多通道反应O(3P)＋CH2F的理论研究

用密度泛函理论研究了氧原子与氟代甲基自由基的反应.反应中出现的所有物种的平衡构型用B3LYP方法在6-311＋＋G（2d, 2p）基组水平上进行了优化，同时对各物种进行了频率分析；在同一理论水平上计算了各反应通道的势能面变化，分析了反应物、中间体、过渡态、产物的振动模式随反应途径的变化关系，阐明了该多通道反应的反应机理.     

电爆炸箔断路开关的理论和实验研究

 采用金属箔电爆炸过程的二维数值计算模型，对含电爆炸金属箔断路开关的电感储能脉冲功率调节系统进行了数值计算。以此为基础，研制出了一种低电感型的电爆炸箔断路开关，并以4μF/75kV脉冲电容器组作为初级能源，13Ω电阻作为负载进行实验研究。研究结果表明：在负载上可获得约250kV，脉宽大于400ns的脉冲电压。     

S-5N全固态重复频率脉冲发生器

 主要介绍S-5N的结构及测试实验结果。S-5N型全固态重复频率脉冲发生器是目前国际上同类源中峰值功率和平均功率均为最大的一台。随负载大小的变化，S-5N脉冲发生器的输出电压为400～600kV，输出电流2～3kA，输出脉冲半高宽40～50ns，单脉冲输出能量40～65J。 S-5N脉冲发生器在300Hz重复频率条件下可连续工作，500Hz重复频率条件下可连续工作3min，平均输出功率高达30kW。     

一种改进的2×2 SOI Mach-Zehnder热光开关

本文设计并制作了基于强限制多模干涉耦合器的2×2 SOI马赫-曾德热光开关.这种光开关采用了深刻蚀结构的多模干涉耦合器和输入/输出波导,较大地提高了干涉耦合器的性能并减少了连接耦合损耗.同时,在调制臂区域采用浅刻蚀结构,保持其单模调制状态.深刻蚀多模干涉耦合器具有优越的特性,在实验中测得不均衡度只有0.03 dB,插入损耗－0.6 dB.基于这种耦合器的新型热光开关,其插入损耗为－6.8 dB,其中包括光纤-波导耦合损耗－4.3 dB,开关时间为6.8 μs.     

杨氏双缝干涉实验的光谱变化

从理论和实验上研究了当部分相干光照射在双缝上时,杨氏双缝干涉实验干涉场中的光谱变化.指出干涉场中的归一化光谱在某些空间点处出现了蓝移,在另外一些空间点处出现了红移,而在这些空间点的中间,光谱分裂为等值的两条,出现了光谱开关现象.发现当观察点从轴上向轴外移动的过程中,在很多空间观察点处都出现了光谱开关现象.此外,研究结果还表明光谱相干度将对光谱的移动和光谱开关现象产生重要的影响.     

多信道接入微谐振环波长选择开关特性

对一种新型结构微谐振环波长选择开关的特性进行了研究.分析了器件的工作状态和相应的开关操作,利用新型光强传递函数公式,对器件不同工作状态的光谱响应和不同开关操作的开关响应进行了数值模拟,讨论了耦合系数和损耗对光谱响应和开关响应的影响.结果表明,该器件可以实现三个信道同时接入、两个信道同时接入、单信道接入以及无信道接入等四种方式的信号波长选择性接入.多信道接入方式的开态串扰性能变差,关态的串扰性能不受影响.实现器件上述接入方式之间转换的开关操作可以分成三类,开关操作达到最佳关态串扰时的小微环折射率变化值都在6.0×10－3左右,而实现完全开关时的小微环折射率变化值小于8.0×10－4,表明易于通过热-光效应实现开关操作,并且温度调制的控制容差较大.损耗对器件开关特性的影响结果表明可根据损耗的实际数值,优化信道关闭时的微环折射率取值.     

