强双折射光纤中单一频率传输区域的调制不稳定性

利用光脉冲在光纤中传播时所遵守的相干非线性薛定谔耦合方程,研究了单一频率的线偏振光,且偏振方向沿两个双折射轴的分量强度相等时,在反常色散区和正常色散区所产生的调制不稳定性.结果表明在反常色散区和正常色散区,对应不同的功率区域输入脉冲有不同的增益谱,并且当输入脉冲功率一定时,双折射性质变化导致增益谱表现出明显的不同.     

乙酸调控MIL-53(Fe)的形貌演变及其高效选择性氧化H2S性能

硫化氢(H2S)广泛存在于以煤、石油和天然气等为原料的化工生产过程中,不仅腐蚀管道和设备,而且还会对健康和环境造成危害.因此,高效脱除H2S已成为工业废气减排的重点.在各种方法中,H2S选择性氧化技术(H2S+(1/2)O2→(1/n)Sn+H2O)由于具有设备需求低、反应不受热力学平衡限制、理论转化率可达100%等优点展现出了巨大的应用前景.实现这一过程的关键在于发展高效稳定的催化剂.作为一类新兴的多孔材料,金属-有机骨架材料(MOFs)由于其独特的结构和性质吸引了广泛的研究兴趣.与传统的脱硫材料相比,MOFs的优势主要体现在:1)高度分散的金属原子可作为催化活性中心;2)超高比表面积和规则的孔结构有利于反应物与活性位点之间的接触;3)结构可调变性高,通过在合成过程中有目的地引入配体或调控剂可产生额外的活性位点,满足特定催化的需求.基于以上特点可知,MOFs是一类有潜力的催化剂,但目前将其应用于H2S选择性氧化领域的研究尚处于起步阶段.本文以典型的铁基MOFs MIL-53(Fe)为研究对象,在制备MIL-53(Fe)过程中添加乙酸(HAc)作为调控剂,通过控制HAc的量,得到一系列具有不同形貌的MIL-53(Fe)-xH样品,并将其应用于H2S选择性氧化反应.SEM结果表明,在MIL-53(Fe)的合成过程中引入乙酸可以显著影响样品的形貌和尺寸.活化前后样品的XRD结果表明,HAc具有与对苯二甲酸(H2BDC)相似羧基基团,二者均可与Fe–O团簇配位.此外,TG-DSC结果证实,随着HAc加入量的提高,与Fe^3+形成配位的HAc/H2BDC比值随之增加.FT-IR和Raman结果进一步证明HAc成功地配位到MIL-53(Fe)的框架中,并且参与配位的HAc可通过真空活化移除从而暴露出Fe^3+不饱和位点.H2S选择性氧化测试表明,MIL-53(Fe)-xH的脱硫活性随着HAc含量的提高先增加然后降低,其中MIL-53(Fe)-5H活性最优.此外,MIL-53(Fe)-5H催化剂在连续运行55 h后仍能保持100%H2S转化率和86%硫选择性,性能远优于传统的Fe2O3催化剂.吡啶原位红外光谱结果表明,HAc的引入可以产生额外的Lewis酸性位点(LAS),LAS含量的不同是造成催化剂活性差异的主要原因.     

Characteristics of microwave filters based on microstrip photonic bandgap ring structures

We study the characteristics of microstrip ring exhibiting photonic band gap properties. Since the stop band is caused by the reflection of electromagnetic waves at the narrow gap introduced in the ring, the geometry of the ring can influence on the characteristics of stop band. The center frequency of the stop band is determined mainly by the outer ring radius when the line width of the circular ring is rather narrow. But it is determined mainly by the mean ring radius when the ring is not a circular form or the line width of circular ring is wide. The frequency range of the stop band can be varied by a reactive component mounted on the gap. The presence of capacitor (inductor) on the gap decreases (increases) the center frequency and the frequency range of the stop band. Moreover, the stop band can be widened by modifying the geometry of ring. These properties can be useful in the applications to the compact microwave circuits, tunable filters and microwave switches.     

The inclusion relation between Sobolev and modulation spaces

The inclusion relations between the Lp-Sobolev spaces and the modulation spaces is determined explicitly. As an application, mapping properties of unimodular Fourier multiplier eiα|D| between Lp-Sobolev spaces and modulation spaces are discussed.     

