Enhanced Metal-Support Interactions Boost the Electrocatalytic Water Splitting of Supported Ruthenium Nanoparticles on a Ni3N/NiO Heterojunction at Industrial Current Density

Developing highly efficient and stable hydrogen production catalysts for electrochemical water splitting (EWS) at industrial current densities remains a great challenge. Herein, we proposed a heterostructure-induced-strategy to optimize the metal-support interaction (MSI) and the EWS activity of Ru-Ni₃N/NiO. Density functional theory (DFT) calculations firstly predicted that the Ni₃N/NiO-heterostructures can improve the structural stability, electronic distributions, and orbital coupling of Ru-Ni₃N/NiO compared to Ru-Ni₃N and Ru-NiO, which accordingly decreases energy barriers and increases the electroactivity for EWS. As a proof-of-concept, the Ru-Ni₃N/NiO catalyst with a 2D Ni₃N/NiO-heterostructures nanosheet array, uniformly dispersed Ru nanoparticles, and strong MSI, was successfully constructed in the experiment, which exhibited excellent HER and OER activity with overpotentials of 190 mV and 385 mV at 1000 mA cm⁻², respectively. Furthermore, the Ru-Ni₃N/NiO-based EWS device can realize an industrial current density (1000 mA cm⁻²) at 1.74 V and 1.80 V under alkaline pure water and seawater conditions, respectively. Additionally, it also achieves a high durability of 1000 h (@ 500 mA cm⁻²) in alkaline pure water.     

Comprehensive two-dimensional gas chromatography— A discussion on recent innovations

Although comprehensive 2-D GC is an established and often applied analytical method, the field is still highly dynamic thanks to a remarkable number of innovations. In this review, we discuss a number of recent developments in comprehensive 2-D GC technology. A variety of modulation methods are still being actively investigated and many exciting improvements are discussed in this review. We also review interesting developments in detection methods, retention modeling, and data analysis.     

滑频滤波器对偏振模色散补偿之研究

对40Gb/s的光脉冲传输系统使用滑频滤波器控制,可减少偏振模色散的影响,提高光脉冲传输的距离.数值计算结果表明:滑频滤波器对偏振模色散效果随传输码型而变化,对色散管理孤子系统的补偿效果最佳,对归零码系统的补偿效果并不显著.     

一种重构辐射噪声调制谱的方法

在进行辐射噪声信号的仿真研究中,希望利用经滤波、特征提取等处理所得到的反映目标特性的线谱、连续谱、调制谱来重构辐射噪声,以便于研究辐射噪声在声场中的传播特性。本文提出了利用迭代算法估算调制深度谱的算法,给出了时域辐射噪声的重构模型,以实测数据的调制谱为出发点,来重构其时域信号,并对重构前后的调制谱进行了误差分析,取得了较好的效果。     

云纹干涉载频调制技术及分析

在物体变形场的测量中,云纹干涉的载频调制技术有重要作用.在云纹干涉中,对称光照明产生的衍射光沿试件栅表面的法线传播并产生干涉.通过改变照明光的入射角度,可实现变形条纹场的空间调制.通过光程差的分析说明了载波条纹产生的机理,得出了载波频率与照明光入射角度变化之间的关系式.利用三点弯曲加载结合二维载频调制实验,给出了实验结果.证明了在初始条纹较少的情况下,载频调制技术能有效地测量物体的位移场.     

Comprehensive two-dimensional gas chromatography: a powerful and versatile analytical tool

Comprehensive two-dimensional gas chromatography (GC×GC) is a novel technique which is rapidly gaining importance for the analysis of complex samples. In the present review, attention is devoted to the principle and advantages, and main characteristics such as modulation, column combinations, detector requirements and data processing, of the technique. Specifically, GC×GC of a variety of real-life samples is discussed to demonstrate the applicability of the technique, with emphasis on the usefulness of the ordered-structure principle and on the analyte-identification power provided by a combination with time-of-flight mass spectrometric detection.     

光纤传感器的分类及其应用原理

光纤传感器是一种有广泛应用前景的新型传感器。文章介绍了光纤传感器的基本原理、分类及其优点。并分别阐述了光强调制型、相位调制型和偏振态调制型光纤传感器的应用原理及基本特点。     

转镜式光谱仪端反射镜误差容限分析

系统分析了当转镜式干涉光谱仪端反射镜发生倾斜,致使反射光束偏转时对干涉图的影响.发现光束偏转带来的误差分为三部分：1）光束偏转导致整体增加的恒定光程差;2）垂直光轴方向因不同光线而引入的偏移光程差;3）光束中心相对于光轴的偏移量.干涉强度中的有效信号减小,同时直流分量不变,因此信噪比降低.最后从调制度和相位误差角度给出了端反射镜倾斜误差容限并讨论了减小干涉图受光束偏转影响的方法.     

玫瑰扫描亚成像系统的性能分析

利用调制传递函数(MTF)法,分析了玫瑰扫描制导系统的光学系统模块和探测器模块的参量对系统性能的影响,重点分析了探测器模块的影响,并给出仿真计算结果,由结果分析指出系统设计时选择参量的一种新思路.