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41.
F. Decremps M. Fischer A. Polian J.P. Itié M. Sieskind 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,9(1):49-57
Compounds belonging to the matlockite family are ionic layered crystals. Some previous experimental studies on these compounds
demonstrated the correlation between the difference in bond strength translating the layered properties and the anisotropic
coordination of the highly polarizable halogen anion. In the present paper, we present a model to estimate the anisotropic
compressibilities of matlockites which could be generalized to other ionic layered compounds. The compressibilities of each
individual polyhedron which built the sheet of an ionic layered crystal are determined from a simple relation based on a semi-empirical
relation obtained by Hazen et al., involving the electrical charge of the ions and the interatomic distances. The electrical charge of the anions are taken
to be direction-dependent and are modulated by the anion polarizability value. Finally, to validate the model, the calculated
compressibilities are compared with previously published data, but also with new high pressure experimental data obtained
by X-ray absorption spectroscopy up to 20 GPa on SrFCl and SrFBr at the K edge of the strontium and by X-ray diffraction up
to 30 GPa on SrFBr and PbFBr. Present estimations give results which differ from the experimental values by less than 15%.
Received 26 October 1998 相似文献
42.
A. Balerna L. Liotta A. Longo A. Martorana C. Meneghini S. Mobilio G. Pipitone 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1999,6(1):89-97
Silver-palladium bimetallic clusters were synthesized on pumice by the reduction of aqueous solution of metal salts with different
Pd:Ag ratios. Used as bimetallic catalysts, in hydrogenation reactions, in situations where molecules can undergo several
different reactions, they eliminate undesired reactions and maximize the desired ones. To characterize the structure of these
bimetallic catalysts and control if the two metallic elements do mix or not to each other to form an alloy, the structure
of the Ag-Pd bimetallic clusters was investigated by means of X-ray-absorption fine-structure spectroscopy (XAFS) and anomalous
wide angle X-ray scattering (AWAXS) experiments performed at the European Synchrotron Radiation Facility (ESRF) using the
GILDA and the BM16 beamlines. A correlation between Ag and Pd was found but not a clear evidence of alloying.
Received: 21 December 1998 / Received in final form: 19 March 1999 相似文献
43.
Nora Graf Eda Yegen Thomas Gross Andreas Lippitz Wilfried Weigel Simone Krakert Andreas Terfort Wolfgang E.S. Unger 《Surface science》2009,603(18):2849-2860
The chemical constitution of functionalized supports is an important parameter that determines their performance in a broad range of applications, e.g. for immobilization of biomolecules. Supports with amino functionalized surfaces are also often used for DNA microarray experiments. However, spectral data which have been reported for surfaces with amino functionalities suffer from some inconsistencies. In this article a detailed XPS (X-ray photoelectron spectroscopy) and NEXAFS (Near edge X-ray absorption fine structure) database for amino functionalized surfaces is presented. Amino-terminated surfaces prepared from aliphatic and aromatic aminosilanes or aminothiols and a field sample are considered. Effects of aging in air and damage by radiation are addressed as well. 相似文献
44.
We have studied the electronic properties of 3C- and 4H-SiC with X-ray absorption (XAS). Particular emphasis is placed on the conduction bands because they exhibit larger differences between the various SiC polytypes than valence bands. XAS spectra at the Si2p and C1s edges provide projections onto Si3d, 4s and C2p conduction band states. We explain the observed differences in the Si L2,3 XAS data to arise from transition into dispersive bands which occur at the M and K point of the hexagonal Brillouin zone. The XAS data are sensitive to a difference in the dispersion of the two lowest conduction bands. For 3C-SiC the dispersion is larger than for 4H-SiC in agreement with theory. We compare the XAS data at the Si L edge with CFS and CIS spectra and find that the SiLVV Auger is dominant. 相似文献
45.
The adsorption of naphthalene, vacuum deposited on a Ag(1 0 0) surface, was comprehensively investigated by means of low-energy electron diffraction (LEED), temperature-programmed thermal desorption (TPD) spectroscopy, X-ray photoelectron spectroscopy (XPS), and polarization-dependent near-edge X-ray absorption fine structure (NEXAFS) spectroscopy in the mono- and multilayer regime. A growth of long-range ordered monolayer at 140 K is observed with LEED. The polarization-dependent C 1s NEXAFS shows that the naphthalene molecules in the monolayer lie almost parallel to the Ag(1 0 0) surface. With increasing film thickness, the molecular orientation turns to upright position. Furthermore, NEXAFS measurements show that in the multilayer regime the molecular orientation depends on the substrate temperature during deposition. 相似文献
46.
