电子诱导脱附研究钨表面O2对N2的置换吸附

实验测量了室温高真空条件下,多晶W表面O2和N2的电子诱导脱附（ESD）阈值能量.O2-W吸附对的ESD能量约为15.5 eV, N2-W吸附对的ESD能量约为13.8 eV.实验结果具有良好的可重复性.利用ESD阈值能量研究了多晶W表面O2对N2的置换吸附过程,表明在一定的时间间隔内,O2可以置换吸附在多晶W表面的N2,且该过程不可逆.对实验结果进行了分析.     

Comparative surface plasmon resonance and enzyme-linked immunosorbent assay characterisation of a monoclonal antibody with N-acyl homoserine lactones

This study shows the detection of (N-acyl) homoserine lactones (AHLs or HSL) with monoclonal antibodies via a surface plasmon resonance (SPR)-based immunosensor in comparison to conventional microtiter plate-based enzyme-linked immunosorbent assay (ELISA). An HSL derivative, named HSL2 (Table 1), was attached to bovine serum albumin (BSA) and the conjugate (HSL2-BSA-r2) was either covalently immobilised on the SPR sensor chip surface via free amino groups or via adsorption on the ELISA polystyrene plate surface. With a newly developed rat monoclonal antibody (mAb HSL1/2 2C10), AHLs were detected sensitively in a competitive format with SPR and ELISA. Well comparable experiments between SPR and ELISA could be obtained in buffers. Moreover, the SPR sensor surface with the immobilised conjugate HSL2-BSA-r2 could be regenerated at least 340 times (regeneration cycles) without loss of activity. The measurement time per cycle was approximately 15 min. The competitive detection format for SPR and ELISA allowed the detection in the μg L⁻¹ range.     

降解裙带菜多糖对纳米硒的形成与稳定作用

在常温下的降解裙带菜多糖(Degraded Undaria Pinnatifida Charv. Suringer polysaccharide, DUP)水溶液中, 由适当过量的抗坏血酸(Vc)与二氧化硒(SeO2)反应制备纳米单质硒(Se0). 通过共振瑞利散射、激光散射和透射电镜(TEM)研究了DUP对Se0粒径的调控和在液相中的稳定作用. 结果表明, DUP通过控制还原速度和表面修饰而把Se0粒子调节在较窄的粒径分布范围内当Se0浓度为0.0507—3.245 mmol/L时, DUP表面修饰的球状纳米硒的平均粒径稳定地保持在24—65 nm范围内, 4 ℃时可在水溶液中稳定保存1个月.     

Binary and ternary oscillations in a cubic numerical scheme

We study a central difference semi-discretization of the cubic scalar conservation law. Both spatial period-2 (binary) and period-3 (ternary) oscillations are stationary solutions of this scheme, and we find where each type is linearly stable. We observe numerically the formation of ternary oscillations, to the left of Riemann shock initial data with u_r = 0, while binary oscillations form to the right of Riemann rarefaction data having u_l = 0. We derive modulation equations for both wave patterns, using them to show that binary oscillations generated by the scheme are numerical artifacts, while computing an explicit solution for the ternary modulation equations. For positive initial data, the ternary modulation equations remain hyperbolic, while the solutions enter an elliptic region for data of both signs. Conditions under which solutions of the ternary modulation equations can be inverted to yield period-3 oscillations are also discussed.     

Selection of modulation frequency of FT-IR equipped with an MCT detector for thin-film analysis

Optimal modulation frequency (scan rate) of an FT-IR equipped with a mercury–cadmium–telluride (MCT) detector has been investigated for obtaining high quality spectra of a monolayer-level thin film. Since an MCT detector is a semiconductor light device, it does not respond to modulation frequency significantly in comparison to a pyroelectric detector. A very thin film, however, requires high-throughput measurements to have high signal-to-noise ratio. In this study, a balance of throughput and measurement time has been investigated by varying modulation frequency by using two spectrometers that have different sampling frequencies. In this study, the stability of the baseline of absorbance spectra was also investigated depending on modulation frequencies, which suggested that 60 kHz was most suitable for quantitatively reliable transmission measurements of Langmuir–Blodgett films.     

