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21.
Hyperfine Interactions - Horse spleen apoferritin was reconstituted with varying numbers of iron atoms per protein shell at 25 and 50°C. Samples with mean particle sizes ranging from...  相似文献   
22.
Shinjo  Teruya  Mibu  Ko 《Hyperfine Interactions》2002,144(1-4):53-64
Hyperfine Interactions - The giant magnetoresistance (GMR) effect was an epoch-making discovery in the field of magnetic materials research. In this article, studies on magnetic multilayered...  相似文献   
23.
We report on a 197Au Mössbauer study of several types of supported gold catalysts. Differences in particle size show up in the Mössbauer spectra by a change in the relative weight of the spectral contribution of the surface atoms. The presence of ionic gold in active gold catalysts is not observed. The spectra can be interpreted in terms of bulk-like contributions from the inner-core atoms plus contributions from the outermost atoms at the surface of the particles.  相似文献   
24.
Funk  Felix  Long  Gary J.  Hautot  Dimitri  Büchi  Ruth  Christl  Iso  Weidler  Peter G. 《Hyperfine Interactions》2001,136(1-2):73-95

The effectiveness of therapeutically used iron compounds is related to their physical and chemical properties. Four different iron compounds used in oral, intravenous, and intramuscular therapy have been examined by X-ray powder diffraction, iron-57 Mössbauer spectroscopy, transmission electron microscopy, BET surface area measurement, potentiometric titration and studied through dissolution kinetics determinations using acid, reducing and chelating agents. All compounds are nanosized with particle diameters, as determined by X-ray diffraction, ranging from 1 to 4.1 nm. The superparamagnetic blocking temperatures, as determined by Mössbauer spectroscopy, indicate that the relative diameters of the aggregates range from 2.5 to 4.1 nm. Three of the iron compounds have an akaganeite-like structure, whereas one has a ferrihydrite-like structure. As powders the particles form large and dense aggregates which have a very low surface area on the order of 1 m2?g?1. There is evidence, however, that in a colloidal solution the surface area is increased by two to three orders of magnitude, presumably as a result of the break up of the aggregates. Iron release kinetics by acid, chelating and reducing agents reflect the high surface area, the size and crystallinity of the particles, and the presence of the protective carbohydrate layer coating the iron compound. Within a physiologically relevant time period, the iron release produced by acid or large chelating ligands is small. In contrast, iron is rapidly mobilized by small organic chelating agents, such as oxalate, or by chelate-forming reductants, such as thioglycolate.

  相似文献   
25.
Structural analyses of Fe-Cr and Fe-Cr-Ni low‐alloyed steels before and after annealing at 600C using Mössbauer spectrometry, X‐ray diffraction and scanning electron microscopy are reported. At the received state, the two steels present a fine bainitic microstructure with equal hardness. From Mössbauer analysis, two iron sites are identified as substitutional by Cr, Mo, Ni atoms and as insertional by carbon in bainitic ferrite. Both sites are locally deformed by residual stresses. The presence of small quantities of retained austenite and ε carbide has been observed. Annealing for one hour at 600C causes a decrease in hardness for both steels with a decrease of retained austenite. After longer time of annealing, precipitation of (Fe,Ni)23C6 occurs in the Fe-Cr-Ni steel and increases hardness.  相似文献   
26.
金属原子和配位体原子均可用作过渡金属化合物的NMR研究,它们的谱特征与常规的NMR谱不同,文中以1H和95Mo为例进行了讨论.  相似文献   
27.
The irradiation‐induced damages and structure modifications of rare earths doped powellite single crystal have been precisely studied using optical and electron microscopy techniques, including optical interferometry, confocal micro‐Raman spectroscopy and transmission electron microscopy. The surface of powellite crystal pops out anisotropically after exposing under Ar ion beam, with a saturation swelling value of 2.0% along a‐axis and 1.3% along the c‐axis of powellite at high dose. Raman mapping on focused ion‐beam sections (5 × 3 µm2) perpendicular to the irradiated surface reveals that irradiation damage induces orientation‐dependent compressive stresses in powellite. However, no significant anisotropic effect has been found on the irradiation‐induced structural disorder in powellite. At low dose (0.012 dpa), the main irradiation‐induced defects created in powellite crystal are small defect clusters. By comparison, the dominant kinds of defects in high‐dose (5.0 dpa) sample are dislocations loops and networks. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
28.
Nanoparticles of zinc-doped maghemite were prepared using ultrasonic radiation. As a precursor, a suspension of maghemite in an alkaline aqueous solution of zinc nitrate at pH 9 was sonicated. The zinc-doped maghemite nanoparticles were investigated by X-ray diffraction, Mössbauer spectroscopy, high-resolution electron microscopy (HREM) and SQUID magnetometry. The Mössbauer measurements, which cover the temperature range 4.2 K to room temperature, were acquired in zero field and an applied field of 5 T. The results show that by using ultrasound radiation, zinc Zn2+ can substitute for Fe3+ up to a composition close to zinc ferrite (ZnFe2O4), which has a random distribution of Fe3+ ions over both A and B sublattices in the spinel structure with an inversity parameter of δ = 0.322. This leads to a maximum saturation magnetization (Ms) of 64.1 emu/g at 300 K and 73.5 emu/g at 2 K.  相似文献   
29.
Oda  Katsuro  Miwa  Yasunari  Ohtsuka  Hideyuki 《Hyperfine Interactions》2002,139(1-4):569-578
The mechanism of GMR effects in La(Mn1–x Fe x )O3 (x=0, 0.01, 0.03) oxides has been investigated by means of magnetic measurements, resistivity measurements in magnetic field and Mössbauer spectroscopy. For the x=0.01 sample, the GMR behavior is similar to that of the conventional (La, A)MnO3 (A: divalent cations) oxides. For the x=0.03 sample, even though the temperature dependence of the Mössbauer spectra was similar to that of the x=0.01 sample, the mechanism for the occurrence of the GMR effect seems to be different. The x=0 sample shows a similar behavior to the x=0.03 sample. A thermal stabilization of spin fluctuation is proposed for the x=0 and x=0.03 sample.  相似文献   
30.
Several novel tin(IV) adducts of amidines, [SnClPh3L], [SnCl2Ph2L] and [SnBr4L] {L=N,N-diphenylacetamidine (Hdpac) or N,N-diphenylbenzamidine (Hdpba)}, were prepared and investigated by Mössbauer spectroscopy which was an important tool for the elucidation of bonding and structural features. The resulting Mössbauer data also led to the conclusion that the tin(IV) centre for the adduct [SnClPh3L] is pentacoordinated in a trigonal bipyramidal arrangement and hexacoordinated for [SnCl2Ph2L] and [SnBr4L] in a geometric patterns of an octahedral. The amidines act as monodentate ligands to the metal centre for the former and bidentate for the latter.  相似文献   
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