A Fault Detection Method for Electrohydraulic Switch Machine Based on Oil-Pressure-Signal-Sectionalized Feature Extraction

A turnout switch machine is key equipment in a railway, and its fault condition has an enormous impact on the safety of train operation. Electrohydraulic switch machines are increasingly used in high-speed railways, and how to extract effective fault features from their working condition monitoring signal is a difficult problem. This paper focuses on the sectionalized feature extraction method of the oil pressure signal of the electrohydraulic switch machine and realizes the fault detection of the switch machine based on this method. First, the oil pressure signal is divided into three stages according to the working principle and action process of the switch machine, and multiple features of each stage are extracted. Then the max-relevance and min-redundancy (mRMR) algorithm is applied to select the effective features. Finally, the mini batch k-means method is used to achieve unsupervised fault diagnosis. Through experimental verification, this method can not only derive the best sectionalization mode and feature types of the oil pressure signal, but also achieve the fault diagnosis and the prediction of the status of the electrohydraulic switch machine.     

氨对硅基铁纳米薄膜高温重凝核的影响

采用弧过滤离子沉积系统（arc filtered deposition,AFD）在纯硅表面制备铁纳米薄膜。研究了750℃下铁纳米薄膜在氢气氛围以及氨气氛围中重凝核的规律。研究表明,在氢气氛围中,铁纳米薄膜重凝核以后形成的铁纳米颗粒随薄膜的厚度增加以及保温时间的延长而增大;但在氨气氛围中,铁纳米薄膜重凝核后形成的纳米颗粒的尺寸随保温时间的变化更为复杂：在氨气作用的初始阶段,铁颗粒的尺寸随氨气作用时间的延长而逐渐变大,但一段时间以后,铁颗粒的尺寸又随氨气作用时间的延长而变小,直到铁颗粒平均直径达到一个最小值（大约在氨气介入后的12min）,随后铁颗粒的尺寸又逐渐变大,并最终达到一稳定值。     

Multi-State Second-Order Nonlinear Optical Switches Incorporating One to Three Benzazolo-Oxazolidine Units: A Quantum Chemistry Investigation

This contribution employs quantum chemistry methods to describe the variations of the second nonlinear optical responses of molecular switches based on benzazolo-oxazolidine (BOX) units, connected by π-linkers, along their successive opening/closing. Under the fully closed forms, all of them display negligible first hyperpolarizability (β) values. When one BOX is opened, which is sketched as C→O, a push–pull π-conjugated segment is formed, having the potential to enhance β and to set the depolarization ratio (DR) to its one-dimensional-like value (DR = 5). This is observed when only one BOX is open, either for the monoBOX species (C→O) or for the diBOX (CC→CO) and triBOX (CCC→CCO) compounds, i.e., when the remaining BOXs stay closed. The next BOX openings have much different effects. For the diBOXs, the second opening (CO→OO) is associated with a decrease of β, and this decrease is tuned by controlling the conformation of the π-linker, i.e., the centrosymmetry of the whole compound because β vanishes in centrosymmetric compounds. For the triBOXs, the second opening gives rise to a Λ-shape compound, with a negligible change of β, but a decrease of the DR whereas, along the third opening, β remains similar and the DR decreases to the typical value of octupolar systems (DR = 1.5).     

与偏振无关的双向3×3光开关结构设计

利用传统成熟的偏振控制技术,设计了一种由偏振光分束器、相位型空间光调制器、反射镜和四分之一波片构成的3×3光开关。该光开关具有结构紧凑规整、功能的实现与信号光的偏振态无关以及可以完成双向交换等特点。根据其路由控制表对该3×3光开关交换模块功能的实现进行了分析,结果表明,通过对各相位型空间光调制器状态的调整,控制通过其信号光的偏振态,完成信号光的路由,该交换模块可以完成输入信号光的全排列无阻塞输出与交换。同时,该交换模块具有一定的扩容和重构能力,对于构建大规模的交换矩阵具有一定的作用。