热敏电阻温度计的线性化设计

基于惠斯通非平衡电桥的热敏电阻温度计,其电压—温度的关系是非线性的。在此基础上利用运算放大电路,通过选择合适的电路参数可以使电压与温度的关系线性化。实验结果与利用计算程序软件得到电压—温度特性的理论值非常接近。     

近代海相沉积型海域大桥施工关键技术研究

近代海相沉积型海域是我国沿海典型地质条件, 由于其构造独特和力学特性复杂, 在建造大桥时必须采取针对性的措施. 因此从跨海大桥施工的测控技术、桥墩桩基和栈桥寿命维护等方面出发, 探讨沉积型海域跨海大桥施工的关键技术, 并在平潭海峡大桥施工中得到了实际应用.     

用电阻箱自组电桥的桥臂电阻选择

本文分析了用电阻箱作桥臂电阻自组电桥的灵敏度及测量结果不确定度,给出桥臂电阻的选择原则。     

惠斯登电桥精测电阻的方法和误差分析

本文探讨了惠斯登电桥精确测量和校准电阻的方法，并分析了内插法和代换法的系统误差。     

钢桥面板顶板与纵肋连接疲劳开裂局部加固分析

正交异性钢桥面板纵肋与顶板连接细节处极易产生疲劳裂纹.本文通过精细化有限元模型,分析了栓接角钢加固法和粘贴纤维增强复合材料(Fiber Reinforced Polymer, FRP)型材加固法对钢桥面板疲劳性能的影响.结果表明:采用角钢、FRP型材对顶板与纵肋连接细节的疲劳裂纹进行加固,焊缝裂纹附近热点应力峰值降幅可达56.2%和46.5%;焊缝裂纹尖端附近应力强度因子随着板件整体尺寸的增大而减小;改变板件厚度对应力强度因子结果值影响最大,最高可使其下降约80%,改变板件纵向长度和单肢长度对其有一定影响;随着裂纹的持续扩展,栓接角钢法的加固效果开始下降.建议在监测到构造细节处疲劳裂纹后应尽早加固.     

Chemical analysis of Gothic mortar from a bridge pier in Roudnice nad Labem (Czech Republic)

In this paper, a Gothic mortar originating from the remains of a bridge pier in Roudnice nad Labem (Czech Republic) was analyzed. The inorganic composition of the mortar showing special mechanical properties was studied using polarizing light microscopy, scanning electron microscopy coupled with energy dispersive X-ray spectrometry, and X-ray diffraction, while the protein content was analyzed by peptide mass mapping using matrix-assisted laser desorption/ionization—time of flight mass spectrometry and nanoliquid chromatography coupled to tandem mass spectrometry. Two types of inorganic binders having a composition similar to mineral wollastonite and hydraulic lime and milk protein additive were detected. We believe that organic and inorganic binders added together to the mortar increase its hardness and firmness in the aquatic environment.     

Synthesis, characterization and magnetism of binuclear cobalt (II) complexes bridged by tetracarboxylato groups

Three new binudear cobalt (II) complexes with extended te-tracarboxylato- bridge have been synthesized and characterized, namely [Co2 (PMTA) (bpy)4] (1), [Co2(PMTA)-(phen)4] (2) and [Co2(PMTA) (NO2phen)4] (3), where PMTA represents the tetraanion of pyroniellitic acid, and bpy, phen, NO2-phen denote 2,2'-bipyridine, 1,10-phenan-throline; 5-nirto-1, 10-plienanthroline, respectively. Based on elemental analyses, molar conductivity measurements, IR and electronic spectra studies, it is proposed that these complexes have PMTA-bridged structures and consist of two cobalt (II) ions, each in a distorted octahedral environment. These complexes were further characterized by variable temperature magnetic susceptibility measurements (4-300 K) and the observed data were successfully simulated by the equation based on the spin Hamiltonian operator, giving the exchange integral J = - 1.02 cm-1 for 1, J = -1.21 cm-1 for 2 and J = - 1.18 cm-1 for 3, respectively. These results revealed the operation of antiferromagneti     

