全文获取类型
收费全文 | 2282篇 |
免费 | 248篇 |
国内免费 | 60篇 |
专业分类
化学 | 1034篇 |
晶体学 | 12篇 |
力学 | 296篇 |
综合类 | 2篇 |
数学 | 185篇 |
物理学 | 1061篇 |
出版年
2024年 | 9篇 |
2023年 | 30篇 |
2022年 | 123篇 |
2021年 | 102篇 |
2020年 | 105篇 |
2019年 | 93篇 |
2018年 | 79篇 |
2017年 | 92篇 |
2016年 | 113篇 |
2015年 | 87篇 |
2014年 | 117篇 |
2013年 | 213篇 |
2012年 | 117篇 |
2011年 | 142篇 |
2010年 | 103篇 |
2009年 | 127篇 |
2008年 | 112篇 |
2007年 | 133篇 |
2006年 | 115篇 |
2005年 | 75篇 |
2004年 | 92篇 |
2003年 | 79篇 |
2002年 | 56篇 |
2001年 | 38篇 |
2000年 | 37篇 |
1999年 | 35篇 |
1998年 | 29篇 |
1997年 | 33篇 |
1996年 | 17篇 |
1995年 | 12篇 |
1994年 | 16篇 |
1993年 | 12篇 |
1992年 | 9篇 |
1991年 | 7篇 |
1990年 | 3篇 |
1989年 | 7篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1982年 | 1篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有2590条查询结果,搜索用时 250 毫秒
991.
A new model is proposed for the structure of low atomic coordination chalcogenide glasses. The closed clusters model is based on the various types of clusters, packed by van der Waals forces in a molecular-type packing. Arguments are given to support the new model, taken as example the typical chalcogenide glass As2S3. 相似文献
992.
Guillaume Beardsell Guillaume Blanquart 《Proceedings of the Combustion Institute》2019,37(2):1895-1902
Thermo-acoustic instabilities are problematic in the design of continuous-combustion propulsion systems such as gas turbine engines, rocket motors, jet engine afterburners, and ramjets. Conceptually, the coupling between acoustics and flame dynamics can be divided into two categories: flame area fluctuations and changes in the local flame speed. The latter can be caused by the thermodynamic fluctuations that accompany an acoustic wave. This coupling is the focus of the present work. In this paper, we are concerned with the dynamics of laminar premixed flames involving large hydrocarbon species. Through high-fidelity numerical simulations, we investigate the flame response for a wide range of fuels and acoustic frequencies. The combustion of hydrogen and methane is considered for verification purposes and as baseline cases for comparison with two large hydrocarbon fuels, n-heptane and n-dodecane. We extract the phase and gain of the unsteady heat release response, which are directly related to the Rayleigh criterion and thus the stability of the system. For all fuels, we observe a local peak in the heat release gain. At high frequencies, we find that the fluctuations of the different species mass fractions decrease with the inverse of the acoustic frequency, leading to chemistry being “frozen” in the high-frequency limit. This allows us to predict the flame behavior directly from the steady-state solution. 相似文献
993.
The present study examines, in presence of thermal expansion effects, the existence of the multiplicity of solutions previously reported within the context of diffusive-thermal modeling in [15], for lean premixed flames with low Lewis number (Le?<?1) propagating in narrow circular adiabatic channels subject to a Poiseuille flow. For this, direct numerical simulations have been carried out within the framework of variable-density Navier–Stokes equations and zero-Mach-number approximation. The simulations, conducted for both axisymmetric and three-dimensional cylindrical geometries, confirm the coexistence of multiple steady flame structures for a given flow rate. They show that axisymmetric flames concave towards the upstream are more unstable to three-dimensional perturbations than convex (toward the upstream) flames. This result evinces earlier findings obtained from stability analysis. The non-axisymmetry property of the flame is also found to push back the critical flashback limits at larger flow rate when compared to those predicted under the assumption of flame axisymmetry. 相似文献
994.