Metaplectic representation on Wiener amalgam spaces and applications to the Schrödinger equation

We study the action of metaplectic operators on Wiener amalgam spaces, giving upper bounds for their norms. As an application, we obtain new fixed-time estimates in these spaces for Schrödinger equations with general quadratic Hamiltonians and Strichartz estimates for the Schrödinger equation with potentials V(x)=±²|x|.     

Boundedness Properties of Pseudo-Differential and Calderón-Zygmund Operators on Modulation Spaces

In this article, we study the boundedness of pseudo-differential operators with symbols in S _ρ,δ ^m on the modulation spaces M ^p,q . We discuss the order m for the boundedness Op(S _ρ,δ ^m )⊂ℒ(M ^p,q ) to be true. We also prove the existence of a Calderón-Zygmund operator which is not bounded on the modulation space M ^p,q with q≠2. This unboundedness is still true even if we assume a generalized T(1) condition. These results are induced by the unboundedness of pseudo-differential operators on M ^p,q whose symbols are of the class S _1,δ ⁰ with 0<δ<1.      

提高GM(1，1)模型拟合预测精度的研究

在简单介绍GM(1,1)模型预测过程的基础上,指出了模型在求解微分方程时已知条件选取和背景值构造两方面存在不足,并对此提出了更换已知条件及通过求解最小值获取背景值构造形式的改进措施.通过把这两种措施进行有机结合,形成了一种新的预测程序和方法.并且通过实例分析证明了这种新的程序和方法的确能够提高GM(1,1)模型的拟合预测精度.     

基于周期极化反转铌酸锂光波导高速非归零码到归零码的转换

研究了基于周期极化反转铌酸锂光波导级联二阶非线性效应实现非归零码到归零码高速全光码型转换的新方案，使用的是马赫-曾德尔干涉仪结构.转换原理是非归零码信号光在级联倍频和差频过程中受到的放大作用引起马赫-曾德尔干涉仪的不平衡，进而通过干涉相消产生归零码信号光输出.首先从耦合波方程出发，数值模拟了非归零码到归零码码型转换过程.然后分析了波导长度、光功率、相对时延对消光比的影响并对码型转换进行了优化设计.最后分析了转换带宽，模拟计算表明信号光在90nm的3dB带宽内可调谐，进而可以实现多信道的同时转换.     

The continuous wave electron paramagnetic resonance experiment revisited

When the modulation frequency used in continuous wave electron paramagnetic resonance (cw EPR) spectroscopy exceeds the linewidth, modulation sidebands appear in the spectrum. It is shown theoretically and experimentally that these sidebands are actually multiple photon transitions, sigma(+)+kxpi, where one microwave (mw) sigma(+) photon is absorbed from the mw radiation field and an arbitrary number k of radio frequency (rf) pi photons are absorbed from or emitted to the modulation rf field. Furthermore, it is demonstrated that both the derivative shape of the lines in standard cw EPR spectra and the distortions due to overmodulation are caused by the unresolved sideband pattern of these lines. The single-photon transition does not even give a contribution to the first-harmonic cw EPR signal. Multiple photon transitions are described semiclassically in a toggling frame and their existence is proven using second quantization. With the toggling frame approach and perturbation theory an effective Hamiltonian for an arbitrary sideband transition is derived. Based on the effective Hamiltonians an expression for the steady-state density operator in the singly rotating frame is derived, completely describing all sidebands in all modulation frequency harmonics of the cw EPR signal. The relative intensities of the sidebands are found to depend in a very sensitive way on the actual rf amplitude and the saturation of single sidebands is shown to depend strongly on the effective field amplitude of the multiple photon transitions. By comparison with the analogous solutions for frequency-modulation EPR it is shown that the field-modulation and the frequency-modulation technique are not equivalent. The experimental data fully verify the theoretical predictions with respect to intensities and lineshapes.