全文获取类型
收费全文 | 9684篇 |
免费 | 1813篇 |
国内免费 | 1330篇 |
专业分类
化学 | 5373篇 |
晶体学 | 380篇 |
力学 | 970篇 |
综合类 | 138篇 |
数学 | 221篇 |
物理学 | 5745篇 |
出版年
2024年 | 16篇 |
2023年 | 62篇 |
2022年 | 215篇 |
2021年 | 286篇 |
2020年 | 260篇 |
2019年 | 249篇 |
2018年 | 284篇 |
2017年 | 399篇 |
2016年 | 467篇 |
2015年 | 357篇 |
2014年 | 500篇 |
2013年 | 887篇 |
2012年 | 674篇 |
2011年 | 631篇 |
2010年 | 567篇 |
2009年 | 614篇 |
2008年 | 566篇 |
2007年 | 659篇 |
2006年 | 567篇 |
2005年 | 529篇 |
2004年 | 494篇 |
2003年 | 442篇 |
2002年 | 369篇 |
2001年 | 318篇 |
2000年 | 318篇 |
1999年 | 311篇 |
1998年 | 244篇 |
1997年 | 207篇 |
1996年 | 186篇 |
1995年 | 157篇 |
1994年 | 138篇 |
1993年 | 155篇 |
1992年 | 126篇 |
1991年 | 73篇 |
1990年 | 71篇 |
1989年 | 64篇 |
1988年 | 84篇 |
1987年 | 47篇 |
1986年 | 40篇 |
1985年 | 24篇 |
1984年 | 17篇 |
1983年 | 10篇 |
1982年 | 28篇 |
1981年 | 23篇 |
1980年 | 15篇 |
1979年 | 23篇 |
1978年 | 15篇 |
1977年 | 10篇 |
1976年 | 7篇 |
1973年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 33 毫秒
71.
荧光光谱法研究蛋白质构象的电磁-温度协同效应 总被引:1,自引:1,他引:0
长期以来电磁生物效应受到人们普遍关注,近年来从各个角度进行了相关研究。电磁-温度协同效应是当前的热点。本研究通过电磁场及温度协同对蛋白质影响的研究,发现蛋白质在电磁场作用下的不可逆变性,而且这种变性也遵循Arrhenius规律,并进一步得出电磁-温度协同作用的蛋白质变性模型。本文从分子反应动力学的角度解释了电磁-温度协同效应,并对非热效应作了一定的探讨。 相似文献
72.
由Q-Nd:YAG脉冲激光(波长1.06μm,脉宽10 ns)烧蚀Al靶产生等离子体.观测了在低气压和直流电场条件下的Al等离子体发射光谱.研究了激光功率密度和直流电场对各谱线强度的影响,分析了谱线半高全宽与外加电压,等离子体电子温度与激光能量的变化规律.结果表明,直流电场对铝原子谱线强度有显著的增强,铝原子谱线的半高全宽与直流电场的外加电压基本上呈线性关系. 相似文献
73.
为了获得CH分子束及其相关特性,以氦气为载气,利用直流脉冲放电技术产生了CH分子束。实验记录了放电时间相对于脉冲分子束不同延时CH光谱信号强度的变化,放电相对延时为460μs左右获得最大的信号强度。研究了在保持CH4/He总气压3 atm和放电电压-4 kV不变的条件下CH分子束强度与不同配比的关系,建立了理论模型,对实验数据进行了理论拟合,拟合曲线与实验结果符合较好,配比为1%(甲烷与氦的气压比为1∶99)左右能够维持较稳定的放电现象和较强的放电强度而获得较强的CH自由基束流。在这一配比下对CH(A2Δ-X2Π)(0,0)带发射光谱进行探测和分析,获得CH(A2Δ)转动温度和振动温度分别为2455 K和4575 K,并估计此时每个脉冲中大约包含1013~1014个CH自由基。 相似文献
74.