Analysis modulation formats of DQPSK in WDM-PON system

In the modulation and demodulation methods of the optical differential quadrature phase shift key (DQPSK) and the different modulation formats including nonreturn-to-zero (NRZ), return-to-zero (RZ), carrier-suppressed return-to-zero (CS-RZ) are introduced, studying the different optical signals in the 40 Gb/s high speed transmission system. The system is simulated in 200 km optical fiber by way of dispersion compensation. It is showed that the ability of anti-dispersion and anti-PMD (polarization mode dispersion) is better in the CS-RZ-DQPSK modulation format, and this format has the smallest eye-opening penalty (EOP) with a wider range of power into the optical fiber.     

Compton 散射对线偏光在相对论等离子体中调制不稳定性的影响

应用多光子非线性Compton 散射模型、电磁波非线性色散方程和Karpman 方法,研究了 Compton 散射对线偏光在相对论等离子体中调制不稳定性的影响,给出了等离子体的非线性色散、控制和调制不稳定性增 长率的修正方程,并进行了数值模拟。结果表明：与散射前相比,随无量纲化频率值减小,即趋于等离子体临界面处,散射使相同扰动波数引起的调制不稳定性增长率更大,使等离子体临界面处的调制不稳定性增长率较其余位置尤为显著。这是由于散射光使等离子体非线性增强,形成了激光场自聚焦和自成丝的缘故。     

光谱数据对油页岩含油率近红外光谱分析PLS建模精度的影响

目前油页岩关键的评价参数——含油率的检测方法均无法实现原位测量,无法满足油页岩资源的勘查和开采中样品检测的要求。便携式近红外光谱分析技术,为实现油页岩含油率的原位检测提供了可能性。由于光谱数据的不同形式与样品的成分含量值之间有不同的相关关系,样品不同成分的吸收特性表现在不同的近红外波段上,因此利用合成样品,针对反射率、吸光度、K-M函数等三种不同的光谱数据表示形式和四种不同的建模区间,研究它们对油页岩含油率PLS模型精度的影响情况。结果表明：对于合成样品,进行PLS建模的最佳光谱数据形式是反射率,最佳建模区间是组合特征区间,即适当的光谱数据形式及建模区间可提高模型的精度。     

Theory and experiment analysis of factors affecting THG efficiency for the TIL prototype laser facility

Based on the study and manufacture of the technical integration experiment line (TIL) prototype laser facility, and using the method that theoretical simulations guide experiments and experimental results check programs, the factors affecting third harmonic generation (THG) efficiency for a large-aperture, high-intensity inertial confinement fusion (ICF) laser facility have been analyzed and studied in detail. Furthermore, in the year 2004-2005, the output ability of a THG system for a TIL driver has been discussed adequately in a first beam eligibility experiment. As shown by experimental results, when the average drive irradiance of fundamental light, I_1ω, is 2.7 GW/cm², the measured value of THG efficiency is 50-55% and the theoretical value is 60%, which indicates that the experimental result agrees well with the theoretical value.     

转镜式干涉光谱仪中的误差容限研究

通过分析可知,转镜的晃动不影响干涉图的调制度,但会带来干涉图周期的变化.通过研究晃动带来干涉图的周期变化,可找到晃动的容限.结果表明：转镜式干涉光谱仪对转镜的晃动不敏感.用同样的方法可以确定转镜转速误差的容限,转镜对转速稳定性有着较高的要求.转镜式干涉光谱仪中的反射镜不是动件,安装时的倾斜对干涉图的调制度和相位都有影响,通过计算,这种影响可得到反射镜的倾斜容限.结果表明,转镜式干涉光谱仪对反射镜的安装准确度有很高的要求.     

Spatiotemporal instability in dispersive nonlinear Kerr medium with a finite response time

We investigated the spatiotemporal modulation instability (MI) in a medium with a non-instantaneous Kerr response in which the nonlinear contribution to the refractive index is governed by a relaxing Debye type equation. The expression for the MI gain spectrum in non-instantaneous Kerr medium is obtained, which clearly reveals the influence of the finite time of the nonlinear response (relaxation effect) on the spatiotemporal MI. It is shown that, due to the relaxation effect, the spatiotemporal MI can appear for the case of anomalous dispersion and defocusing nonlinearity, while it cannot appear in instantaneous Kerr medium for the same case, and a new MI gain spectrum appears, adding to the conventional MI gain spectrum similar to that in an instantaneous Ker medium. In addition, the bandwidth of MI gain spectrum is extended and the maximum MI gain is reduced with increasing of the relaxation time. Interestingly, spatiotemporal MI can appear for any spatial frequencies in non-instantaneous Kerr medium for any combination of dispersion and nonlinearity. We have performed an experiment of MI in carbon disulfide (CS₂), a typical non-instantaneous Kerr medium, which shows quantitative agreement with the theoretical analyses.