Rhodium nanoparticles were synthesized by the reduction of Rh3+ ion in ethanol solvent with use of the polyvinylpyrrolidone (PVP) of various molecular weights and the solvent of different volume ratios of water to ethanol. The formed Rh(PVP) nanoparticles have been characterized by transmission electron microscopy (TEM), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and near edge X-ray absorption fine structure (NEXAFS) techniques. The TEM and AFM results show that the Rh(PVP) nanoparticles are monodispersed and do not agglomerate with each other. The particle size can be controlled by the molecular weight of PVP and/or the water/ethanol ratio of the solvent. The XPS and NEXAFS results indicate that the chlorine derived from RhCl3(3H2O) remains in the obtained nanoparticles but can be removed by heating. 相似文献
47.
In this work we present results from density functional theory (DFT) cluster studies to determine polarization-dependent near edge X-ray absorption fine structure (NEXAFS) spectra of the vanadyl termination of the V2O3(0 0 0 1) surface. The oxygen K edge spectra are calculated for the relaxed surface geometry where geometric parameters are taken from recent periodic DFT work. A detailed analysis of energetic peak positions, relative intensities, and final state orbitals allows a deep understanding of the complex angular dependence of the calculated spectra on the basis of the local binding environment of differently coordinated oxygen species. Further, our theoretical analysis can assign and explain various spectral details in the experimental NEXAFS data, in particular, those related to vanadyl oxygen. This allows us to support the experimentally suggested vanadyl surface termination. 相似文献
48.
Geometrical characterization of adenine and guanine on Cu(1 1 0) by NEXAFS, XPS, and DFT calculation
Adsorption of purine DNA bases (guanine and adenine) on Cu(1 1 0) was studied by X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine-structure spectroscopy (NEXAFS), and density-functional theory (DFT) calculation. At coverages near 0.2 monolayers, Angular-resolved NEXAFS analysis revealed that adenine adsorbates lie almost flat and that guanine adsorbates are tilted up on the surface with the purine ring parallel to the atom rows of Cu(1 1 0). Referring to the previous studies on pyrimidine DNA bases [M. Furukawa, H. Fujisawa, S. Katano, H. Ogasawara, Y. Kim, T. Komeda, A. Nilsson, M. Kawai, Surf. Sci. 532-535 (2003) 261], the isomerization of DNA bases on Cu(1 1 0) was found to play an important role in the adsorption geometry. Guanine, thymine and cytosine adsorption have an amine-type nitrogen next to a carbonyl group, which is dehydrogenated into imine nitrogen on Cu(1 1 0). These bases are bonded by the inherent portion of -NH-CO- altered by conversion into enolic form and dehydrogenation. Adenine contains no CO group and is bonded to Cu(1 1 0) by participation of the inherent amine parts, resulting in nearly flatly-lying position. 相似文献
49.
Ping Zhu Tai-Quan Wu Jing-Chang Tang 《Journal of Electron Spectroscopy and Related Phenomena》2007,160(1-3):7-14
A theoretical study on the S K-edge near edge X-ray absorption fine structure (NEXAFS) of a hexanethiolate monolayer on Ag(1 0 0) has been performed by employing the multiple-scattering cluster (MSC) method. The unoccupied molecular orbitals of the system, which are closely correlated with resonances of the NEXAFS spectra, have been calculated by using the discrete variational (DV)-Xα method. The physical origins of the resonances are elucidated by these theoretical studies. It has been shown that the leading peak at 2470.3 eV is not a π*(S–C), but a resonance corresponding to the transition of 1s electrons into a hybrid orbital of the S(3p) atomic orbital of a hexanethiolate molecule and Ag atomic orbitals. The interaction between the adsorbate and the substrate induces other two weak resonances at 2475.2 and 2478.2 eV in the NEXAFS. The adsorption structure of a hexanethiolate monolayer on Ag(1 0 0) deduced from the theoretical analysis on the NEXAFS is in agreement with that from the SEXAFS of the system. 相似文献
50.
DENG Ju-Zhi CHEN Rong SEKIGUCHI Tetsuhiro BABA Yuji HIRAO Norie HONDA Mitsunori 《中国物理C(英文版)》2008,32(9)
Thin silicon Phthalocyanine dichloride films on HOPG were prepared and the sample was heated in the vacuum with laser.The thickness of the thin sample on HOPG was checked by X-ray photoemission spectroscopy.The orientation of the molecules in respect to the substrate plane Was investigated by measuring the silicon K-edge near edge X-ray absorption fine structure(NEXAFS).In the NEXAFS spectra of the thin sample,two clear peaks which were assigned to 1s→σ*Si-N and 1s→σ*Si-C1 appeared around 1847.2 eV and 1843.1 eV respectively.The intensities of the resonance peaks showed strong polarization dependence.A quantitative analysis of the polarization dependence revealed that the Si-N bond tended to lie down while the Si-C1 bond was out of the molecular plane. 相似文献