陈隆懋 《光谱学与光谱分析》1997,17(4):73-76
本文对国产WLY100型顺序扫描ICP光谱仪在设计中对单色仪,高频发生器,扫描机构,测光系统,短紫外光域的测量,恒温,气流控制与软件编制等方案的选择作了详尽的阐述,稳妥的方案使研制工作顺利进行,保证整机一次成功。 相似文献
75.
76.
D. Radic L. H. Tagle A. Opazo A. Godoy L. Gargallo 《Journal of Thermal Analysis and Calorimetry》1994,41(5):1007-1018
Poly(monoitaconates) containing octyl, decyl and dodecyl groups and random monoalkylitaconate-co-vinylpyrrolidone copolymers were studied by thermogravimetric analysis. Copolymers of mono-n-octylitaconate (MOI), mono-n-decylitaconate (MDI), and mono-n-dodecylitaconate (MDoI), respectively, with N-vinyl-2-pyrrolidone (VP) of different compositions were studied by dynamic thermogravimetric analysis. The thermal stability of the copolymers depends on the structure of the monoitaconate comonomer and on the composition of the copolymer The kinetic analysis of the degradation data shows that the thermal decomposition of these copolymers can be described by several kinetic orders depending on the copolymer and on the composition. The relative thermal stability of the copolymers increases as the VP content increases and as the length of the side chain of the itaconate increases, following the same trend as the flexibility of the copolymers in solution. 相似文献
77.
本文在Skyr}e相互作用、核物质近似和自洽半经典方法的基础上,将微观光学势的自洽研究推J“到中能区(60-r300MeV),研究了”+907r在该能区光学势的径向形状和温度效应 相似文献
78.
We present a calculation of the electronic Raman cross section for the scattering of light across the energy gap of an antiferromagnetic insulator. The antiferromagnet is described in terms of a spin density wave state for the Hubbard model at half filling. We consider the coupling of the light to the current density and the inverse mass tensor on equal footing. A comparison of the cross section for different scattering geometries is given. 相似文献
79.
The motivation of this work is to provide reliable and accurate modeling studies of the physical (surface, thermal, mechanical and gas diffusion) properties of chitosan (CS) polymer. Our computational efforts have been devoted to make a comparison of the structural bulk properties of CS with similar type of polymers such as chitin and cellulose through cohesive energy density, solubility parameter, hydrogen bonding, and free volume distribution calculations. Atomistic modeling on CS polymer using molecular mechanics (MM) and molecular dynamics (MD) simulations has been carried out in three dimensionally periodic and effective two dimensionally periodic condensed phases. From the equilibrated structures, surface energies were computed. The equilibrium structure of the films shows an interior region of mass density close to the value in the bulk state. Various components of energetic interactions have been examined in detail to acquire a better insight into the interactions between bulk structure and the film surface. MD simulation (NPT ensemble) has also been used to obtain polymer specific volume as a function of temperature. It is demonstrated that these V–T curves can be used to locate the volumetric glass transition temperature (Tg) reliably. The mechanical properties of CS have been obtained using the strain deformation method. Diffusion coefficients of O2, N2, and CO2 gas molecules at 300 K in CS have been estimated. The calculated properties of CS are comparable with the experimental values reported in the literature. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1260–1270, 2007 相似文献
80.
We have studied the temperature dependence of the radiative deactivation of the Pd-porphine triplet states in Shpol’skii matrices
in the temperature range 1.2–210 K. A substantial transformation of the phosphorescence spectra is observed as the temperature
increases and is due to the inclusion of thermally activated Pd-porphine states in the radiative deactivation processes. The
activation energy Ea of these Pd-porphine states is measured in matrices of n-octane and n-nonane. The splitting of the lowest quasidegenerate
triplet state ΔE(T2−T1) is determined for planar and distorted conformations of the Pd-porphine macrocycle in the n-octane matrix as 40 and 57 cm−1, respectively. The ability to use the temperature dependence of the phosphorescence properties of Pd-porphine to fabricate
molecular thermometers for the low-temperature range is analyzed.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 4, pp. 460–464, July–August, 2007. 相似文献