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《Arabian Journal of Chemistry》2022,15(7):103933
In this study, a fingerprint-activity relationship modeling between chemical fingerprints and antirheumatic activity was established, and multivariate statistical analysis was used to evaluate the quality of Taxilli Herba (TH) from different hosts. Characteristic fingerprints of 20 batches of TH samples were generated by high-performance liquid chromatography coupled with triple quadrupole-time of flight tandem mass spectrometry (HPLC-Triple TOF-MS/MS), and the similarity analysis was calculated based on thirteen common characteristic peaks by hierarchical clustering analysis (HCA). Subsequently, nine efficacy markers were discovered by combining fingerprints and antirheumatic activity through grey correlation analysis (GCA) and bivariate correlation analysis (BCA). Meanwhile, the content of 5 constituents in 9 markers was determined by high-performance liquid chromatography coupled with triple quadrupole-linear ion trap tandem mass spectrometry (HPLC-QTRAP-MS/MS). The comprehensive quality of TH was assessed using multivariate statistical analysis, including principal components analysis (PCA) and technique for order preference by similarity to ideal solution (TOPSIS). The results showed that a high dose of TH extract could markedly ameliorate arthritis damage compared to other doses, with flavonoids playing an important role in the antirheumatic activity. The comprehensive quality of samples from Morus alba L. (SS) was superior to those from Liquidambar formosana Hance (FXS). The present study will demonstrate the markers associated with efficacy, and provide an applicable strategy for more comprehensive quality control and evaluation of TH. 相似文献
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Graphene oxide (GO) was functionalized using three different diamines, namely ethylenediamine (EDA), 4,4′-diaminodiphenyl sulfone (DDS) and p-phenylenediamine (PPD) to reinforce an epoxy/glass fiber (EP/GF) composite laminate, with the aim of improving the overall composite mechanical performance. Different mechanical characterization techniques were used to determine the mechanical performance, including: tensile stress strain, double cantilever beam (DCB) mode-I fracture toughness and dynamic mechanical thermal analysis (DMTA). Scanning electron microscopy (SEM) was used to support the results and conclusions. The results demonstrated remarkable enhancements in the mechanical performance of EP/GF composite laminates by incorporation of functionalized graphene oxide (FGO) nanofiller, whilst the mechanical performance of the GO reinforced composite only improved marginally. Finally, the mechanical performance of the EP/GF/FGO multi-scale composites was found to be dependent on the type of FGO functional groups; of which EDA exhibited the highest performance. These investigations confirmed that the EDA-FGO-reinforced EP/GF composites possess excellent potential to be used as multifunctional engineering materials in industrial applications. 相似文献
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石墨烯由于拥有超高比表面积和超高电导率而被作为电化学电容器材料广泛研究.本文采用树脂为碳源,通过一种方便快捷的树脂交换法制备一种具有高比表面积的多级孔三维石墨烯(3DG).经过此种方法的催化、造孔、热处理等主要工艺步骤后,可显著增加石墨烯材料的小、介孔数量,从而提高材料的电化学性能.通过BET测试表明,3DG的比表面积可达2400 m2/g,孔体积达到2.0 cm3/g.以3DG作为正负极材料制备高比能量高功率型锂离子电容器(3DG-LIC),可使3DG-LIC的工作电压从传统超级电容器的2.5 V扩展到4.0 V,能量密度也从20 Wh/kg提高到105 Wh/kg.另外,相同的化学和微观结构能很好地平衡正负极的容量及速率,使高比能量高功率的3DG-LIC具有更宽阔的应用领域. 相似文献
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《Journal of Coordination Chemistry》2012,65(3):406-417
Two rare 12-tungstovanadate-bipyridine inorganic–organic hybrid compounds, [VW12O40] · 2(4,4′-H2bipy) · 2H2O (1) and [VW12O40] · 4(2,2′-Hbipy) (2), have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction and IR analysis. In 1, a 2-D supramolecular architecture is formed by hydrogen-bonding between [VW12O40]4? and bipy. Compound 1 shows good activity for photocatalytic reduction of rhodamine B in a liquid–solid system. The electrochemical and electrocatalytic properties of 2-bulk carbon paste electrode modified with 2 were investigated by cyclic voltammetry. 相似文献
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The (mixed finite element) discretization of the linearized Navier–Stokes equations leads to a linear system of equations of saddle point type. The iterative solution of this linear system requires the construction of suitable preconditioners, especially in the case of high Reynolds numbers. In the past, a stabilizing approach has been suggested which does not change the exact solution but influences the accuracy of the discrete solution as well as the effectiveness of iterative solvers. This stabilization technique can be performed on the continuous side before the discretization, where it is known as ‘grad‐div’ (GD) stabilization, as well as on the discrete side where it is known as an ‘augmented Lagrangian’ (AL) technique (and does not change the discrete solution). In this paper, we study the applicability of ??‐LU factorizations to solve the arising subproblems in the different variants of stabilized saddle point systems. We consider both the saddle point systems that arise from the stabilization in the continuous as well as on the discrete setting. Recently, a modified AL preconditioner has been proposed for the system resulting from the discrete stabilization. We provide a straightforward generalization of this approach to the GD stabilization. We conclude the paper with numerical tests for a variety of problems to illustrate the behavior of the considered preconditioners as well as the suitability of ??‐LU factorization in the preconditioners. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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Identification,characterization and evolution of non-local quasi-Lagrangian structures in turbulence
Yue Yang 《Acta Mechanica Sinica》2016,32(3):351-361
The recent progress on non-local Lagrangian and quasi-Lagrangian structures in turbulence is reviewed. The quasi-Lagrangian structures, e.g., vortex surfaces in vis-cous flow, gas-liquid interfaces in multi-phase flow, and flame fronts in premixed combustion, can show essential Lagrangian following properties, but they are able to have topological changes in the temporal evolution. In addition, they can represent or influence the turbulent flow field. The challenges for the investigation of the non-local structures include their identification, characterization, and evolution. The improving understanding of the quasi-Lagrangian struc-tures is expected to be helpful to elucidate crucial dynamics and develop structure-based predictive models in turbulence. 相似文献