio Leonardi Maria Jos Lo Faro Alessia Irrera Enrico Berretti Juan Víctor Perales-Rondn Alvaro Colina Elena Bujedo Saiz Massimo Innocenti 《Molecules (Basel, Switzerland)》2022,27(17)
Molybdenum disulfide (MoS2) has attracted great attention for its unique chemical and physical properties. The applications of this transition metal dichalcogenide (TMDC) range from supercapacitors to dye-sensitized solar cells, Li-ion batteries and catalysis. This work opens new routes toward the use of electrodeposition as an easy, scalable and cost-effective technique to perform the coupling of Si with molybdenum disulfide. MoS2 deposits were obtained on n-Si (100) electrodes by electrochemical deposition protocols working at room temperature and pressure, as opposed to the traditional vacuum-based techniques. The samples were characterized by X-ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM) and Rutherford Back Scattering (RBS). 相似文献
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Noresah Said Kar Chun Wong Woei Jye Lau Ying Siew Khoo Yin Fong Yeong Nur Hidayati Othman Pei Sean Goh Ahmad Fauzi Ismail 《Molecules (Basel, Switzerland)》2022,27(23)
Most researchers focused on developing highly selective membranes for CO2/CH4 separation, but their developed membranes often suffered from low permeance. In this present work, we aimed to develop an ultrahigh permeance membrane using a simple coating technique to overcome the trade-off between membrane permeance and selectivity. A commercial silicone membrane with superior permeance but low CO2/CH4 selectivity (in the range of 2–3) was selected as the host for surface modification. Our results revealed that out of the three silane agents tested, only tetraethyl orthosilicate (TEOS) improved the control membrane’s permeance and selectivity. This can be due to its short structural chain and better compatibility with the silicone substrate. Further investigation revealed that higher CO2 permeance and selectivity could be attained by coating the membrane with two layers of TEOS. The surface integrity of the TEOS-coated membrane was further improved when an additional polyether block amide (Pebax) layer was established atop the TEOS layer. This additional layer sealed the pin holes of the TEOS layer and enhanced the resultant membrane’s performance, achieving CO2/CH4 selectivity of ~19 at CO2 permeance of ~2.3 × 105 barrer. This performance placed our developed membrane to surpass the 2008 Robeson Upper Boundary. 相似文献
996.
Maria Jos Lo Faro Antonio Alessio Leonardi Dario Morganti Sabrina Conoci Barbara Fazio Alessia Irrera 《Molecules (Basel, Switzerland)》2022,27(14)
Silicon nanowires (NWs) are appealing building blocks for low-cost novel concept devices with improved performances. In this research paper, we realized a hybrid platform combining an array of vertically oriented Si NWs with different types of bucky gels, obtained from carbon nanotubes (CNT) dispersed into an ionic liquid (IL) matrix. Three types of CNT bucky gels were obtained from imidazolium-based ionic liquids (BMIM-I, BIMI-BF4, and BMIM-Tf2N) and semiconductive CNTs, whose structural and optical responses to the hybrid platforms were analyzed and compared. We investigated the electrical response of the IL-CNT/NW hybrid junctions in dark and under illumination for each platform and its correlation to the ionic liquid characteristics and charge mobility. The reported results confirm the attractiveness of such IL-CNT/NW hybrid platforms as novel light-responsive materials for photovoltaic applications. In particular, our best performing cell reported a short-circuit current density of 5.6 mA/cm2 and an open-circuit voltage of 0.53 V. 相似文献
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