Matthew Emmett Weiqun Zhang Michael Minion John B. Bell 《Combustion Theory and Modelling》2019,23(4):592-625
In this paper, we present a fourth-order in space and time block-structured adaptive mesh refinement algorithm for the compressible multicomponent reacting Navier–Stokes equations. The algorithm uses a finite-volume approach that incorporates a fourth-order discretisation of the convective terms. The time-stepping algorithm is based on a multi-level spectral deferred corrections method that enables explicit treatment of advection and diffusion coupled with an implicit treatment of reactions. The temporal scheme is embedded in a block-structured adaptive mesh refinement algorithm that includes subcycling in time with spectral deferred correction sweeps applied on levels. Here we present the details of the multi-level scheme paying particular attention to the treatment of coarse–fine boundaries required to maintain fourth-order accuracy in time. We then demonstrate the convergence properties of the algorithm on several test cases including both non-reacting and reacting flows. Finally we present simulations of a vitiated dimethyl ether jet in 2D and a turbulent hydrogen jet in 3D, both with detailed kinetics and transport. 相似文献
995.
996.
The statistical behaviour and the modelling of turbulent scalar flux transport have been analysed using a direct numerical simulation (DNS) database of head-on quenching of statistically planar turbulent premixed flames by an isothermal wall. A range of different values of Damköhler, Karlovitz numbers and Lewis numbers has been considered for this analysis. The magnitudes of the turbulent transport and mean velocity gradient terms in the turbulent scalar flux transport equation remain small in comparison to the pressure gradient, molecular dissipation and reaction-velocity fluctuation correlation terms in the turbulent scalar flux transport equation when the flame is away from the wall but the magnitudes of all these terms diminish and assume comparable values during flame quenching before vanishing altogether. It has been found that the existing models for the turbulent transport, pressure gradient, molecular dissipation and reaction-velocity fluctuation correlation terms in the turbulent scalar flux transport equation do not adequately address the respective behaviours extracted from DNS data in the near-wall region during flame quenching. Existing models for transport equation-based closures of turbulent scalar flux have been modified in such a manner that these models provide satisfactory prediction both near to and away from the wall. 相似文献
997.
Faster vortex core switching with lower current density using three-nanocontact spin-polarized currents in a confined structure 下载免费PDF全文
We perform micromagnetic simulations on the switching of magnetic vortex core by using spin-polarized currents through a three-nanocontact geometry. Our simulation results show that the current combination with an appropriate current flow direction destroys the symmetry of the total effective energy of the system so that the vortex core can be easier to excite,resulting in less critical current density and a faster switching process. Besides its fundamental significance, our findings provide an additional route to incorporating magnetic vortex phenomena into data storage devices. 相似文献
998.
Molecular dynamics simulations have been performed on the fully hydrated lipid bilayer with different concentrations of sodium dodecyl sulfate(SDS). SDS can readily penetrate into the membrane. The insertion of SDS causes a decrease in the bilayer area and increases in the bilayer thickness and lipid tail order, when the fraction of SDS is less than 28%.Through calculating the binding energy, we confirm that the presence of SDS strengthens the interactions among the DPPC lipids, while SDS molecules act as intermedia. Both the strong hydrophilic interactions between sulfate and phosphocholine groups and the hydrophobic interactions between SDS and DPPC hydrocarbon chains contribute to the tight packing and ordered alignment of the lipids. These results are in good agreement with the experimental observations and provide atomic level information that complements the experiments. 相似文献
999.
1000.
龙林 《原子与分子物理学报》2017,34(6)
本文采用分子动力学模拟方法结合镶嵌原子势,研究了在200 K时二元(CoAl)1415团簇的结构随Co原子浓度的变化情况。利用径向分布函数、对分析技术和键取向序参数方法研究了微观局部结构情况,研究结果表明: (CoAl)1415团簇的组分对最终冷却结构影响较大,Co原子浓度为100%~70%的团簇表现出不完全的六角密排结构特征;Co原子浓度为50%的团簇具有局部的体心立方体结构特征;Co原子浓度为30%~10%时,表现出部分区域的二十面体和缺陷二十面体结构特征。 相似文献