Carpet Beater Molecules: Synthesis and Characterization of Functional Hexa-peri-benzocoronene–Alkyne Coupling Products

Within the scope of this paper, nine π-expanded mono-substituted 5,8,11,14,17-pentakis-(tert-butyl)-hexa-peri-hexabenzocoronenes (HBC) are introduced. 2-Iodo-5,8,11,14,17-pentakis-(tert-butyl)-hexa-peri-hexabenzocoronene served as precursor and was reacted with ethynyltrimethylsilane in a Sonogashira coupling reaction. The acetylene unit is used as a linker and can undergo another Sonogashira coupling reaction combining different phenyl coupling partners with the HBC core. The electron-withdrawing groups such as nitrile, pyridine and carbonyl species (aldehyde, methylester, carboxylic acid) as well as the three quinoxaline based species (diphenylquinoxaline, dibenzo[a,c]phenazine, phenanthro[4’,5’-a,b,c]phenazine) serve as substitution moieties. Their influence on the optoelectronic properties were investigated by UV/Vis absorption spectroscopy demonstrating a maximum redshift of 7 nm compared to starting compound 2-Iodo-5,8,11,14,17-pentakis-(tert-butyl) HBC. As for the phenanthro[4’,5’-a,b,c]phenazine substituted HBC a dramatic decrease in the intensity of the absorption of the UV/Vis spectrum was observed. The fluorescence spectroscopy pointed out that the dibenzo[a,c]phenazine and phenanthro[4’,5’-a,b,c]phenazine substitution changed the spectra to one broad peak departing from the characteristic HBC-like emission pattern.     

Novel Cyanide-Bridged Three-Dimensional Coordination Polymer Derived from an Octahedral Rhenium Cluster [Re6Te8(CN)6]4?: Synthesis and Crystal Structure of [{Mn(H2O)2(DMF)} 2Re6Te8(CN)6]·2H2O

The reaction of a water solution of K₄Re₆Te₈(CN)₆ with a solution of Mn(NO₃)₂ in 0.02M hydrochloric acid in the presence of DMF gave crystals of a cluster rhenium complex [{ Mn(H₂O)₂(DMF)}₂Re₆Te₈(CN)₆]·2H₂O. The structure of the compound was determined by single crystal X-ray diffraction (a = 12.6679(9) Å, b = 17.4524(12) Å, c = 9.7882(6) Å, β = 105.570(6)°, V = 2084.6(3) ų, Z = 2, space group P2₁/n, R = 0. 0389). In the complex, the [Re₆Te₈(CN)₆]⁴⁻ cluster anions are linked to Mn²⁺ cations by the cyanide bridges, the manganese cations being additionally coordinated by the DMF molecule and two water molecules. The neighboring clusters are joined by Re-C-N-Mn bridges into a three-dimensional framework possessing cavities filled with doubly disordered water molecules.Original Russian Text Copyright © 2004 by Yu. V. Mironov, S. F. Solodovnikov, V. E. Fedorov, and Yu. V. Gatilov__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 918–922, September–October, 2004.     

Polycyclic aromatic hydrocarbon-bridged coumarin derivatives for organic light-emitting devices

Three biscoumarin dyes bridged by polycyclic aromatic bridges (anthracen, pyrene and dibenzo[g,p]chrysene) were prepared as the emissive materials for the application of organic light-emitting devices. The relationship between their structures, photophysical properties, electrochemical properties and performances of organic light-emitting devices are described. The multilayered doped devices with a configuration of ITO/NPB (20 nm)/TBADN: biscoumarin compound (x wt%, 30 nm)/TPBi (30 nm)/Liq (2 nm)/Al (100 nm) have been successfully fabricated by vacuum-deposition method. All the devices showed green emission with high electroluminescent efficiencies. Especially, the device based on the compound containing pyrene as a bridge group at 7% doping concentration showed the best performance with a maximum brightness of 10552 cd/m², maximum luminous efficiency of 5.39 cd/A and maximum external quantum efficiency (EQE) of 2.35%.